Catalytic reduction of 2,4‐dinitrophenylhydrazine by cuttlebone supported Pd NPs prepared using Conium maculatum leaf extract

A facile and green process to synthesise cuttlebone supported palladium nanoparticles (Pd NPs/cuttlebone) is reported using Conium maculatum leaf extract and in the absence of chemical solvents and hazardous materials. The antioxidant content of the C. maculatum leaf extract played a significant role in converting Pd²⁺ ions to Pd NPs. Various techniques were used for the characterisation of the Pd NPs/cuttlebone such as field‐emission scanning electron microscopy, X‐ray diffraction, energy dispersive X‐ray spectroscopy, Fourier transform infrared and ultraviolet–visible spectroscopy. This Pd NPs/cuttlebone showed excellent catalytic activity in the reduction of 2,4‐dinitrophenylhydrazine to 2,4‐diaminophenylhydrazine by sodium borohydride as the source of hydrogen at ambient condition. The catalyst could be separated and recycled up to five cycles with no loss of its activity.Inspec keywords: catalysis, catalysts, chemical engineering, palladium, nanoparticles, field emission electron microscopy, scanning electron microscopy, X‐ray diffraction, X‐ray chemical analysis, sodium compounds, ultraviolet spectroscopy, visible spectroscopyOther keywords: catalytic reduction, 2,4‐dinitrophenylhydrazine, cuttlebone, Conium maculatum leaf extract, green process, palladium nanoparticles, antioxidant content, field‐emission scanning electron microscopy, X‐ray diffraction, energy dispersive X‐ray spectroscopy, Fourier transform infrared, ultraviolet–visible spectroscopy, 2,4‐diaminophenylhydrazine, sodium borohydride     

Intelligent Firefly Algorithm Deep Transfer Learning Based COVID-19 Monitoring System

With the increasing and rapid growth rate of COVID-19 cases, the healthcare scheme of several developed countries have reached the point of collapse. An important and critical steps in fighting against COVID-19 is powerful screening of diseased patients, in such a way that positive patient can be treated and isolated. A chest radiology image-based diagnosis scheme might have several benefits over traditional approach. The accomplishment of artificial intelligence (AI) based techniques in automated diagnoses in the healthcare sector and rapid increase in COVID-19 cases have demanded the requirement of AI based automated diagnosis and recognition systems. This study develops an Intelligent Firefly Algorithm Deep Transfer Learning Based COVID-19 Monitoring System (IFFA-DTLMS). The proposed IFFA-DTLMS model majorly aims at identifying and categorizing the occurrence of COVID19 on chest radiographs. To attain this, the presented IFFA-DTLMS model primarily applies densely connected networks (DenseNet121) model to generate a collection of feature vectors. In addition, the firefly algorithm (FFA) is applied for the hyper parameter optimization of DenseNet121 model. Moreover, autoencoder-long short term memory (AE-LSTM) model is exploited for the classification and identification of COVID19. For ensuring the enhanced performance of the IFFA-DTLMS model, a wide-ranging experiments were performed and the results are reviewed under distinctive aspects. The experimental value reports the betterment of IFFA-DTLMS model over recent approaches.     

The performance of multiwavelets based OFDM system under different channel conditions

In wireless communication reception, the reliability of orthogonal frequency division multiplexing (OFDM) is limited because of the time-varying nature of the channel. This causes inter-carrier interference (ICI) and increases inaccuracies in channel tracking. This can effectively be avoided at the cost of power loss and bandwidth expansion by inserting a cyclic prefix guard interval before each block of parallel data symbols. However, this guard interval decreases the spectral efficiency of the OFDM system as the corresponding amount. Recently, it was found that based on Haar-orthonormal wavelets, discrete wavelet-based OFDM (DWT-OFDM) is capable of reducing the inter symbol interference (ISI) and ICI, which are caused by the loss in orthogonality between the carriers. DWT-OFDM can also support much higher spectrum efficiency than discrete Fourier-based OFDM (DFT-OFDM). In this paper the DFT-OFDM is replaced by Multiwavelets OFDM (DMWT-OFDM) in order to further reduce the level of interference and increase spectral efficiency. It is found that proposed Multiwavelet design achieves much lower bit error rates, increases signal to noise power ratio (SNR), and can be used as an alternative to the conventional OFDM. The proposed OFDM system was modeled tested, and its performance was found under different channel conditions.     

Analysis,modeling, and design of cascaded defected microstrip structure for planar circuits

In this article, two cascaded defected microstrip structures (CDMSs) are proposed to increase the effective inductance. So the cutoff frequencies of filters made by CDMSs can be controlled. The proposed CDMSs have wider stopband characteristic and sharper transition from passband to stopband than defected microstrip structure (DMS). To show the behavior variations of the effective inductance, the DMS and CDMSs have been analyzed, compared, and their design parameters are formulated. These parameters are necessary for a fast filter design procedure. Also, the models of DMS and CDMSs using the very simple lumped element forms are presented according to the physical parameters. The results of the proposed models have been compared with those obtained by full wave analysis. To verify the proposed DMS model, the comparison in response not only has been considered in amplitude but also in phase of all S‐parameters of proposed model and full wave analysis. It is obvious that the stopband is enhanced by periodically cascading the DMS. Surviving of EMC aspects between DMS, DGS, and CDMS is considered and compared. Finally, the theoretical results are validated by comparison with simulations of the structures and experimental results. The simulations from modeling results are found to be in good agreement with the full wave analysis and measurement results in the range of 0.5–35 GHz. © 2010 Wiley Periodicals, Inc. Int J RF and Microwave CAE, 2010.     

