PPO/PA合金的研制

比较了三条技术路线、PPO／PA质量比、各种抗冲击剂对PPO／PA合金性能的影响。应用FTIR．Molau实验、DSC曲线证实了改性反应原理及增容作用。结果表明：在双螺杆挤出机中，聚苯醚(PPO)与马来酸酐(MAH)接枝反应，然后与聚酰胺(PA66)、SEBS挤出共混，制成的PPO／PA合金，抗冲击性能高。     

Water uptake of epoxy coatings modified with γ-APS silane monomer

Epoxy resin was modified by a silane monomer, γ-aminopropyltrimethoxy silane (γ-APS), and was used as the protective coatings for LY12 aluminum alloys. The aim of the modification is to reduce the water uptake of polymeric coatings. The water absorption of coatings was measured by coating capacitance method in 3.5 wt.% NaCl aqueous solution. The result indicates that water uptake of epoxy coatings modified with 1.0 wt.% γ-APS decreases compared with pure epoxy coatings, whereas larger amounts of sliane result in the deterioration in performance against water permeation, due to the excessive consumption of epoxide group in epoxy resin by amino-group in silane agent, thus reduce the cross-linking of epxoy coating as a result of presence of excessive curing agent (polyamide). T_g of silane-modified coatings increases slightly after immersion, extremely contrasting with that of pure epoxy coating, which was observed to decrease significantly after water permeation. The formation of Si–O–Si structure resulting from the hydrolysis and condensation of silane components during the immersion in aqueous media may be a reasonable explanation for the abnormal change in T_g of silane-modified coatings. In addition, all silane-modified coatings display better protection performance, which is characterized by higher charge transfer resistances (R_ct) and lower double layer capacitance (C_dl) at substrate/electrolyte interface.     

高摩尔质量牵引剂改性聚丙烯/蒙脱土的研究

考察了自行合成的聚异丁烯基新型高摩尔质量牵引剂和活化剂对聚丙烯改性纳米蒙脱土的作用效果，研究了不同摩尔质量的牵引剂及复合使用产生的梯度牵引作用，考察了牵引剂、活化剂用量等因素以及加工条件对改性聚丙烯专用料性能的影响。结果表明，以聚丙烯为基础树脂，蒙脱土为改性剂，用该牵引剂加活化剂进行改性，采用简单的混合混炼工艺，当蒙脱土质量分数4％时，改性聚丙烯专用料的性能大幅提高，并且加工性能良好。     

Modification of zeolite surfaces by Grignard reagent

New microporous hybrid organic/inorganic materials were obtained by modification of zeolites using chlorination of their surface, followed by treatment with a Grignard reagent. Loading of butyl groups and retained crystallinity of ZSM-5 type zeolites was higher than for zeolites Y. In contrast to zeolites Y, the lattice parameters of zeolites ZSM-5 increased after surface modification. The obtained hybrid materials on the basis of high-silica zeolites possess a high degree of crystallinity at increased hydrophobicity.     

Toward a toolbox of functional block copolymers via free-radical addition of mercaptans

This work demonstrates the applicability of the free-radical addition of ω-functional mercaptans onto 1,2-polybutadienes as a modular synthetic pathway toward a toolbox of diverse functional block copolymers. Functional groups included, for instance electrolytes (carboxylic acid and amine), l-amino acid, and fluorocarbon. The number of functional groups attached to the polymer was lower than that of double bonds reacted (degree of functionalization=50–85%, typically 70–80%) due to cyclization of two neighboring units, but the narrow molecular-weight distribution of the parent (co)polymer was always maintained.     

机械力化学改性硅灰石/聚丙烯性能的研究

利用气流磨对硅灰石进行机械力化学改性，并用IR分析对改性效果进行了预评价；对比了用改性前后的硅灰石填充聚丙烯(PP)的性能。结果表明：改性后硅灰石分别为由亲水疏油性变为亲油疏水性；硬脂酸质量分数为1．5％时，改性硅灰石／PP复合材料的拉伸强度和冲击强度最好。     

改性AC发泡剂的现状与发展对策

分析AC发泡剂原粉在应用中的一些缺陷;叙述改性AC的种类、改性的途径及我国改性AC的现状研究进展;探讨我国改性AC在品种和应用研究方面与国外的差距;应大力开发改性AC.     

聚甲醛耐老化性能及其改进研究

以研制耐候性聚甲醛为目标，将自制高分子改性剂、其它改性剂与聚甲醛共混(POM)以提高POM的耐老化性。通过拉伸强度、断裂伸长率、冲击强度和色差的测定，比较了未改性聚甲醛和改性聚甲醛的耐紫外光老化、热氧老化和热水老化性能，结果表明：自制改性剂与其它改性剂共混用于聚甲醛，能显著改善聚甲醛的稳定性及耐老化性。     

超支化聚合物用于材料制备和改性的研究

综述了近年来超支化聚合物在聚合物增韧、增塑、粉体填料的表面改性以及制备纳米粒子和纳米复合材料等方面的研究进展。     

GJB151A/152A—1997亟待修订

从复杂电磁环境客观要求、标准化要求、军民用技术融合、标准自身存在不合规范问题等4个方面论述GJB151A/152A—1997修订的必要性和紧迫性。明确提出军事电磁兼容概念,针对标准化发展趋势、我军电磁兼容特殊情况和标准本身等方面的问题,提出了修订GJB151A/152A—1997的建议。