硬质合金刀具涂层技术的研究进展

随着涂层技术的进步，使得硬质合金刀具涂层方法在不断地进步，日趋复杂化和多样化；硬质合金刀具涂层种类也在不断地更新，从单一的化合物涂层朝着多元复杂化合物涂层发展，涂层层数也从几层到十几层发展。本文简要地综述了目前国内外涂层硬质合金刀具的特点，高温化学气相沉积涂层(HTCVD或简称CVD)、物理气相沉积涂层(PVD)、等离子化学气相沉积涂层(PCVD)、中温化学气相沉积涂层(MTCVD)和离子辅助物理气相沉积涂层(IBVD)这5种硬质合金刀具涂层方法的机理、特点和缺点，以及单渗层涂层硬质合金、多渗层涂层硬质合金和新渗层涂层硬质合金这3种硬质合金刀具涂层的特点和应用。     

Effect of Sr and Ce on Synthesis of Nanometer Perovskite LaMnO3＋λ

Nanometer perovskite LaMnO3 λ, La0.6Ce0.4MnO3 λ and La0.6Sr0.4MnO3 λ were prepared by citric acid-aide dsol-gel method. The effects of Ce, Sr on the structure and properties of nanometer perovskite were studied through DTTGA, XRD, TEM and BET analyses. The results show that, by sol-gel method, LaMnO3 λ, La0.6Ce0.4MnO3 λ and La0.6Sr0.4MnO3 λ were made with average particle size of about 60, 100 and 30 nm, respectively. After partially substituting Sr on La positions in LaMnO3 λ, it is found that Sr is located at the perovskite lattice so as to reduce the formation temperature of the perovskite. As a result, the perovskite has a smaller particle size and larger specific surface area. On the contrary, it is difficult for Ce to enter the perovskite lattice. Ce exists mostly in the form of CeO2 as partially substituting La in LaMnO3 λ. The formation temperature of the perovskite increases, and the catalyst containing CeO2 presents a larger particle size and less specific surface area.     

稳定剂对环保型无铅无镉釉上彩熔剂性能影响的研究

在碱-硼-硅系统基础熔剂中引入稳定剂，运用正交实验方法对无铅无镉釉上彩熔剂性能进行研究。通过化学稳定性、堆烧、粘度测试、印花彩烤等一系列对比试验，研究了稳定剂ZrO2、ZnO、SnO2和TiO2的最佳引入量。实验结果表明：在基础熔剂配方的基础上。稳定剂ZrO2的最佳引入量为6％；SnO2引入量不应超过5％；ZnO引入量10％为最好；TiO2引入1％的最低水平即可，8#为本研究中的最佳配方。     

草酸钴还原过程的相变研究

利用电子探针扫描研究了制取钴粉的两个不同过程产物的相变。结果表明:由草酸钴(CoC2O4·2H2O)直接通过氢气还原制取钴粉,其钴粉的分散性和流动性差,不利于进一步生产优质硬质合金;由草酸钴(CoC2O4·2H2O)先在空气中煅烧为氧化钴(Co2O3),然后再用煅烧所得的氧化钴(Co2O3)通过氢气还原制取钴粉,其钴粉分散性和流动性好,利于进一步生产优质硬质合金。     

螺旋状匹配搜索的块拼贴纹理合成

基于样图的纹理合成方法是继纹理映射、过程纹理合成等方法后发展起来的一种纹理拼贴方法。该文在Efros块拼贴算法和徐晓刚的螺旋状点匹配搜索算法基础上,提出了一种螺旋状匹配搜索的块拼贴算法。该算法利用纹理块的连惯性,在搜索待合成纹理块时,在已合成纹理块在样本图像中位置的邻域进行搜索,找到匹配纹理块后进行输出。该方法大大加快了纹理合成的速度,与Efros块拼贴算法相比,在合成质量不变的基础上,合成速度平均提高了10倍。对于不同的纹理进行实验,其结果也令人满意。     

Effects of cerium and vanadium on the activity and selectivity of MnOx-TiO2 catalyst for low-temperature NH3-SCR

MnOx-TiO2,CeO2-MnOx-TiO2 and V2O5-MnOx-TiO2 catalysts for low-temperature NH3-SCR were prepared by sol-gel method.The results showed that both cerium and vanadium prevented the transformation of anatase TiO2 to the rutile phase.The addition of vanadium oxide induced the segregation of crystalline Mn2O3,which contributed little to low-temperature SCR and ammonia oxidation,from the MnOx-TiO2 solid solutions.However,the selectivity of the V-containing catalyst was almost 100% due to the decreased ammonia consump-tion and enhanced adsorption capacity of ammonia on Br(?)nsted acid sites at relatively high temperatures.The electron-donating effect of ce-rium reduced the Mn4+/Mn3+ ratio to some extent,resulting in a decreased activity for ammonia oxidation.This,in combination with the en-hanced ammonia adsorption capacity by Cen+ as additional Lewis acid sites,endowed the Ce-doped catalyst a higher N2 selectivity than MnOx-TiO2 despite the slightly elevated light-off temperature for NO conversion.     

不完全竞争市场钢铁价格形成机制研究

通过分析钢铁价格市场化形成的机理及对我国钢铁市场的影响和作用，揭示在我国市场竞争体系建设尚不健全的背景下，价格在完全自由竞争中形成的弊端，探索合乎我国钢铁市场可持续发展之路的价格形成机制。     

宝钢连铸中间包热状态测试与分析

连铸中间包内钢水温度是炼钢生产过程的重要工艺参数之一，影响该参数的因素很多，通过对宝钢炼钢部60t中间包的包衬热状态进行测试，分析了包衬蓄热状况对中间包钢水温度的影响。     

控灌技术的升华

控制灌溉技术也称精准灌溉技术，它是精准农业的一部分，其原理是根据水稻生理生态需水的特点，通过对水稻生长发育的动态研究而确定的灌溉新模式。控制灌溉是在水稻稳产增产的同时，提高了水肥的有效利用率，增加了田间的积温，有利于水稻的优质高产。其特点是优质、高产，节水、高效，抗倒伏、抗病虫害。其本质，就是用控制灌溉的方式，使有利于水稻生长的各个过程达到最佳状态。