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71.
72.
A planar, interdigitated, integrated device structure is described whose characteristics show a voltage controlled negative resistance between two of its terminals. This negative resistance can be controlled by the applied bias to a third terminal. Devices have been fabricated with this structure to achieve negative resistance values ranging from a few hundred thousand ohms down to less than a hundred ohms. The physical mechanisms that give rise to this negative resistance are described and a dc analysis of its behavior is presented. The analysis shows excellent agreement with the observed device characteristics.  相似文献   
73.
A first-order Markov process is used to model the sequence of quantization noise samples in delta modulation. An autocorrelation parameterCin the Markov model controls the shape of the noise spectrum, and asCdecreases from 1 to 0 and then to -1, the spectrum changes from a low-pass to a flat, and then to a high-pass characteristic. One can also use the Markov model to predict the so-called out-of-band noise rejection that is obtained when delta modulation is performed with an oversampled input, and the resulting quantization noise is lowpass filtered to the input band. The noise rejectionGis a function ofCas well as an oversampling factorFand an interesting asymptotic result is thatG=frac{1-C}{1+C} dot FifF gg frac{1+C}{1-C} dot frac{pi}{2}. Delta modulation literature has noted the importance of the specialGvalues,Fand2F. These correspond to autocorrelation values of 0 and -1/3.  相似文献   
74.
Consider the delta-modulation (DM) of a first-order Gauss-Markov signalX. Let the adjacent-sample correlation inXbec, and let the (first-order) DM predictor coefficient bea. We express the quantizer input Qrin the form[S_{r} - aE_{r - 1} + (c - a)X_{r - 1}], where Sris an "innovations" term,aE_{r - 1}denotes the effect of quantizationerror(E)feedback and(c - a)X_{r - 1}reflects the effect of using ana neq c. For the important case ofc rightarrow 1(which models over-sampled DM inputs), we propose the simplifying assumption [7] of uncorrelatedXandE; with this assumption, our formalization of quantizer input leads very simply to interesting results in linear (LDM) and adaptive delta modulation (ADM). The LDM results are generalizations of known expressions for optimum values ofa, and the step-size Δ, and the value of signal-to-noise ratio SNR. For ADM, we derive optimum multiplier values for step-size adaptations with a one-bit memory, using the case ofc sim a = 1for simplicity. Our results depend on modeling instantaneous step-size adaptation as a mechanism for tracking the expected magnitude ofQ; existing literature has formalized such adaptation models only for the case of multi-bit quantizers.  相似文献   
75.
    
BACKGROUND: Disposal of large amounts of recurring industrial waste lignin is a big problem for the paper industries and there is need for a rational alternative to utilize this waste lignin. Thus highly porous activated carbons (ACs) were prepared from lignin using H3PO4 as an activating chemical with and without microwave treatment in a self‐generated environment at 600 °C and the influence of different types of impregnation on the adsorption–desorption capacities of endosulfan from a liquid phase was studied. RESULT: The maximum adsorption capacities (Xm) for ACs prepared by a microwave treatment and using a simple impregnation method were 6.2422 mg g?1 and 3.9557 mg g?1, respectively. Equilibrium adsorption time determined from kinetic experiments was 5 h and the experimental kinetic data were described by a pseudo‐second‐order rate model. Surface characteristics and desorption patterns showed considerable difference between the two ACs with the microwave treated AC showing less hysteresis, greater Xm and established overall superiority over the other. CONCLUSION: Use of microwave treatment produced more oxygen surface functional groups. Results indicate that surface chemistry of the microwave treated sample is more important than the textural properties for the higher adsorption of endosulfan. The microwave treated sample also resulted in less hysteresis and fewer carbonyl surface groups. Desorption patterns cannot be predicted from adsorption alone. Copyright © 2011 Society of Chemical Industry  相似文献   
76.
    
The fundamental properties of pure poly(3,4-thylenedioxythiophene) (PEDOT), one of the most common electrically conducting organic polymers, are the key to the development of more prominent applications in which PEDOT and its derivatives can be utilized. Conducting molecular complex of PEDOT with silica was synthesized in the presence of charged silica template by the in situ biomimetic polymerization. To remove silica from PEDOT/template complex, hydrofluoric acid was used to etch silica particles. The electrochemical, thermal, and optical properties of pure PEDOT recovered were investigated in comparison with those of EDOT monomer or PEDOT with template by using UV–vis–near–IR spectra, cyclic voltammetry, thermogravimetric analysis, and fluorescence spectra. POLYM. ENG. SCI., 47:71–75, 2007. © 2006 Society of Plastics Engineers  相似文献   
77.
    
