排序方式: 共有56条查询结果,搜索用时 841 毫秒
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采用第一性原理方法,模拟了应变对四方相BaTiO3(BTO)空位形成能的影响,并计算了应变和双空位共同作用下BaTiO3体系的极化.计算结果表明,应变改变了空位形成能,且在–3%到3%的应变范围内,氧空位的形成能逐渐减小,亦即压应变抑制了氧空位的形成,这与Ti–O键的变化有关.此外压应变在改变双空位形成能的同时,增大了体系的极化和极化偏移,对于1A和2A组合的双空位即使在–3%的应变下其极化偏移也只有1μC/cm2和0.3μC/cm2,而极化偏移是印记效应的表现,因此应变对印记效应的影响很小,可以忽略. 相似文献
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本文结合纳米压痕和有限元法确定了横观各向同性ZnO纳米带各方向上的弹性常数。在正向分析过程中,用ABAQUS有限元软件的压电模式大量模拟了纳米带/硅基底体系的压痕实验,得到无量纲方程的具体形式。在反向分析过程中,通过对沉积在硅基底上的ZnO纳米带进行纳米压痕实验,将相关实验数据代入无量纲方程,确定横观各向同性ZnO纳米带各方向上的弹性常数为ET=35GPa,EL=49GPa和GL=5GPa。 相似文献
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Evolution of domain structure and frequency effect on ferroelectric properties in BIT ferroelectrics
Based on the time-dependent Ginzburg-Landau (TDGL) equation, the temporal evolution of the domain structure and hysteresis loops of polarization versus electric field were simulated by a phase-field model for Bi4Ti3O12 (BIT) ferroelectric single crystal under an applied electric field. In the static electric energy induced by an applied alternating electric field, the effects of field frequency on the ferroelectric properties of BIT ferroelectrics were investigated. The results show that the evolution of ferroelectric domain structure is a gradual process including domain nucleation, domain wall motion, domain growth and domain combination. In the boundary regions of ferroelectric domain, the new domain nucleations occur and the old domains disappear. The coercive field increases with the field frequency, and it is in good agreement with the previous experiment. 相似文献
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Nanocrystalline nickel films of 17-40 nm grain sizes were prepared using pulsejet electrodeposition. Structure, corrosion and lattice strain were analysed by transmission electron microscope, electrochemical workstation and X-ray diffraction, revealing that with decreasing of grain size, the lattice strain, corrosion rate of the films are enhanced. The observations can be consistently understood in terms of the bond-order-length-strength correlation mechanism indicating that the shortened and strengthened bonds between the under-coordinated atoms modify the eriergy density and the atomic cohesive energy in the surface skins of the grains. The surface energy density gain is responsible for the residual atomic cohesive energy for the activation energy of corrosion. Additionally, a novel algorithm was proposed to extract the elastic-plastic properties of nickel films and results that the nickel film has much higher yield strength than bulk nickel. 相似文献
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应用纳米压痕法测量残余应力的2种理论模型对5种电沉积镍镀层中的残余应力在不同压痕深度处进行了测量,并与X射线衍射法的测量结果进行了比较.结果表明,压深位于薄膜/基底界面处的2种压痕法测量结果与X射线衍射法的测量结果相近,且Yun-Hee模型与其符合得更好. 相似文献
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在壳模型的基础上, 通过分子动力学方法模拟了压强对Bi4Ti3O12(BIT)铁电相变行为的影响. 为了提高模拟的准确性, 在原有势参数的基础上增加了Ti-Ti短程相互作用势. 计算得出了温度为300K时BIT单晶的铁电正交B2cb相在x方向和z方向的自发极化强度分别为39.4μC/cm2和0, 与实验结果较好的吻合. 然后模拟了压强对BIT相变行为的影响. 模拟结果表明: BIT单晶在压强从-2 GPa到24 GPa范围内, 经历了两次结构相变, 分别发生在 6 GPa和20 GPa处. 这种对称性的改变类似于在环境压力条件下温度导致BIT单晶对称性的改变. 因而模拟结果为研究压强引起BIT的相变行为提供了理论依据. 相似文献