石油液化气瓶炸裂原因分析

利用扫描电子显微镜和光学金相显微镜,对15MnHP钢石油液化气钢瓶炸裂断面和组织特征进行了观察与分析.研究认为由于所使用的15MnHP钢中存在典型的磷偏析带,导致了气瓶瓶身脆性开裂现象.     

Electromagnetic torque detecting for optimization of in-mould electromagnetic stirring in the billet and bloom continuous casting

ABSTRACT

In this paper, an electromagnetic torque device based on the theoretical model was established to determine the optimum frequency accurately and conveniently in billet and bloom continuous casting with in-mould electromagnetic stirring (M-EMS). Magnetic characteristics with M-EMS was investigated by numerical simulation and physical experiment with the application of electromagnetic torque device and gauss meter. In addition, the effects of stirring frequency with M-EMS on macro segregation and equiaxed crystal ratio were compared and analysed for 55SiCr with 150?mm?×?150?mm billet caster and BU with 310?×?360?mm bloom caster by a series of plant trials, respectively. The results showed that maximum magnetic flux density and maximum electromagnetic torque occurred with different frequency and same current in M-EMS, and central equiaxed crystal ratio and macro segregation has been significantly improved by optimum frequency with M-EMS.     

厚规格调质高强度船板心部冲击不合格原因分析

为找出厚规格调质高强度船板心部冲击不合格的原因,通过光谱仪、显微镜、SEM-EDS能谱仪等仪器,对心部试样的成分、组织进行分析,结果表明:心部冲击不合格的原因是中心偏析带上存在大尺寸MnS夹杂与Nb、Ti的夹杂物,以及较多Al2O3夹杂和Mg、Ca等外来夹杂物.分析认为,通过提高钢水洁净度,避免钢水二次氧化污染,控制钢...     

C晶界偏析对α-Fe纳米晶高温力学性能的影响

纳米晶在常温下具有很高的强度,然而其高温力学性能往往低于其对应粗晶.C是钢中的重要成分,由于其原子半径较小,容易在纳米晶中发生晶界偏析.通过分子动力学模拟,探讨了利用C的晶界偏析来提升纳米晶高温力学性能的可能性.在不同温度和应力水平下模拟了Fe-C与纯Fe纳米晶的拉伸蠕变试验,得到对应的应变速率,并根据Mukherje...     

Promotion through gas phase induced surface segregation: methanol synthesis from CO, CO2 and H2 over Ni/Cu(100)

We have studied the rate of methanol formation over Cu(100) and Ni/Cu(100) from various mixtures of CO, CO₂ and H₂. It is found that the presence of submonolayer quantities of Ni leads to a strong increase in the rate of methanol formation from mixtures containing all three components whereas Ni does not influence the rate from mixtures of CO₂/H₂ and CO/H₂, respectively. The influence of the partial pressures of CO and CO₂ on the rate indicates that the role of CO is strictly promoting. From temperature-programmed desorption spectra it follows that the surface concentration of Ni depends strongly on the partial pressure of CO. In this way the increase in reactivity is interpreted as a CO-induced structural promotion introduced by the stronger bonding of CO to Ni as compared to Cu. It is suggested that this type of promotional behavior will be of general importance in existent catalysts and perhaps even more relevant in the development of new or improved bimetallic catalysts. This revised version was published online in July 2006 with corrections to the Cover Date.     

串罐式无钟高炉炉顶炉料运动的离散元分析

建立了串罐式无钟炉顶装料系统全模型,应用离散单元法对炉料从皮带到炉喉运动的全过程进行数值计算,考察了皮带上上下料罐内的粒度偏析,对比了料罐内是否安装石盒对料罐内炉料分布、料罐装料和卸料时炉料运动及布料时料流粒度变化的影响. 结果表明,皮带上小颗粒向料层下部渗透,皮带末端料层下部平均粒度比上部小. 炉料沿上料罐周向、径向和纵向存在粒度偏析;沿下料罐径向和纵向存在粒度偏析,周向上分布较均匀,相对粒度变化的标准差为0.03. 料罐内安装石盒对周向和纵向粒度分布影响较小,石盒附近小颗粒渗透影响径向粒度分布,料面基本水平,料罐卸料呈活塞流;无石盒时料面形成堆尖,料罐卸料呈漏斗流. 布料时料流粒度变化受料罐内料流运动和炉料分布影响,料罐内不安装石盒时料流粒度变化的标准差为7.15,安装石盒时为10.42,料流粒度变化更明显.     

碘化物-碘酸盐体系离集指数计算式的修正

从1953年Danckwerts提出离集的概念到现在,微观混合研究已有50多年的历史．所谓微观混合是指分子尺度上的均匀化过程,即通过破碎和变形使未混合的液体微元尺度减小,再由分子扩散达到最后混合．由于缺乏足够的分辨率,以物理现象为基础的方法难以满足微观混合研究的需要,因此采用化学反应作为分子探头的化学方法就成了目前最常用的研究微观混合的方法．这些反应可以分为3类：     

高强轻集料混凝土工作性能优化的试验研究

以分层度、坍落度、扩展度为新拌混凝土工作性能的评价指标,研究了矿物掺合料、砂率、增粘剂和减水剂对高强轻集料混凝土(LWAC)工作性能的影响.结果表明:增粘剂、减水剂是影响LWAC工作性能的主要因素,矿物掺合料、砂率对LWAC工作性能的影响则较小;在相同条件下,复掺减水剂和增粘剂比单掺减水剂更能改善轻集料混凝土的匀质性,同时对抗压强度也有所提高.最后提出了高强轻集料混凝土工作性能优化的试验配合比.