A commercial acrylic fiber with 92% (w/w) acrylonitrile content was partially hydrolyzed converting a fraction of the nitrile (? CN) groups to carboxylic acid (? COOH) groups, to coat the fiber with polyethylenimine (PEI) resin, which was then crosslinked with glutaraldehyde and further quaternized with ethyl chloroacetate to produce a novel strong‐base anionic exchanger in the form of fiber. Designated as PAN(QPEI.XG)(Cl?), the fibrous sorbent was compared with a commercial bead‐form resin Amberlite IRA‐458(Cl?) in respect of sorption capacity, selectivity, and kinetics for removal of silver thiosulfate complexes from aqueous solutions. Though the saturation level of [Ag(S2O3)2]3? on PAN(QPEI.XG)(Cl?) is considerably less than that on IRA‐458(Cl?), the gel‐coated fibrous sorbent exhibits, as compared to the bead‐form sorbent, a significantly higher sorption selectivity for the silver thiosulfate complex in the presence of excess of other anions such as S2O32?, SO42?, and Cl?, and a remarkably faster rate of both sorption and stripping. The initial uptake of the sorbate by the fibrous sorbent is nearly instantaneous, reaching up to ~80% of the saturation capacity within 10 s, as compared to only ~12% on the bead‐form sorbent. The high initial rate of uptake fits a shell‐core kinetic model for sorption on fiber of cylindrical geometry. With 4M HCl, the stripping of the sorbed silver complex from the fibrous sorbent is clean and nearly instantaneous, while, in contrast, a much slower rate of stripping on the bead‐form sorbent leads to its fouling due to a slow decomposition of the silver thiosulfate complex in the acidic medium. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2604–2613, 2006  相似文献   
78.
    
Unusually photoluminescent undoped oligomers and doped electrically conducting polymers of 4‐(3‐Pyrrolyl)butyric acid have been enzymatically synthesized using the oxidoreductase soybean peroxidase as a catalyst. This biocatalytic approach provides a direct route to a fluorescent‐undoped oligomer of pyrrole that requires no protection/deprotection chemistry. The synthesis is carried out in aqueous media that requires only monomer, enzyme, and hydrogen peroxide. The undoped oligomer exhibits stable emission properties and is highly sensitive to the presence of environmentally important metal ions, such as Co(II), Hg(II), and Cu(II) in solution. Electrically conducting polymers can also be obtained by adding a dopant to a buffered reaction solution prior to initiating the polymerization. Polymers doped with camphor‐10‐sulfonic acid exhibit conductivity values as high as 10?2 S/cm. Additionally, polymers synthesized in the presence of a biobased cationic template, N,N,N‐trimethylchitosan chloride, exhibit conductivity values that are an order of magnitude greater than polymers synthesized with the anionic polymeric template, poly(styrene sulfonic acid)‐sodium salt. The biobased synthetic strategy described here is the first report of directly obtaining an undoped, fluorescent conjugated oligomer of a pyrrole in aqueous solution. Unlike conventional chemical catalysts, the enzyme does not dope the oligomer and therefore provides the opportunity to directly obtain fluorescent conjugated species. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 41035.  相似文献   
79.
Analytical solutions for the breakdown voltage of abrupt cylindrical and spherical junctions have been obtained, using suitable approximations for the electric field in the depletion layer. These solutions are shown to be within ±1% of exact computer solutions for doping densities of less thant 1016 cm?1. By normalization to the parallel plane case, these solutions have been presented in a form which allows the computation of the breakdown voltage of both cylindrical and spherical junctions using a single curve for each situation.  相似文献   
80.
Advances in MOS devices on silicon carbide (SiC) have been greatly hampered by the low inversion layer mobilities. In this paper, the electrical characteristics of lateral n-channel MOSFETs fabricated on 4H-SiC are reported for the first time. Inversion layer electron mobilities of 165 cm2/V·s in 4H-SiC MOSFETs were measured at room temperature. These MOSFETs were fabricated using a low temperature deposited oxide, with subsequent oxidation anneal, as the gate dielectric  相似文献   
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