基于都市发展阶段论的城市居住隔离研究

本文归纳并总结我国居住隔离研究的现状,从研究成果及应用性、研究层面及针对性和规划对策三方面评述居住隔离研究存在的问题,在此基础上引入并剖析都市发展阶段论与居住隔离的内在关联,结合我国城市化特点构建基于都市发展阶段论的居住隔离研究框架,探讨我国居住隔离问题的应对策略,并着重论述框架中各类居住隔离问题的混居措施。     

旋转采样机粒度偏析机理

本文建立了旋转类采样机包含皮带中部采样机、旋斗采样机、旋转缩分机、旋管缩分机的通用数学模型,推导了截取料流时的轨迹方程、速度方程、最大速度波动公式、最大面积波动公式,从数学分析角度阐述了粒度偏析机理,找到了减少粒度偏析及提高采样精度的有效途径。     

Preferred growth orientation and microsegregation behaviors of eutectic in a nickel-based single-crystal superalloy

Abstract

A nickel-based single-crystal superalloy was employed to investigate the preferred growth orientation behavior of the (γ + γ′) eutectic and the effect of these orientations on the segregation behavior. A novel solidification model for the eutectic island was proposed. At the beginning of the eutectic island’s crystallization, the core directly formed from the liquid by the eutectic reaction, and then preferably grew along [100] direction. The crystallization of the eutectic along [110] always lagged behind that in [100] direction. The eutectic growth in [100] direction terminated on impinging the edge of the dendrites or another eutectic island. The end of the eutectic island’s solidification terminates due to the encroachment of the eutectic liquid/solid interface at the dendrites or another eutectic island in [110] direction. The distribution of the alloying elements depended on the crystalline axis. The degree of the alloying elements’ segregation was lower along [100] than [110] direction with increasing distance from the eutectic island’s center.     

Enhancing Photovoltaic Performance Using an All‐Conjugated Random Copolymer to Tailor Bulk and Interfacial Morphology of the P3HT:ICBA Active Layer

Bulk heterojunction (BHJ) solar cells are fabricated using active material blends of poly(3‐hexylthiophene) (P3HT) donor, indene‐C₆₀ bisadduct (ICBA) acceptor, and an all‐conjugated random copolymer (RCP) additive. By optimizing RCP loading, power conversion efficiencies (PCEs) up to 20% higher than those of a binary P3HT:ICBA mixture are achieved. The improved device characteristics are rationalized in terms of the differences between the photoactive thin film morphologies. Energy‐filtered transmission electron micro­scopy reveals that incorporation of the RCP improves the degree of structural order of the BHJ fibrillar network and increases the extent of microphase separation between P3HT and ICBA. Additionally, a combination of atomic force microscopy and X‐ray photoelectron spectroscopy analysis indicates segregation of the RCP at the free interface, leading to a shift in the surface potentials measured by Kelvin probe force microscopy. These changes, both in the bulk morphology and in the interfacial composition/energetics, are correlated to improved carrier collection efficiency due to a reduction of non‐geminate recombination, which is measured by charge extraction of photo­generated carriers by linearly increasing voltage.     

Nanoscale synthesis and characterization of graphene-based objects

Abstract

Graphene-based nano-objects such as nanotrenches, nanowires, nanobelts and nanoscale superstructures have been grown by surface segregation and precipitation on carbon-doped mono- and polycrystalline nickel substrates in ultrahigh vacuum. The dominant morphologies of the nano-objects were nanowire and nanosheet. Nucleation of graphene sheets occurred at surface defects such as step edges and resulted in the directional growth of nanowires. Surface analysis by scanning tunneling microscopy (STM) has clarified the structure and functionality of the novel nano-objects at atomic resolution. Nanobelts were detected consisting of bilayer graphene sheets with a nanoscale width and a length of several microns. Moiré patterns and one-dimensional reconstruction were observed on multilayer graphite terraces. As a useful functionality, application to repairable high-resolution STM probes is demonstrated.     

X52管线钢抗氢致开裂试验裂纹成因分析

针对某段时期出现的X52管线钢产品经抗阶梯型破裂试验后,试样有明显阶梯裂纹,产品检验不合格的问题,对不合格批次的试样进行化学成分、炼钢工艺以及显微组织等方面的分析,分析了该抗硫化氢腐蚀X52管线钢氢致开裂的原因。结果表明:开裂批次试样的钙硫含量比值偏低,导致出现夹杂物偏聚和中心偏析,且夹杂物呈线状分布,是造成该管线钢产品抗氢致开裂试验开裂的主要原因。最后对X52管线钢的生产控制要点提出了相应建议,以提高其抗硫化氢腐蚀的能力。     

Research of the Continuous Casting Slab Transverse Cracking During Retarded Cooling Process

In this paper, the reason of 50Mn2V transverse cracking is studied by optical metallographic, SEM and in situ analysis system. Results show that the pearlite is surrounded by the net‐like pro‐eutectoid ferrite which locates at the former austenite grain boundary, the hydrogen content (ca.2 × 10^?4 wt%) exceeds the critical solubility in room temperature structure, divers types, and sizes inclusions (10–100 µm), plenty of fissures (2–50 µm) and classical cleavage fracture surface are obviously observed, meanwhile, a great degree of elements segregation (P, S, V, Ni, Cr correspond to 1.757, 1.674, 1.729, 1.475, 1.195, respectively) and a poorly 0.9283 integral density exist in this blank. From the above, internal gas pressure should be the dominant factor that leads the transverse embrittlement, while internal stresses, element segregation, and defects play an ancillary role.     

Key factors affecting nickel recovery during the segregation of laterite ores

The segregation process as applied to nickel laterite ores involves the formation of gaseous nickel and iron chlorides which are subsequently reduced to form ferronickel on the surface of a solid carbon reductant. A fundamental study of the process has been carried out using limonite, nontronite and garnierite ores. The study highlighted the significant impacts that ore mineralogy and carbon addition have on the amount of nickel which is segregated rather than retained within the ore due to in situ reduction. These important aspects affecting nickel recovery and the success of the process are discussed in this paper.     

Microstructure and mechanical properties of in-situ MC-carbide particulates-reinforced refractory high-entropy Mo0.5NbHf0.5ZrTi matrix alloy composite

Refractory high-entropy Mo_0.5NbHf_0.5ZrTi alloy matrix composite with MC-carbide particulates-reinforced was prepared by arc melting. It is found that Mo_0.5NbHf_0.5ZrTiC_0.1 and Mo_0.5NbHf_0.5ZrTiC_0.3 alloys consist of one disordered body-centered cubic (BCC) solid solution phase as the matrix phase and MC carbide phase. MC carbide is enriched with Zr and Hf due to the higher binding strength and without any Mo. Noticeable strengthening from the carbide is not observed for C_0.1 and C_0.3 alloys while the compressive plasticity is improved slightly due to the decrease of solution strengthening for the matrix BCC disordered solid solution phase.