Crystal Structure and Properties of Europium m-Chlorobenzoate Complex with 1, 10-Phenanthroline

A europium m-chlorobenzoate complex with 1,10-phenanthroline [Eu(m-ClBA)3(phen)]2 single crystal, where m-ClBA=m-chlorobenzoate and phen=1,10- phenanthroline,was prepared and structurally characterized by X-ray diffraction. It crystallizes in triclinic, space group P1- with a=1.10138(8)nm, b=1.18606(9) nm, c=1.32516(10) nm, α=112.5390(10)°, β=92.1700(10)°, γ=101.6220(10)°,C66H40N4O12Cl6Eu2, Mr=1597.64, V=1.5533(2) nm3, Z=1, Dc=1.708 g·cm-3, μ(Mo Kα)=2.325 mm-1, F(000)= 788, the final R=0.0424 and wR=0.0899 for 6856 independent reflections with Rint=0.0776.The crystal consists of binuclear molecules of the title compound. Each Eu3 ion is nine-coordinated to one 1,10-phenanthroline molecule, one bidentate carboxylate group and four bridging carboxylate groups. The carboxylate groups are bonded to the europium ion in three modes: the chelating bidentate, the bridging bidentate and bridging-chelating thridentate. Excitation and luminescence data observed at room temperature show that the title complex emits very intensive red fluorescence under ultraviolet light. The results of thermal analysis indicate that the complex ［Eu(m-ClBA)3(phen)］2 is quite stable to heat.     

透射式烟度计检定用中性标准滤光片的研制

一、原理 1.透射式烟度计原理透射式烟度计是依据不同物质对可见光区辐射产生的特征吸收光谱不同及朗伯-比尔(Lambert-Beer)定律,测量物质对某些波长的吸收程度进行定量分析的仪器.定律如下:     

养护参数对常压干热养护灰砂混凝土力学性能的影响

本文通过掺入一种外加剂MH,提高了灰砂混凝土在高温下的保水性,研究了常压干热养护工艺参数对灰砂混凝土力学性能的影响。钙硅比为0.25,水固比为0.14,胶集比为0.5,MH掺量为9%的灰砂混凝土在升温速率为1℃/min,恒温温度为140℃,恒温时间为5h的养护制度下进行常压干热养护,抗压强度可达40.2MPa,抗折强度可达8.3MPa。X射线衍射和扫描电子显微镜分析结果表明:掺入MH制备的常压干热养护灰砂混凝土主要反应产物为NaCaHSiO_4、Na_2Ca_2Si_2O_7·H_2O和沸石类为主的水化产物。     

Synthesis of calcium silicate hydrate based on steel slag with various alkalinities

This study aimed to improve the hydraulic potential properties of the slag. Therefore, a method of dynamic hydrothermal synthesis was applied to synthesize calcium silicate hydrate. The phases and nanostructures were characterized by XRD, FTIR, TEM, and BET nitrogen adsorption. The infl uence of alkalinity of steel slag on its structures and properties was discussed. The experimental results show that, the main product is amorphous calcium silicate hydrate gel with fl occulent or fi brous pattern with a BET specifi c surface area up to 77 m2/g and pore volume of 0.34 mL/g. Compared with low alkalinity steel slag, calcium silicate hydrate synthesized from higher alkalinity steel slag is prone to transform to tobermorite structure.     

大药量水箱法测定炸药爆轰压力的研究

研究了恩梯和钝化黑索今两种炸药的装药直径和长度对爆压的影响。确定了测定爆压的标准药量,改进并统一了试验方法,起爆条件,记录底片的判读区间和数据处理方法。测试精确度接近美国军用标准水平。     

发挥涂装行业作用,不断提高涂装技术水平

涂装是机械制造业中的重要工艺之一。过去由于世俗偏见,涂装工艺长期来不被重视,相对其它基础工艺来说是比较落后的。落后的工艺必然导之产品涂装质量的低劣,尽管产品的内在质量是一流的,往往因表面涂装质量差而成为不起眼的处理品,造成严重的经济损失。随     

黏结剂对含铝炸药造型粉流散性和堆积密度的影响

为了研究黏结剂对含铝炸药造型粉流散性和堆积密度的影响,使用炸药造型粉流散性测量仪,以A-Ⅸ-Ⅱ炸药为参比标准,对使用不同黏结剂体系制造的含铝炸药造型粉进行分析测试.结果表明,使用硬脂酸和聚异丁烯黏结剂体系,含铝炸药造型粉的流散性与A-Ⅸ-Ⅱ炸药相当,而堆积密度明显优于A-Ⅸ-Ⅱ炸药.采用该黏结剂体系制备出的含铝炸药造型粉更适合分步压装装药工艺.     

浅谈项目实施阶段工程造价管理

本文剖析了项目实施阶段段工程造价管理应从三个方面入手,即招标管理、施工管理和结算管理     

活性白土生产工艺

用浓度为１．２５－２．２５ｍｏｌ／ｌ的硫酸溶液润土,回收反应液和洗涤水循环用于膨润土的活化和产品的洗涤,在生产活性白土的同时,生产硫酸铝。硫酸的利用率达到９７％,耗水量减少到一般湿法生产的１５－２０％。生产成本降低,不污染环境。活性白土产品脱色率达９７％以上,活性度大于２００。     

响应面优化红花籽油碱异构化法制备共轭亚油酸的研究

以新疆优质红花籽油为原料,通过碱异构化法制备共轭亚油酸(CLA)。采用单因素试验研究了异构化过程中反应温度、反应时间、PEG-400用量、Fe(OH)_3用量对CLA转化率的影响,同时采用响应面法对制备工艺进行优化。结果表明:在红花籽油质量为20 g前提下,红花籽油碱异构化法制备共轭亚油酸的最佳工艺条件为以PEG-400为溶剂、Fe(OH)_3为催化剂、反应温度178℃、反应时间2.7 h、PEG-400用量265 m L、Fe(OH)_3用量6 g,在此条件下,CLA转化率为96.54%。