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1.
Feng  Yingrui  Hu  Kang  Zhang  Min  Ding  Wei  Kong  Xiangkai  Sheng  Zhigao  Liu  Qiangchun 《Journal of Materials Science》2022,57(1):204-216
Journal of Materials Science - Rationally designing microwave absorption materials with highly efficient and tunable bandwidth is in great demand but remains a huge challenge. In this study,...  相似文献   
2.
The present work was conducted to illustrate the mechanism of gel formation of myofibrillar proteins (MPs) under different microwave heating times. The results showed that the denaturation enthalpy (ΔH) of the MPs significantly decreased when the heating time increased from 3 to 9 s and then completely disappeared as the heating time progressed, indicating that the MPs gradually denatured and subsequently aggregated with increasing heating time, which was further verified by the changes in the secondary structure, electrophoretic bands, and gel properties (e.g., water holding capacity and textural profiles) of the MPs. Microstructural images indicated that the MP gel formed under 12 s had the most compact network, indicating that extended microwave heating time could induce quality deterioration of MP gels. Moreover, the hydrophobic forces, electrostatic forces, and disulphide bonds of the MPs gradually intensified with increasing microwave heating time, suggesting that both non-covalent and covalent bonds could promote molecular denaturation and subsequent aggregation of MPs. In addition, correlation analysis revealed that the changes in the molecular conformation of MPs induced by different microwave heating times could effectively regulate the formation of MP gels and their related properties.  相似文献   
3.
Liu  Wei  Zhao  Fusheng  Kong  Meiling  Yin  Songfeng  Wang  Huiying  Liu  Xiaoying 《Fire Technology》2022,58(5):2811-2823
Fire Technology - The use of perfluorinated hexanone as a fire extinguishing agent for lithium-ion batteries (LIBs) has been steadily increasing in China in recent years. It successfully handles...  相似文献   
4.
Adsorption separation of olefin and paraffin can greatly lower the energy consumption associated with the currently utilized distillation technique but remains a great challenge. Herein, we report the efficient separation of propylene (C3H6) and propane (C3H8) in a phosphate anion-functionalized metal–organic framework (MOF) ZnAtzPO4 by synergetic effect of equilibrium and kinetics. The material features periodically expanded and contracted apertures decorated with electronegative groups, offering eligible pore shape and pore chemistry to effectively trap C3H6 under moderate isosteric heat of adsorption (27.5 kJ mol−1) while obstruct the diffusion of C3H8. It simultaneously combines excellent thermodynamic selectivity (uptake ratio of 1.71) and kinetic selectivity (~31) for C3H6/C3H8 separation, meanwhile can be easily regenerated. Breakthrough experiment for C3H6/C3H8 gas mixture was conducted and confirmed the outstanding separation capability of ZnAtzPO4. The equilibrium and kinetics cooperative C3H6/C3H8 adsorption separation was for the first time found in anion-functionalized MOFs, and further confirmed by computational studies.  相似文献   
5.
简述了磁化处理的发展历程,阐述了磁化处理对浮选水系性质的影响规律及其机理,列举了磁化处理在金属矿、非金属矿、煤等不同物料浮选中应用的研究结果,总结分析发现磁化处理在浮选中应用具有简化工艺流程、优化分选指标、减少药剂消耗等优势.磁化处理影响浮选的机理尚不明确,磁化处理影响浮选的因素及影响规律、设备和工艺也有待进一步研究.理论分析、计算机模拟、实验和先进的检测方法相结合,对磁化处理应用于浮选的机理、影响因素及影响规律、工艺及设备进行深入研究是今后的发展趋势.  相似文献   
6.
The hardness and toughness of regenerated cemented carbides, in general, are contradictory. Therefore, it is critical to explore regenerated cemented carbides with both high hardness and high toughness. In this study, regenerated WC-8-wt% Co cemented carbide with SiC nanowhisker were prepared by low-pressure sintering. The influence of SiCw contents on the microstructure and mechanical properties of regenerated WC-8-wt% Co cemented carbide was investigated. The results indicated that the hardness, density, flexural strength, and fracture toughness of regenerated cemented carbide first increased and then decreased with the addition of SiCw. The Vickers hardness, density, flexural strength, and fracture toughness could reach 1575 HV, 14.6 g/cm3, 2204 MPa, 16.85 MPa·m1/2, respectively, with SiCw content 0.5 wt%, which were increased by 14.4%, 0.7%, 12.2%, and 17.3%, respectively, when compared with the regenerated cemented carbide without SiCw. The lowest friction coefficient and the best wear resistance could be also reached when 0.5-wt% SiCw was added. The fracture mechanism of the regenerated cemented carbide contained both transgranular and intergranular fracture through the microscopic observation of fracture surface via scanning electron microscope.  相似文献   
7.