MobiEureka: an approach for enhancing the discovery of mobile web services

While several service discovery protocols and standards have been proposed for supporting service discovery from mobile devices, this remains a challenging problem. In many cases, mobile clients may discover services which they consider relevant but soon realize that such services are not completely usable on their mobile devices due to compatibility and interoperability issues. Without integrating device capabilities into the discovery process, or a device-aware mobile service discovery, it becomes extremely difficult to determine whether discovered services may or may not function properly within the device’s constraints. This paper introduces a solution known as MobiEureka, a mobile device-aware system for enhancing the discovery of mobile web services from mobile devices. Experimental validation, results, and analysis of the introduced ideas are discussed.     

Empirical comparison of three metrics suites for fault prediction in packages of object-oriented systems: A case study of Eclipse

Packages are important high-level organizational units for large object-oriented systems. Package-level metrics characterize the attributes of packages such as size, complexity, and coupling. There is a need for empirical evidence to support the collection of these metrics and using them as early indicators of some important external software quality attributes. In this paper, three suites of package-level metrics (Martin, MOOD and CK) are evaluated and compared empirically in predicting the number of pre-release faults and the number of post-release faults in packages. Eclipse, one of the largest open source systems, is used as a case study. The results indicate that the prediction models that are based on Martin suite are more accurate than those that are based on MOOD and CK suites across releases of Eclipse.     

Fuzzy logistic regression based on the least squares approach with application in clinical studies

To model fuzzy binary observations, a new model named “Fuzzy Logistic Regression” is proposed and discussed in this study. In fact, due to the vague nature of binary observations, no probability distribution can be considered for these data. Therefore, the ordinary logistic regression may not be appropriate. This study attempts to construct a fuzzy model based on possibility of success. These possibilities are defined by some linguistic terms such as …, low, medium, high…. Then, by use of the Extension principle, the logarithm transformation of “possibilistic odds” is modeled based on a set of crisp explanatory variables observations. Also, to estimate parameters in the proposed model, the least squares method in fuzzy linear regression is used. For evaluating the model, a criterion named the “capability index” is calculated. At the end, because of widespread applications of logistic regression in clinical studies and also, the abundance of vague observations in clinical diagnosis, the suspected cases to Systematic Lupus Erythematosus (SLE) disease is modeled based on some significant risk factors to detect the application of the model. The results showed that the proposed model could be a rational substituted model of an ordinary one in modeling the clinical vague status.     

Recognition of Arabic (Indian) bank check digits using log-gabor filters

In this paper we present a technique for the automatic recognition of Arabic (Indian) bank check digits based on features extracted by using the Log Gabor filters. The digits are classified by using the K-Nearest Neighbor (K-NN), Hidden Markov Models (HMM) and Support Vector Machines (SVM) classifiers. An extensive experimentation is conducted on the CENPARMI data, a database consisting of 7390 samples of Arabic (Indian) digits for training and 3035 samples for testing extracted from real bank checks. The data is normalized to a height of 64 pixels, maintaining the aspect ratio. Log Gabor filters with several scales and orientations are used. In addition, the filtered images are segmented into different region sizes for feature extraction. Recognition rates of 98.95%, 98.75%, 98.62%, 97.21% and 94.43% are achieved with SVM, 1-NN, 3-NN, HMM and NM classifiers, respectively. These results significantly outperform published work using the same database. The misclassified digits are evaluated subjectively and results indicate that human subjects misclassified 1/3 of these digits. The experimental results, including the subjective evaluation of misclassified digits, indicate the effectiveness of the selected Log Gabor filters parameters, the implemented image segmentation technique, and extracted features for practical recognition of Arabic (Indian) digits.     

Relaxed constraints support vector machines for noisy data

Real-world data collected for computer-based applications are frequently impure. Differentiation of outliers and noisy data from normal ones is a major task in data mining applications. On the other hand, elimination of noisy and outlier data from training samples of a dataset may lead to over-fitting or information loss. A fuzzy support vector machine (FSVM) provides an effective means to deal with this problem. It reduces the effect of the noisy data and outliers by using a fuzzy membership functions. In this paper, a new formation for SVMs is introduced that considers importance degrees for training samples. The constraints of the SVM are converted to fuzzy inequalities. The proposed method, RSVM, shows better efficiency in the classification of data in different domains. Especially, using the proposed RSVM for multi-class classification of arrhythmia disease is presented at the end of this paper as a practical case study to show the effectiveness of the proposed system.