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Strength of Materials - A metallographic method, dilatometry, and X-ray diffraction were applied to investigate the effects of undercooling and holding time on bainitic transformation,... 相似文献
33.
Scientometrics - The purpose of this study is to ascertain the suitability of GS’s url-based method as a valid approximation of universities’ academic output measures, taking into... 相似文献
34.
Evangelopoulos Xenophon Brockmeier Austin J. Mu Tingting Goulermas John Y. 《Machine Learning》2019,108(4):595-626
Machine Learning - We propose a set of highly scalable algorithms for the combinatorial data analysis problem of seriating similarity matrices. Seriation consists of finding a permutation of data... 相似文献
35.
Refinement of atomic models is a necessary step in solving the macromolecular structure by X-ray diffraction methods. Nowadays, high automation and well-developed interfaces give a possibility to use the most popular refinement programs as black boxes. Nevertheless, working with complex objects requires an understanding of the internal structure and principles of operation of these programs and critical assessment of the results of refinement. In this review, we discuss the basic principles of the organization of refinement programs and the history of their improvement and development, as the studied objects became more and more complicated. The discussions are kept at the level of basic mathematic knowledge avoiding unnecessary formalism and too detailed expressions. 相似文献
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Bahaa El-Dien M. El-Gendy Atwa Shoukar T. Ahmed Aziza A. El-Etre Ali Y. 《Protection of Metals and Physical Chemistry of Surfaces》2019,55(1):179-186
Protection of Metals and Physical Chemistry of Surfaces - Three novel inhibitors based on 4,5,6,7-tetrahydrobenzo[b]thiophene scaffold were synthesized and characterized. The inhibitive action of... 相似文献
38.
360° VR videos provide users with an immersive visual experience. To encode 360° VR videos, spherical pixels must be mapped onto a two‐dimensional domain to take advantage of the existing video encoding and storage standards. In VR industry, standard cubemap projection is the most widely used projection method for encoding 360° VR videos. However, it exhibits pixel density variation at different regions due to projection distortion. We present a generalized algorithm to improve the efficiency of cubemap projection using polynomial approximation. In our algorithm, standard cubemap projection can be regarded as a special form with 1st‐order polynomial. Our experiments show that the generalized cubemap projection can significantly reduce the projection distortion using higher order polynomials. As a result, pixel distribution can be well balanced in the resulting 360° VR videos. We use PSNR, S‐PSNR and CPP‐PSNR to evaluate the visual quality and the experimental results demonstrate promising performance improvement against standard cubemap projection and Google's equi‐angular cubemap. 相似文献
39.
In situ real-time imaging and electrochemical impedance spectroscopy (EIS) measurements were performed on pure aluminium, aluminium-copper and copper electrodes, with the aim to elucidate the relationship between the shape of EIS spectra and the local processes occurring on the surface of corroding aluminium, with particular attention to the appearance of inductive behaviour. When a stable oxide was present on the aluminium surface, the impedance modulus increased with decreasing frequencies, indicating the absence of inductive behaviour. Conversely, the presence of depassivating condition coupled with the availability of some anodic current, generated localized corrosion and associated hydrogen evolution at the corrosion front (also known as superfluous hydrogen evolution). In these conditions, a clear inductive behaviour was observed, regardless on the source of the anodic current at the corrosion front, i.e. galvanic coupling or external anodic polarization. 相似文献
40.
Shuaiqi Meng Dr. Jia Guo Dr. Kaili Nie Prof. Tianwei Tan Haijun Xu Prof. Luo Liu 《Chembiochem : a European journal of chemical biology》2019,20(17):2232-2235
Fatty acids are versatile precursors for fuels, fine chemicals, polymers, perfumes, etc. The properties and applications of fatty acid derivatives depend on chain length and on functional groups and their positions. To tailor fatty acids for desired properties, an engineered P450 monooxygenase has been employed here for enhanced selective hydroxylation of fatty acids. After oxidation of the hydroxy groups to the corresponding ketones, Baeyer–Villiger oxidation could be applied to introduce an oxygen atom into the hydrocarbon chains to form esters, which were finally hydrolyzed to afford either hydroxylated fatty acids or dicarboxylic fatty acids. Using this strategy, we have demonstrated that the high-value-added flavors exaltolide and silvanone supra can be synthesized from stearic acid through a hydroxylation/carbonylation/esterification/hydrolysis/lactonization reaction sequence with isolated yields of about 36 % (for ω−1 hydroxylated stearic acid; 100, 60, 80, 75 % yields for the individual reactions, respectively) or 24 % (for ω−2 hydroxylated stearic acid). Ultimately, we obtained 7.91 mg of exaltolide and 13.71 mg of silvanone supra from 284.48 mg stearic acid. 相似文献