Nickel-graphite self-lubricating composites are a promising candidate to be used in turbine constructions that are usually exposed to high temperature oxidation and wear.However,the high-temperature stability of graphite as well as the effect that the oxide scale will play on the following wear process are still yet in debate.In this work,oxidation behavior of a NiCrAl-graphite composite and the subsequent friction and wear performances were studied.Results indicate that graphite is stable in the composites after oxidation at T≤400 ℃ for 300 h,which contributes synergistically with the thin oxide film to self-lubrication.The friction coefficient is below 0.20 and the wear rate is ~1.43×10~(-5) mm~3 N~(-1) m~(-1).The composite has the highest friction coefficient and wear rate when it was suffered from the high temperature oxidation at 500 ℃.Once it was oxidized at 600 ℃,a glaze layer would develop during the subsequent sliding.It plays a positive role in improving tribological properties though in the absence of lubricant phase of graphite,with to be exactly the friction coefficient and wear rate reduced by 13% and 21%,respectively,in comparison with the case of oxidation at 500℃.  相似文献   
8.
The soft nature of organic–inorganic halide perovskites renders their lattice particularly tunable to external stimuli such as pressure, undoubtedly offering an effective way to modify their structure for extraordinary optoelectronic properties. Here, using the methylammonium lead iodide as a representative exploratory platform, it is observed that the pressure-driven lattice disorder can be significantly suppressed via hydrogen isotope effect, which is crucial for better optical and mechanical properties previously unattainable. By a comprehensive in situ neutron/synchrotron-based analysis and optical characterizations, a remarkable photoluminescence (PL) enhancement by threefold is convinced in deuterated CD3ND3PbI3, which also shows much greater structural robustness with retainable PL after high peak-pressure compression–decompression cycle. With the first-principles calculations, an atomic level understanding of the strong correlation among the organic sublattice and lead iodide octahedral framework and structural photonics is proposed, where the less dynamic CD3ND3+ cations are vital to maintain the long-range crystalline order through steric and Coulombic interactions. These results also show that CD3ND3PbI3-based solar cell has comparable photovoltaic performance as CH3NH3PbI3-based device but exhibits considerably slower degradation behavior, thus representing a paradigm by suggesting isotope-functionalized perovskite materials for better materials-by-design and more stable photovoltaic application.  相似文献   
9.
Multifluid model (MFM) simulations have been carried out on liquid–solid fluidized beds (LSFB) consisting of binary and higher-order polydisperse particle mixtures. The role of particle–particle interactions was found to be as crucial as the drag force under laminar and homogenous LSFB flow regimes. The commonly used particle–particle closure models are designed for turbulent and heterogeneous gas–solid flow regimes and thus exhibit limited to no success when implemented for LSFB operating under laminar and homogenous conditions. A need is perceived to carry out direct numerical simulations of liquid–solid flows and extract data from them to develop rational closure terms to account for the physics of LSFB. Finally, a recommendation flow regime map signifying the performance of the MFM has been proposed. This map will act as a potential guideline to identify whether or not the bed expansion characteristics of a given polydisperse LSFB can be correctly simulated using MFM closures tested.  相似文献   
10.
目的:为实现人源溶血磷脂酶D(LysoPLD)的原核异源可溶性表达。方法:通过NCBI检索,确定人源LysoPLD基因序列(GenBank: L46720.1)。采用密码子优化后的序列,克隆至pET-28a表达载体中,采用共表达麦芽糖结合蛋白融合标签(MBP)和共表达促蛋白正确折叠分子伴侣触发因子Trigger factor(tig)两种方式提高LysoPLD蛋白在大肠杆菌中的异源可溶性表达,建立对应蛋白的纯化工艺包括离子柱纯化,硫酸铵盐析,疏水柱纯化,淀粉树脂柱(Amylose Resin)纯化,分离纯化获得的重组酶,经聚丙烯酰胺凝胶电泳(SDS-PAGE)测定蛋白纯度,以对羟基棕榈酸酯为底物对比两种蛋白的酶学性质。结果:成功构建载体pET28a-MBP-LysoPLD和pET28a-pTF16-LysoPLD,并获得工程菌BL21(DE3)-pET28a-MBP-LysoPLD和BL21(DE3)-pET28a-pTf16-LysoPLD。BL21(DE3)-pET28a-MBP-LysoPLD经0.6 mmol/L异丙基硫代半乳糖苷(IPTG)低温诱导过夜可获得上清表达的MBP-LysoPLD蛋白;BL21(DE3)-pET28a-pTf16-LysoPLD在含有0.5 μg/mL L-Arabinose的LB培养基中培养,经0.1 mmol/L IPTG低温诱导表达,可获得可溶性表达的LysoPLD蛋白,经纯化,酶纯度可大于80%。以对羟基棕榈酸酯为底物,对比两种方法得到的蛋白的酶学性质,发现二者催化反应的最适温度、最适pH、最适Ca2+浓度、比酶活基本一致。结论:两种基因共表达方式都可实现人源LysoPLD的在大肠杆菌中的可溶性表达,且酶学性质基本相同。  相似文献   
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