Analysis of trace mercury in water by solid phase extraction using dithizone modified nanometer titanium dioxide and cold vapor atomic absorption spectrometry

A new method for analysis of trace mercury in water samples was developed, based on the combination of preconcentration/separation using dithizone-modified nanometer titanium dioxide (TiO2) as a solid phase extractant and determination by cold vapor atomic adsorption spectrometry (CVAAS). Dithizone was dissolved with alcohol and loaded on the surface of nano-sized TiO2 powders by stirring. The static adsorption behavior of Hg2 on the dithizone-modified nanoparticles was investigated in detail. It was found that excellent adsorption ratio for Hg2 could be obtained in the pH range of 7-8 with an oscillation time of 15 min, and a 5 mL of 3.5 mol·L-1 HCl solution could quantitatively elute Hg2 from nanometer TiO2 powder. Common coexisting ions caused no obvious influence on the determination of mercury. The mechanisms for the adsorption and desorption were discussed. The detection limit (3σ) for Hg2 was calculated to be 5 ng·L-1. The proposed method was applied to the determination of Hg2 in a mineral water sample and a Zhujiang River water sample. By the standard addition method, the average recoveries were found to be 94.4%-108.3% with RSD (n = 5) of 2.9%-3.5%.     

附加励磁阻尼控制抑制次同步谐振研究

基于阻尼特性分析对抑制次同步振荡的附加励磁系统阻尼控制器（SEDC）进行了详细研究。首先基于IEEE次同步谐振第一标准测试系统及IEEE ST1A型励磁系统设计相应的SEDC。采用测试信号法，通过计算发电机组的次同步电气阻尼特性，分析所设计的SEDC对发电机组次同步振荡的抑制效果。结果表明，SEDC在不采用带通滤波器的方式下，将转速偏差经适当移相及放大，通过对励磁电压的调节，可以提供足够的阻尼转矩抑制次同步谐振;采用带通滤波器可大大提高通带频率对应的电气阻尼，同时对多个模态采用带通滤波，可以同时提高各个扭振频率处的电气阻尼，有利于次同步谐振的抑制。     

录像机伺服系统

该文主要论述了录像机的伺服系统，包括带盘伺服，鼓伺服，主导轴伺服的工作原理。     

用AD8302实现幅相测量系统

本文介绍了用于RF/IF幅度和相位测量的新型芯片AD8302的功能及特点,并给出了此芯片在实际工作中的两种典型应用。     

直流无刷电机定子三次谐波反电势的过零检测及其相位修正

针对方波直流无刷电机无位置传感器的控制，介绍了采用定子三次谐波法换相的原理及实现方法，并通过实验仿真的方法证明了其可行性。     

一种新的混合相位反褶积方法

在地震资料处理中,常用预测反褶积方法提高地震资料的分辨率,它具有两个基本的假设条件:①地震子波是最小相位;②反射系数序列是随机过程。上述假设条件与实际地震子波的混合相位存在较大差别。为此,笔者在借鉴前人研究的基础上,提出了一种新的混合相位反褶积方法。其实现过程为:①根据地震记录的自相关和地震子波自相关之间的关系,由最小二乘法拟合出地震子波的振幅谱,进而计算出地震子波的自相关;②利用计算出来的地震子波自相关设计一个最小相位滤波器,然后加一个延迟量于自相关函数的主对角线上,将最小相位反滤波器分解为一个长度很短的滤波器,再与一个长度较长的滤波器进行褶积,可得到一系列的混合相位子波和混合相位滤波器;③将得到的混合相位滤波器和原始地震道进行褶积,选取一定的判别准则,以选出最佳的混合相位滤波器以及相应的混合相位子波。通过模型试算和实际资料处理可知,分时窗反褶积的效果要好于单时窗反褶积,混合相位反褶积效果好于最小相位反褶积。在分时窗求取地震子波时,为了得到更好的反褶积效果,要注意时窗宽度与算子长度之间的关系。     

平滑相位的π/4DQPSK调制及其在移动通信系统中的应用

本文详细介绍了一种新型π/ 4DQPSK调制解调方法 ,该方法将π/ 4DQPSK调制中的相位跳变改为平滑变化。仿真实验表明 ,与普通的π/ 4DQPSK相比 ,该方法使高次谐波分量大幅下降 ,可以有效降低功耗 ,压缩频带宽度。     

光纤陀螺数字闭环处理技术

介绍了光纤陀螺的原理，给出了一种新型的全数字光纤陀螺闭环检测方案－数字相位斜波技术，讨论了该方案的电路设计及与调测。     

STUDY ON PHASE PERCEPTION IN SPEECH

The perceptual effect of the phase information in speech has been studied by auditory subjective tests. On the condition that the phase spectrum in speech is changed while amplitude spectrum is unchanged, the tests show that: (1) If the envelop of the reconstructed speech signal is unchanged, there is indistinctive auditory perception between the original speech and the reconstructed speech; (2) The auditory perception effect of the reconstructed speech mainly lies on the amplitude of the derivative of the additive phase; (3) td is the maximum relative time shift between different frequency components of the reconstructed speech signal. The speech quality is excellent while td <10ms; good while 10ms< td <20ms; common while 20ms< td <35ms, and poor while td >35ms.     

线性相位FIR滤波器的设计

论述用软件来实现线性相位ＦＩＲ数字滤波器的方法。先推导线性相移ＦＩＲ滤波器要满足的条件，说明当ｈ（ｎ）为偶对称或奇对称时，都能具有严格的线性相位。为达到这个目的，采用了将无限长序列变为有限长序以及将非因果序列变为因果序列的设计思想，并给出了设计实例，最后讨论了改善频率特性的主要途径。实践证明，这种设计方法简单，方便实用。