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La_(1-x)Ce_xMnO_3微波吸收特性 总被引:1,自引:0,他引:1
用溶胶-凝胶法制备了La1-xCexMnO3(x=0.1,0.2,0.3,0.4,0.5)样品,用微波矢量网络分析仪测试了该样品在2~18 GHz微波频率范围的复介电常数、复磁导率,根据测量数据计算了电磁损耗角正切及微波反射率与频率的关系.结果表明,在x=0.4时,样品微波吸收效果最好.当样品厚度为2.20 mm、x=0.4时,吸收峰值为27 dB,10 dB以上频带宽度达3.2 GHz.初步探讨了该材料的电磁损耗机理,发现损耗吸收来自磁损耗和介电损耗的共同作用,吸收峰所在频率介于介电损耗角正切最大值与磁损耗角正切最大值对应的频率之间,即在13.2 GHz附近.对样品的电阻率测试表明,其室温范围内电导在半导体范围内,有利于降低微波在样品表面的反射率. 相似文献
94.
PAN-based graphite felt (PGF) treated in 98% sulphuric acid for 5 h and then kept at 450 ℃ for 2 h was evaluated for their electrochemical performance as electrodes of vanadium redox battery (VRB). Structure and characteristic of treated PAN-based graphite felt (TPGF) were determined by means of Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy, Brunauer-Emmett-Teller surface area analysis and VRB test system. The results show that the acid and heat synergistic effect increase the number of —COOH functional groups on the PGF surface, and the PGF is eroded by sulphuric acid oxidation, resulting in the surface area increases from 0.31 m2/g to 0.45 m2/g. The V(Ⅱ)/V(Ⅲ) redox reaction is electrochemically reversible on the TPGF electrode, while the V(Ⅳ)/V(Ⅴ) couple is a quasi reversible process. The diffusion coefficients of the oxidation for V(Ⅳ)/V(Ⅴ) obtained from the scope of peak current Ip vs scan rate v1/2 is 4.4×10-5 cm2/s. The improvement of electrochemical activity for the electrode is mainly ascribed to the increase of the number of —COOH groups on the TPGF, which behaves as active sites catalyzing the vanadium species reactions and accelerating electron transfer reaction and oxygen transfer. 相似文献
95.
A series of Eu( Ⅲ)/Y(Ⅲ) complexes of terephthalic acid(TPA) with 2-thenoyltrifluoroacetone(HTTA) and trioctylphosphine oxide(TPPO) were synthesized. Compositions of these complexes are revealed to be Eu2(1-x)Y2x(TPA)(TTA)4- (TPPO)4 or EU1-xYx(TPA)(TTA)(TPPO)2. Their 1R spectra, fluorescent spectra and the thermal and optical stability were studied. The fluorescent excitation spectra of these complexes show more broad excitation bands than those of Eu2(TPA)3(TPPO)4 and Eu(TTA)3(TPPO)2 corresponding to their formations. In addition, both the binuclear complex EuY(TPA)(TTA)4(TPPO)4 and the chain complex EU0.4Y0.6(TPA)(TTA)(TPPO)2 present higher thermal stability and better optical stability than the mononuclear complex Eu(TTA)3(TPPO)2 does. And their thermal and optical stabilities are preferably interpreted from the binuclear structure together with the chain polynuclear structure of the complexes. The fluorescence enhancement of cofluorescence Y^3+ ions to the Eu(Ⅲ) complexes is clear. The optimum content of Y^3+ is 0.6 (molar fraction) for the chain complexes Eu1-xYx(TPA)(TTA)- (TPPO)2 and 0.5 for the binuclear complexes Eu^2(1-x)Y2x(TPA)(TTA)4(TPPO)4. The formation of polynuclear structure of the complex Eu1-xYx(TPA)(TTA)(TPPO)2 appears to be responsible for the good cofluorescence effect of Y^3+ ions. 相似文献
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采用溶胶-凝胶法制备了钙钛矿结构的MSnO3(M=Ca,Sr,Ba)晶体.将其作为锂离子电池负极材料的活性物质,利用恒电流电池测试仪研究其电化学性能.结果表明CaSnO3、SrSnO3和BaSnO3的首次放电容量分别为894.3
mAh/g、703.8 mAh/g和673.6 mAh/g,首次充电容量分别为418.3 mAh/g、257.8 mAh/g和224.8
mAh/g,不可逆容量损失分别达53.2%、63.3%和66.6%. 相似文献
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100.
采用水热法制备了ZnGa2O4纳米粉体,使用XRD、SEM、TEM及AFM对不同pH值条件下产物的结构及微观形貌进行了表征.结果表明pH值调节严重影响ZnGa2O4的晶相及粒度:当pH≥7.5时,可得到纯相的ZnGa2O4纳米粉体;随着pH的增加,晶胞参数增加,所得样品的平均粒径不断减小,其粒径范围为6~11nm,发射峰位置在450nm左右.所得样品的晶型很完整,GaO(OH)为细长棒状,ZnGa2O4晶粒为四方形和圆形. 相似文献