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21.
基于在硫酸介质中,铼催化溴酸钠氧化铬黑T的褪色反应,建立了测定铼的光度分析新方法。确定了催化体系的动力学条件,计算得出催化反应的表观活化能Ea=39.12KJ/mol,反应速率常数为K=1.248×10-3/s。在选定的试验优条件下,铼的浓度在0~10.02mg/L范围内与相对吸光度呈良好的线性关系,检出限为2.7675mg/L。方法所用仪器简单,操作简便。 相似文献
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M. Sibeijn E. K. Poels A. Bliek J. A. Moulijn 《Journal of the American Oil Chemists' Society》1994,71(6):553-561
The metathesis of alkenes is a well-established reaction that is applied in various commercial processes. The meta-thesis
of functionalized olefins has not yet been commercialized despite its considerable potential. The conversion of oleochemical
feedstocks into specialty chemicals appears especially attractive. In this paper, a process scheme is proposed for the production
of 1,18-dimethyl octadecanedioate from pure methyl oleate by metathesis. The chemical and technological bottlenecks are explored,
and a rough economic evaluation of this route is given. From these considerations, it is concluded that such a process for
the metathesis of functionalized alkenes could be viable only if certain conditions are met. Rapid catalyst deactivation is
identified as one of the main obstacles. Feedstock purity, efficient recycling of unreacted feed and multiple catalyst regeneration
are crucial for economic feasibility. Rhenium-based catalysts are to be preferred over molybdenum ones because their activation
is easier and regenerability is superior. Finally, the direction for future technological and catalysis research is given
based upon the results of this work. 相似文献
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26.
研究了一种化学气相沉积(CVD)制备超细铼粉的新方法,即以NH4ReO7为原料,通过将其分解为Re2O7后气相输运至还原区,经氢气还原生成超细铼粉。对不同还原温度下制备的超细铼粉样品,采用XRD、SEM、激光粒度分析进行表征,实验揭示了烧结作用对晶粒尺寸、形貌、表面状态及粒度等粉末性能的影响规律。结果表明,随还原温度升高,烧结作用增强,制备的超细铼粉晶粒尺寸增大,具有更好的球形度,表面趋于光洁,平均粒径增大。 相似文献
27.
A. K. Aboul-Gheit M. F. Menoufy A. K. El-Morsi S. M. Abdel-Hamid 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1987,39(1):37-43
The hydroconversion of n-heptane on catalysts containing platinum hydrogen-mordenite, platinum/alumina-deficient hydrogen mordenite and platinum-rhenium/alumina-deficient hydrogen mordenite was carried out in a continuous high-pressure plug-flow reactor system and product analysis was carried out by gas chromatography (GC). The effectiveness factor for each catalyst was calculated by iteration on estimated rate constant at various reaction temperatures and the effect of diffusion on the catalytic behaviour was correlated. Catalysts exhibiting larger values of effectiveness factor were found to enhance production of 2,3-dimethylpentane on account of 3-methylhexane, whereas the reverse is true with respect to catalysts exhibiting lower values of effectiveness factor. 相似文献
28.
The work function of chemically vapor deposited rhenium, with a (0001) preferred orientation, on a molybdenum substrate was
determined using the thermionic emission method. Data were collected as a function of time and temperature on temperature
ramps from 1800 to 2600 K in 100-K increments. The effect of pressure on effective work function was demonstrated by introducing
oxygen, nitrogen, and carbon dioxide through a precision leak valve into the vacuum emission vehicle. The effect of introducing
various gasses was negligible. Also, no significant time or temperature dependence was observed. The sample yielded the maximum
average effective work function, 5.08 eV, at 2100 K. The overall average effective work function was determined to be 5.02
eV. 相似文献
29.