用硫代硫酸钠从分银渣中提取银

本文对采用硫代硫酸钠浸出银，连二亚硫酸钠还原银的工艺从分银渣中提取银进行了研究，结果表明：当分银渣中含银量为0．38％，硫代硫酸钠的用量为160kg/t，氨水用量为50L/t，浸出温度60℃，浸出温度为3h，采用二段浸出，其浸出率＞86％，采用连二亚硫酸钠还原银，还原率＞95％，同时，还原后液可再生用于浸出。     

Phase diagrams of Li2MoO4-Na2MoO4 and Na2MoO4-K2MoO4 systems

The phase diagrams of the Li2MoO4-Na2MoO4 and Na2MoO4-K2MoO4 systems have been reassessed using differential thermal analysis together with high-temperature and room-temperature X-ray diffraction analysis. The results showed that the compound Li2MoO4.6Na2MoO4 did not exist; however, it confirmed the existence of the compound Li2MoO4.3Na2MoO4 in the Li2MoO4-Na2MoO4 systen＇ls. With regard to the system of Na2MoO4-K2MoO4, we could not confirm the results reported by Bukhanova who claimed that the system was eutectic type with 1：1 and 1：2 intermediate compounds, refuting the statement of Amadori who thought there was an apparent phase boundary at high temperature in α-solid solution region of the Na2MoO4-K2MoO4 binary system. The revised phase diagrams of these systems are illustrated in this article. These experimental results are in agreement with the computerized prediction using the support vector machine-atomic parameter method for the assessment of phase diagrams.     

失效双氧水催化剂中钯的浸出-沉淀富集效率研究

研究了从失效双氧水催化剂中富集钯的工艺，采用“焙烧浸出-硫化沉钯”的工艺实现了钯的高效富集。重点考察在浸出中硫酸浓度、浸出温度、浸出时间、盐酸浓度、NaClO3用量对富集倍数的影响。研究了富集钯的最佳工艺条件，结果表明，钯平均富集12.09倍，钯的平均回收率为99.55%。     

基于动态约简的增量贝叶斯分类算法的研究

朴素贝叶斯由于条件独立性假设使其分类效果不明显,同时在处理海量数据时缺乏灵活性。针对以上情况,提出一种基于动态约简的增量贝叶斯分类算法。算法首先利用(F-λ)广义动态约简计算出数据集的核属性,然后根据训练集的先验信息构造分类器对测试实例进行分类,最后利用类置信度进行选择性增量学习,增强处理增量数据的能力。实验结果表明,该算法在处理属性少的小量数据时,分类效果有一定的改善,在处理多属性大量数据时,分类效果明显提高。     

面向主题的微博热门话题舆情监测研究——以“北京单双号限行常态化”舆情分析为例

社交媒体舆情监测是社交媒体分析的热点研究问题,学界和工业界取得了很多研究成果。但目前针对热门话题舆情监测研究中,往往只在整体上关注事件舆情趋势,而没有对事件内部不同的讨论主题进行分析。鉴于此,该研究将主题分类模型引入到舆情监测中来,并在此基础上,以时间为脉络进行面向主题的情感分析。并以“北京市单双号限行常态化”这一微博话题为例进行实证研究,通过各个时段 “北京市单双号限行常态化”这一微博话题群体情感倾向变化的分析,为舆情的监测提供对象和时点选择的参考建议。
     

Nave Bayes分类器制导的专业网页爬取算法

从Web中快速、准确地检索出所需信息的迫切需求催生了专业搜索引擎技术。在专业搜索引擎中,网络爬虫(Crawler)负责在Web上搜集特定专业领域的信息,是专业搜索引擎的重要核心部件。该文对中文专业网页的爬取问题进行了研究,基于KL距离验证了网页内容与链接前后文在分布上的差异,在此基础上提出了以链接锚文本及其前后文为特征、Nave Bayes分类器制导的中文专业网页爬取算法,设计了自动获取带链接类标的训练数据的算法。以金融专业网页的爬取为例,分别对所提出的算法进行了离线和在线测试,结果表明,Nave Bayes分类器制导的网络爬虫可以达到近90%的专业网页收割率。     

Na(i)ve Bayes分类器制导的专业网页爬取算法

从Web中快速、准确地检索出所需信息的迫切需求催生了专业搜索引擎技术.在专业搜索引擎中,网络爬虫(Crawler)负责在Web上搜集特定专业领域的信息,是专业搜索引擎的重要核心部件.该文对中文专业网页的爬取问题进行了研究,基于KL距离验证了网页内容与链接前后文在分布上的差异,在此基础上提出了以链接锚文本及其前后文为特征、Naive Bayes分类器制导的中文专业网页爬取算法,设计了自动获取带链接类标的训练数据的算法.以金融专业网页的爬取为例,分别对所提出的算法进行了离线和在线测试,结果表明,Naive Bayes分类器制导的网络爬虫可以达到近90%的专业网页收割率.     

Sufficient Utilization of Mn2+/Mn3+/Mn4+ Redox in NASICON Phosphate Cathodes towards High-Energy Na-Ions Batteries

Na superionic conductor of Na₃MnTi(PO₄)₃ only containing high earth-abundance elements is regarded as one of the most promising cathodes for the applicable Na-ion batteries due to its desirable cycling stability and high safety. However, the voltage hysteresis caused by Mn²⁺ ions resided in Na⁺ vacancies has led to significant capacity loss associated with Mn reaction centers between 2.5–4.2 V. Herein, the sodium excess strategy based on charge compensation is applied to suppress the undesirable voltage hysteresis, thereby achieving sufficient utilization of the Mn²⁺/Mn³⁺ and Mn³⁺/Mn⁴⁺ redox couples. These findings indicate that the sodium excess Na_3.5MnTi_0.5Ti_0.5(PO₄)₃ cathode with Ti⁴⁺ reduction has a lowest Mn²⁺ occupation on the Na⁺ vacancies in its initial composition, which can improve the kinetics properties, finally contributing to a suppressed voltage hysteresis. Based on these findings, it is further applied the sodium excess route on a Mn-richer phosphate cathode, which enables the suppressed voltage hysteresis and more reversible capacity. Consequently, this developed Na_3.6Mn_1.15Ti_0.85(PO₄)₃ cathode achieved a high energy density over 380 Wh kg⁻¹ (based on active substance mass of cathode) in full-cell configurations, which is not only superior to most of the phosphate cathodes, but also delivers more application potential than the typical oxides cathodes for Na-ion batteries.     

Na3Zr2Si2PO12固态电解质研究进展

钠离子电池具有资源丰富、能量密度高等优点,使用固态电解质的固态钠电池兼具高安全性成为研究热点。固态电解质是超离子导体,是固态电池关键材料。Na₃Zr₂Si₂PO₁₂是钠超离子导体（NASICON）中最具代表性的固态电解质材料。总结了Na₃Zr₂Si₂PO₁₂材料的结构、离子传输机制及其相互关系,旨在从机理上理解Na₃Zr₂Si₂PO₁₂固态电解质中钠离子传输性能;总结了主要制备方法,指出了不同方法的优缺点;在提升离子电导率方面,对合成工艺、掺杂、界面因素进行了总结,力求归纳和探索合成高性能钠离子固态电解质的途径。