Recycling of inorganic waste in monolithic and cellular glass‐based materials for structural and functional applications

The stabilization of inorganic waste of various nature and origin, in glasses, has been a key strategy for environmental protection for the last decades. When properly formulated, glasses may retain many inorganic contaminants permanently, but it must be acknowledged that some criticism remains, mainly concerning costs and energy use. As a consequence, the sustainability of vitrification largely relies on the conversion of waste glasses into new, usable and marketable glass‐based materials, in the form of monolithic and cellular glass‐ceramics. The effective conversion in turn depends on the simultaneous control of both starting materials and manufacturing processes. While silica‐rich waste favours the obtainment of glass, iron‐rich wastes affect the functionalities, influencing the porosity in cellular glass‐based materials as well as catalytic, magnetic, optical and electrical properties. Engineered formulations may lead to important reductions of processing times and temperatures, in the transformation of waste‐derived glasses into glass‐ceramics, or even bring interesting shortcuts. Direct sintering of wastes, combined with recycled glasses, as an example, has been proven as a valid low‐cost alternative for glass‐ceramic manufacturing, for wastes with limited hazardousness. The present paper is aimed at providing an up‐to‐date overview of the correlation between formulations, manufacturing technologies and properties of most recent waste‐derived, glass‐based materials. © 2016 The Authors. Journal of Chemical Technology & Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.     

Effects of blended vegetable‐based cutting fluids with extreme pressure on tool wear and force components in turning of Al 7075‐T6

In this study, performances of four different types of vegetable‐based cutting fluids (VBCFs) over a commercial mineral cutting fluid were evaluated for machinability of Al 7075‐T6. Lubrication properties of VBCFs were improved with additive of extreme pressure. Cutting force and tool wear data were obtained for performance analyses of cutting fluids during longitudinal turning of Al 7075‐T6. Cutting, feed and radial forces indicated 1.70–38.25% improvements for VBCFs over the commercial mineral cutting fluid. The lowest average values of flank and nose wears obtained with blended cutting fluid containing 12% of extreme pressure were 0.09 and 0.10 mm, respectively, whereas these values for the commercial mineral cutting fluid were 0.18 and 0.15 mm. The scanning electron microscope results showed adherence of workpiece material occurred on rake and flank faces, and flank and nose wears were the dominant wear modes. It was found that performances of VBCFs during turning of Al 7075‐T6 were better than that of the commercial mineral cutting fluid. Copyright © 2012 John Wiley & Sons, Ltd.     

Some physical properties of ZnO thin films prepared by RF sputtering technique

ZnO thin films were deposited with RF sputtering using pure Zn target. In order to generate oxidation process of Zn, Ar:O₂ gas mixing in (9:1), (7:3) and (5:5) ratios of Ar:O₂ was used. To characterize ZnO thin films thickness and transparency were measured using optical method, and refractive index and band gap energies were calculated. Electrical conductivity of the ZnO thin films was also determined. AFM images were used to determine surface morphology of produced ZnO thin films.     

Thermodynamic analysis of an existing coal-fired power plant for district heating/cooling application

In a conventional coal-fired power plant, which is only designed for electricity generation, 2/3 of fuel energy is wasted through stack gases and cooling water of condensers. This waste energy could be recovered by trigeneration; modifying the plants in order to meet district heating/cooling demand of their locations. In this paper, thermodynamical analysis of trigeneration conversion of a public coal-fired power plant, which is designed only for electricity generation, has been carried out. Waste heat potentials and other heat extraction capabilities have been evaluated. Best effective steam extraction point for district heating/cooling system; have been identified by conducting energetic and exergetic performance analyses. Analyses results revealed that the low-pressure turbine inlet stage is the most convenient point for steam extraction for the plant analyzed.     

Probabilistic Model for the Assessment of Cyclically Induced Reconsolidation (Volumetric) Settlements

A maximum likelihood framework for the probabilistic assessment of cyclically induced reconsolidation settlements of saturated cohesionless soil sites is described. For this purpose, over 200 case history sites were carefully studied. After screening for data quality and completeness, the resulting database is composed of 49 high-quality, cyclically induced ground settlement case histories from seven different earthquakes. For these case history sites, settlement predictions by currently available methods of Tokimatsu and Seed (1984), Ishihara and Yoshimine (1992), Shamoto et al. (1998), and Wu and Seed (2004) are presented comparatively, along with the predictions of the proposed probabilistic model. As an integral part of the proposed model, the volumetric strain correlation presented in the companion paper is used. The accuracy of the mean predictions as well as their uncertainty is assessed by both linear regression and maximum likelihood methodologies. The analyses results revealed that (1) the predictions of Shamoto et al. and Tokimatsu and Seed are smaller than the actual settlements and need to be calibrated by a factor of 1.93 and 1.45, respectively; and (2) Ishihara and Yoshimine, and Wu and Seed predictions are higher than the actual settlements and need to be calibrated by a factor of 0.90 and 0.98, respectively. The Wu and Seed procedure produced the most unbiased estimates of mean settlements [i.e., their calibration coefficient (0.98) is the closest to unity], but the uncertainty (scatter) of their predictions remains high as revealed by the second to last smaller R2 value, or relatively higher standard deviation (σε) of the model error. In addition to superior model predictions, the main advantage of the proposed methodology is the probabilistic nature of the calibration scheme, which enables incorporation of the model uncertainty into mean settlement predictions. To illustrate the potential use of the proposed model, the probability of cyclically induced reconsolidation settlement of a site after a scenario earthquake to be less than a threshold settlement level is assessed.     

