Raft crystals of poly(isoprene)-block-poly(ferrocenyldimethylsilane) and their surface wetting behavior during melting as observed by AFM and NanoTA

We report on the morphology evolution during heating and melting of lamellar poly(isoprene)-block-poly(ferrocenyldimethylsilane) (PI₇₆-b-PFDMS₇₆) raft crystals deposited at the native oxide surface of silicon (SiO₂) or at a highly ordered pyrolytic graphite (HOPG) surface, studied by in situ temperature controlled atomic force microscopy. Crystals deposited on hydrophilic SiO₂ surfaces revealed an irreversible decrease in length at temperatures of up to tens of degrees above their expected melting temperature, while maintaining their platelet-like structure. Crystals deposited on hydrophobic HOPG surfaces initially decreased in length below their expected melting temperature, while at 120 °C and above a typical molten morphology was observed. In addition, the irreversible formation of a PI₇₆-b-PFDMS₇₆ wetting layer around the crystals was observed upon increasing the temperature. These observations in the morphological behavior upon heating emphasize the role of interfacial energy between a surface deposited block copolymer based macromolecular nanostructure and its supporting substrate.     

Ultranarrow Bandwidth Organic Photodiodes by Exchange Narrowing in Merocyanine H‐ and J‐Aggregate Excitonic Systems

Ultranarrowband organic photodiodes (OPDs) are demonstrated for thin film solid state materials composed of tightly packed dipolar merocyanine dyes. For these dyes the packing arrangement can be controlled by the bulkiness of the donor substituent, leading to either strong H‐ or strong J‐type exciton coupling in the interesting blue (H‐aggregate) and NIR (J‐aggregate) spectral ranges. Both bands are shown to arise from one single exciton band according to fluorescence measurements and are not just a mere consequence of different polymorphs within the same thin film. By fabrication of organic thin‐film transistors, these dyes are demonstrated to exhibit hole transport behavior in spin‐coated thin films. Moreover, when used as organic photodiodes in planar heterojunctions with C₆₀ fullerene, they show wavelength‐selective photocurrents in the solid state with maximum external quantum efficiencies of up to 11% and ultranarrow bandwidths down to 30 nm. Thereby, narrowing the linewidths of optoelectronic functional materials by exciton coupling provides a powerful approach to produce ultranarrowband organic photodiodes.     

FPGA Implementation of a Power Amplifier Linearizer for an ETSI-SDR OFDM Transmitter

Most satellite digital radio （SDR） systems use orthogonal frequency-division multiplexing （OFDM） transmission, which means that variable envelope signals are distorted by the RF power amplifier （PA）. It is customary to back off the input power to the PA to avoid the PA nonlinear region of operation. In this way, linearity can be achieved at the cost of power efficiency. Another attractive option is to use a linearizer, which compensates for the nonlinear effects of the PA. In this paper, an OFDM transmitter conforming to European Telecommunications Standard Institute SDR Technical Specifications 2007-2008 was designed and implemented on a low-cost field-programmable gate array （FPGA） platform. A weakly nonlinear PA, operating in the L-band SDR frequency, was used for signal transmission. An adaptive linearizer was designed and implemented on the same FPGA device using digital predistortion to correct the undesired effects of the PA on the transmitted signal. Test results show that spectral distortion can be suppressed between 6-9 dB using the designed linearizer when the PA is driven close to its saturation region.     

Fabrication of Copper Nanowire Films and their Incorporation into Polymer Matrices for Antibacterial and Marine Antifouling Applications

With the ban of tributyltin, copper‐based biocides are now widely used in antifouling coatings as the major active ingredients. Given the past experience of heavy‐metal accumulation in harbors with limited water exchange, there is a significant interest in developing copper materials that greatly reduce the amount of copper ions released into marine surroundings. In this paper, copper nanowires (NWs) encapsulated in polymer matrices are investigated as the means to control the release of copper ions and to achieve a long‐lasting antifouling effect. Very long CuNWs with high aspect ratio in organic solution are drop‐coated onto substrates to fabricate uniform thin films. They are then incorporated into an elastomeric polydimethylsiloxane (PDMS) matrix. A small amount of CuNWs in PDMS can inhibit barnacle cyprid settlement, while it exhibits low mortality to cyprids and nauplii present in the surrounding seawater environment. The low levels of copper released after 50 days suggest that the intersecting and interconnected CuNWs embedded in PDMS could potentially release copper ions continuously over a few years in seawater. This approach provides a novel platform to use hybrid materials as effective marine antifouling coatings, and may be applied to fouling release materials to enhance their antifouling properties.     

Volitional facilitation of difficult intentions: Joint activation of intention memory and positive affect removes Stroop interference.

Removal of Stroop interference was obtained after exposure to words eliciting positive affect. This effect was predicted by personality systems interactions (PSI) theory, which assumes that (a) an abstract (high-level) representation of a difficult intention is generated in intention memory under certain conditions (e.g., when an action plan contains more than 1 step); (b) positive affect releases the inhibition of the pathway between intention memory and its output system. Interference removal is interpreted in terms of volitional facilitation. This effect posits a challenge to current cognitive models of the Stroop effect. Compared with alternative explanations, PSI theory can explain the data in a broader context: Implications of volitional facilitation and volitional inhibition for the study of prospective memory, alienation, procrastination, and rumination in depression are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Microstructures for characterization of seebeck coefficient of doped polysilicon films

CMOS based thermoelectric micro-transducers have been demonstrated for various applications. To achieve better design and optimization of such micro-transducers, the Seebeck coefficient of doped polysilicon thin film needs to be measured accurately with respect to optimization effort in process and structure design of micro-transducers. A novel circular test structure is firstly presented to get accurate value of Seebeck coefficient in this paper, while the known planar and cantilever test structures are fabricated together and characterized separately to validate the measured Seebeck coefficient of samples with the same process conditions for comparison. Seebeck coefficient measured by the circular structure shows good agreement with the result measured by cantilever structure, while there is an error of about 14% for the result given by planar structure. The circular test structure is a good at accurate testing of the average absolute values of Seebeck coefficient of p-type and n-type. Strength and drawback for the three structures are summarized.