Compatibilization and properties of ethylene vinyl acetate copolymer (EVA) and thermoplastic polyurethane (TPU) blend based foam

Ethylene vinyl acetate copolymer/thermoplastic polyurethane (EVA/TPU) blending foams are rarely reported so far because of their poor compatibility, and addition of a compatibilizer to the blend system was our major interest, which can improve interfacial adhesion between the two phases. In this paper, TPU-grafted EVA (EVA-g-TPU), as a compatibilizer, was simply prepared using maleic anhydride-grafted EVA (EVA-g-MAH) and 4,4′ diamino diphenyl methane in the mixing process of TPU and EVA matrix. Fourier transform infrared spectroscopy and differential scanning calorimetry were used to investigate the structures of EVA-g-TPU and the interfacial reaction in the mixing process, and the effect of EVA-g-TPU on compatibilization between the two phases of EVA/TPU blends was investigated using scanning electron microscopy. Finally, EVA/EVA-g-TPU/TPU foams based on the good compatibility of the resin blends were prepared, and the physical properties directly related to the compatibility were investigated as a function of the theoretical quantity (molar mass) of EVA-g-TPU (n _EVA-g-TPU) in the foams. Moreover, the tensile strength, elongation at break, tear strength and compression set were improved by 19.0, 9.3, 43.6 and 7.5 %, respectively. Overall, EVA/EVA-g-TPU/TPU foams with excellent mechanical properties were obtained without sacrificing other important physical properties (lower density etc.) through popular and friendly means in this research.     

Ag/Bi2WO6 plasmonic composites with enhanced visible photocatalytic activity

Three-dimensional flower-like Bi₂WO₆ microspheres with the diameter of about 4 μm were prepared by a facile hydrothermal method using bismuth nitrate pentahydrate and sodium tungstate dihydrate as raw materials. A novel Ag-modified Bi₂WO₆ was synthesized through a simple and practical photoreduction process. The UV–vis diffuse reflectance spectra indicate that the Ag/Bi₂WO₆ samples have a significantly enhanced optical absorption in the visible light region than that of pure Bi₂WO₆ microspheres due to the surface plasmon resonance (SPR) of Ag nanoparticles on the surface of pure Bi₂WO₆. The photocatalytic activities of the as-prepared samples were evaluated by the decolorization of rhodamine B under simulated sun-light irradiation. The results reveal that the photocatalytic activities of the Ag/Bi₂WO₆ samples increase first and then decrease with increasing amount of loading Ag and the 1.0 wt% Ag-loaded Bi₂WO₆ sample exhibits the best photocatalytic activity compared with the other samples. The enhanced photocatalytic activity could be attributed to the synergistic effect of the strong SPR and the effective separation of photogenerated electrons and holes caused by Ag nanoparticles.     

石墨烯材料的吸附性能研究进展

石墨烯材料的吸附性能引起了国内外科学工作者的极大关注,主要介绍了近些年石墨烯和氧化石墨烯对水中金属离子、有机染料、无机非金属离子的吸附性能及研究进展。     

正交实验法优选黄连中盐酸小檗碱醇提工艺的研究

用乙醇提取黄连中盐酸小檗碱,采用正交实验法优化工艺条件.结果表明,优选的醇提工艺条件为：50％乙醇提取3次,每次提取时间1.5h,3次加醇量分别8,6,6倍.该醇提工艺重现性和稳定性良好.     

Synthesis of chemically controllable and electrically tunable graphene films by simultaneously fluorinating and reducing graphene oxide

Fluorine and oxygen co-doped graphene with controllable element coverage was effectively synthesized through simultaneously fluorinating and reducing graphene oxide by pyrolysis of fluorinated graphite. Morphology investigation indicates that the doped graphene is of few-layered thickness, and the prepared films exhibit layered structure through cross-section. Chemical composition analysis confirms that fluorine has been grafted onto graphene scaffold through CF covalent bond, and the doping level can be readily manipulated just by adjusting the reaction temperature. The structural changes of graphene induced by the controllable doping thus facilitate the tunable electrical property, which can be tuned over several orders of magnitude. These results indicate our method is not only potentially useful to tailor the chemical surface and electronic structure of graphene, but also can find applications in novel electronic devices based on graphene co-doped with different dopants.     