Technetium-99m-MIBI scintigraphy in pulmonary tuberculosis

The acute phase plasma protein ceruloplasmin (Cp) appears to play some role in host defense. The possibility that production of Cp in extrahepatic sites may also be essential for the activation, effector functions and cytoprotection of immune cells in localized environments has received minimal attention. Here, we have surveyed various types of human and rat immune cells for the presence of Cp mRNA using RT-PCR with primers that span exons 17-19 as an initial step in addressing this possibility. Validated Cp RT-PCR bands were obtained from RNA samples isolated from resting and activated human lymphocytes, CD4 and CD8 T-cells and B-cells. Semiquantitative RT-PCR indicated that Cp mRNA in immune cells is present at about 0.2% the level of Cp mRNA in HepG-2 human liver cell line. Various human cell lines derived from the immune system, rat splenic MNC and purified rat T-lymphocytes also constitutively express Cp gene.     

Effects of nimodipine and isradipine on endothelin-1-induced contraction of pregnant rat myometrium

Bladder malignancy in the renal transplant recipient is an infrequent occurrence. The 11 previously reported cases reflect an aggressive tumor growth with invasion, requiring partial or complete cystectomy with or without conduit diversion. We report an additional case in a 40-yr-old woman with a living related renal transplant, who experienced rapid progression of her tumor over 3 wk from initial hematuria to a pelvic mass involving the anterior bladder. Her allograft ureter and native ureters, as well as her left iliac vein, became obstructed with tumor in another 2 wk. Biopsy showed poorly differentiated, invasive transitional carcinoma. Attempted resection was abandoned because of finding tumor involvement in most of the pelvis. Chemotherapy was not attempted. She died 2 wk after her attempted resection from tumor burden. Our report presents a collective review of these previously reported 11 cases plus our case. These bladder tumors demonstrate a rapid progression of invasive disease and respond poorly to chemotherapy. There is a possible association of bladder tumors with cyclophosphamide immunosuppression. An aggressive surgical approach should be followed, especially since these tumors present in a younger age group.     

Probabilistic models for the initiation of seismic soil liquefaction

A Bayesian framework for probabilistic assessment of the initiation of seismic soil liquefaction is described. A database, consisting of post-earthquake field observations of soil performance, in conjunction with in situ “index” test results is used for the development of probabilistically-based seismic soil liquefaction initiation correlations. The proposed stochastic model allows full and consistent representation of all relevant uncertainties. including (a) measurement/estimation errors, (b) model imperfection, (c) statistical uncertainty, and (d) inherent variabilities. Different sets of probabilistic liquefaction boundary curves are developed for the seismic soil liquefaction initiation hazard problem, representing various sources of uncertainty that are intrinsic to the problem. The resulting correlations represent a significant improvement over prior efforts, producing predictive relationships with enhanced accuracy and greatly reduced overall model uncertainty.     

Standard Penetration Test-Based Probabilistic and Deterministic Assessment of Seismic Soil Liquefaction Potential

This paper presents new correlations for assessment of the likelihood of initiation (or “triggering”) of soil liquefaction. These new correlations eliminate several sources of bias intrinsic to previous, similar correlations, and provide greatly reduced overall uncertainty and variance. Key elements in the development of these new correlations are (1) accumulation of a significantly expanded database of field performance case histories; (2) use of improved knowledge and understanding of factors affecting interpretation of standard penetration test data; (3) incorporation of improved understanding of factors affecting site-specific earthquake ground motions (including directivity effects, site-specific response, etc.); (4) use of improved methods for assessment of in situ cyclic shear stress ratio; (5) screening of field data case histories on a quality/uncertainty basis; and (6) use of high-order probabilistic tools (Bayesian updating). The resulting relationships not only provide greatly reduced uncertainty, they also help to resolve a number of corollary issues that have long been difficult and controversial including: (1) magnitude-correlated duration weighting factors, (2) adjustments for fines content, and (3) corrections for overburden stress.     

In situ stabilization of chromium(VI) in polluted soils using organic ligands: the role of galacturonic, glucuronic and alginic acids

Laboratory batch sorption and column experiments were performed to investigate the role of organic ligands such as galacturonic, glucuronic and alginic acids (main constituents of bacterial exopolymeric substances (EPS)) on Cr(VI) uptake and transport in heterogeneous subsurface media. Our batch sorption experiments demonstrate the addition of galacturonic, glucuronic and alginic acids to soils enhances Cr(VI) uptake by soil at pH values <7.7 depending on the concentration of the ligand and pH used. The enhanced Cr(VI) uptake at pH values <7.7 may be explained through either the catalytic reduction of Cr(VI) to Cr(III) by the surface-bound organic matter/Fe oxides and/or the dissolved metal ions (e.g., Fe(III)) from the soil. On the other hand, organic ligands have no or little effect on Cr(VI) uptake under highly alkaline pH conditions since the catalytic Cr(VI) reduction decreases with increasing pH. Similarly, the results from column experiments show that, depending on the concentration of organic ligands, the Cr(VI) breakthrough curves were significantly retarded relative to the organic acid-free systems at pH 7.6. A significant portion of Cr(VI) initially added to the feed solution was not readily recoverable in the effluent, indicating Cr(VI) reduction in columns, most probably catalyzed by surface-bound metal-oxides (e.g., Fe oxides) or dissolved metal ions such as Fe(II; III). The overall results suggest that EPS constituents such as glucuronic, galacturonic and alginic acids may play a significant role on Cr(VI) stabilization in subsurface systems under acidic to slightly alkaline pH conditions.