特低渗透油藏启动压力对油田开发的影响

特低渗透油藏由于孔喉结构的特殊性而导致流体在微小孔喉中呈现微尺度流动效应,即非达西渗流。利用岩心实验及数学模拟方法详细研究了特低渗透油藏启动压力梯度及其对油田开发的影响。研究结果表明:启动压力梯度与渗透率之间呈幂函数关系;启动压力梯度对水平井产量影响小于直井;在相同的含水饱和度下,具启动压力的油藏含水率上升较快且容易发生指进。非达西渗流将增大特低渗透油藏注水开发的难度。     

超低渗透油藏体积压裂技术研究与试验

随着低渗、超低渗油藏的开发,由于受到储层条件、注采井网、压裂工艺等多重限制,单一增加缝长来提高超低渗油藏产量效果不明显,常规压裂工艺改造难以实现该类油藏的有效开发。混合水体积压裂技术通过"大液量、高排量、低砂比"增加缝内净压力,有效扩大储层改造体积,从而提高措施增油能力,为有效提高单井产量提供了新思路、新方法。     

回火温度对40CrMoVNbTi钢组织和性能的影响

采用780℃亚温淬火和不同温度回火,探究回火温度对40CrMoVNbTi钢组织和力学性能的影响。对淬火不同温度回火40CrMoVNbTi钢的力学性能变化及显微组织和冲击断口断貌进行观察和分析。结果表明,780℃亚温淬火,随回火温度的提高,40CrMoVNbTi钢的强度下降,塑性呈上升趋势,300℃回火冲击吸收能量值最低,出现回火脆性。200℃回火组织为回火马氏体和残留奥氏体,其抗拉强度为2150 MPa,KV₂为23.8 J;550～600℃回火组织为回火索氏体,韧性较好,其抗拉强度为1190～1070 MPa,KV₂为94～123 J,满足AISI 4140钢的力学性能要求,具有较高的冲击性能。     

Structural and Interfacial Properties of Hyperbranched-Linear Polymer Surfactant

With oleic acid grafting modification, a series of hyperbranched-linear polymer surfactants (HLPS) were prepared by hydroxyl-terminated hyperbranched polymer (HBP), which was gained through a step synthesis method using trimethylolpropane and AB₂ monomer. The AB₂ monomers were obtained through the Michael addition reaction of methyl acrylate and diethanol amine. The structures of HLPS were characterised by Fourier transform infrared spectrophotometer and nuclear magnetic resonance (NMR), which indicated that HBP was successfully modified by oleic acid. Furthermore, the properties of surface tension and critical micelle concentration of HLPS solution showed that HLPS can significantly reduce the surface tension of water. The morphology of the HLPS solution was characterised by dynamic light scattering, which revealed that HLPS exhibited a nonmonotonic appearance in particle size at different scattering angles owing to the different replaced linear portions. The relationships of the surface pressure to monolayer area and time were measured using the Langmuir–Blodgett instrument, which showed that the surface tension of monolayer molecules increased with the increasing of hydrophobic groups. In addition, the interface conditions of different replaced HLPS solutions were simulated.     

格列美脲分子印迹聚合物应用于固相萃取的研究

以降血糖药物格列美脲为模板分子,ɑ-甲基丙烯酸(MAA)为功能单体,乙二醇二甲基丙烯酸酯(EDMA)为交联剂,偶氮二异丁腈(AIBN)为引发剂,采用本体聚合法制备了格列美脲分子印迹聚合物(MIP),用于血浆样品前处理,建立了对加标兔血浆中格列美脲含量的固相萃取检测方法,通过高效液相色谱法测定,分子印迹固相萃取柱的回收率可达80%以上,有效地减少了基体中蛋白质等杂质对目标物检测的干扰,适用于生物样品中模板分子的富集和纯化。