Destination-aware metric based social routing for mobile opportunistic networks

Wireless Networks - Although centrality is widely used to differentiate the importance of nodes for social-aware routing in mobile opportunistic networks (MONs), it is destination-agnostic since...     

Co-precipitation synthesis of ZnAl2O4: Cr3+ phosphor for better light penetration in pc-LED

Cr doped ZnAl₂O₄ spinel samples were prepared by the traditional solid state reaction and co-precipitation synthetic route, and the results suggest that the co-precipitation method has some superiority in contrast to the solid state reaction method. XRD, FT-IR, and XPS spectra confirmed that the well-crystallized spinel cubic phase of ZnAl₂O₄: Cr³⁺ samples were successfully formed. The morphology of the samples was investigated by FE-SEM and FE-TEM, and the results show that the samples by the co-precipitation route can generate a smaller size of particles compared to the solid state reaction. Photoluminescence excitation spectra monitored at 686 nm are comprised of two broad excitation bands near 530 nm and 395 nm, and the emission spectra show emissions ranging from 640 to 780 nm, due to the ²E?→?⁴A₂ spin-forbidden transition of Cr³⁺ ions in spinel lattices. The optimized concentration monitored at 686 nm is 1%, while at 693 nm is 3.5%. Compared with the samples by solid state reaction method, the samples by co-precipitation method show preferable luminescent properties, such as the higher photoluminescence intensity and higher quantum efficiency. Several phosphor-converted LEDs were to investigate the applicability of the prepared samples. The results confirm that the phosphor has potential applications in plant growth and supplementing the red region in white-LEDs and the phosphors prepared by co-precipitation are more suitable to be used in phosphor-converted LED devices due to their preferable luminescent properties.

     

离子型稀土矿山淋洗及尾水富集试验研究

对浸矿后离子型稀土原地浸矿场采用清水进行淋洗，在184天的清水淋洗过程中，尾水氨氮值从最开始的507mg/L，降低至140mg/L，淋洗尾水pH4.52~3.10。淋洗尾水采用两级反渗透膜分离，既回收有价资源稀土，又能使出水氨氮达标。结果表明，产水氨氮浓度稳定低于15mg/L，对稀土的截留率高于98.25%，浓水中稀土离子平均浓度313.4mg/L，可进一步回收稀土资源。     

新型防屈曲高强钢腹板可更换钢连梁抗震性能研究

文章率先提出一种新型防屈曲高强钢腹板可更换钢连梁(简称“新型钢连梁”)：腹板采用高强钢，可提高钢连梁的屈服抗剪强度，连梁变形减小，从而减小可更换结构整体变形，便于更换；加劲肋紧贴腹板(但不焊接)提供约束，仅与上下翼缘焊接，可减少60%以上的焊接量。其次，设计并开展了11个试件的拟静力试验，研究了加劲肋间距(规范限值dmax、0.85dmax)、腹板厚度(6mm、8mm)、腹板钢材强度(Q460、Q550)和构造形式(加劲肋与腹板贴紧或焊接)等参数对新型钢连梁抗震性能的影响。试验结果表明：试件均发生剪切破坏；满足加劲肋间距限值的新型钢连梁，滞回曲线饱满，峰值时腹板未发生鼓曲且极限转角均超过0.1rad，大于规范限值0.08rad，表现出良好的耗能和变形能力；缩小加劲肋间距、增加腹板厚度或提高腹板钢材强度，新型钢连梁刚度及承载力提高；新型钢连梁峰值承载力较传统构造试件低约5%。最后，基于试验结果建立了有限元模型并开展了分析，研究结果表明：对腹板采用Q460、Q550高强钢材的新型钢连梁，峰值承载力计算时超强系数建议取1.43(长度比为0.5～1.0)或1.39(长度比为1.0～1.6)、1.25，以期为实际工程设计提供依据。     

Co?N graphene encapsulated cobalt catalyst for H2O2 decomposition under acidic conditions

Hydrogen peroxide (H₂O₂) has been listed as one of the 100 most important chemicals in the world. However, huge amount of residual H₂O₂ is hard to timely decomposed into O₂ and H₂O under acidic condition, easily resulting in explosion hazard. Here, we reported a core–shell structure catalyst, that is graphene with Co N structure encapsulated Co nanoparticles. Co N graphene shell serves as the active site for the H₂O₂ decomposition, and Co core further enhance this decomposition. Benefiting from it, the H₂O₂ decomposition were close to 100% after 6 cycles without pH adjustment, which increased 6 orders of magnitude compared with no catalyst. At the same time, the O₂ generation reached 99.67% in 2 h with little metal leaching, and ·OH has been greatly inhibited to only 0.08%. This work can cleanly remove H₂O₂ with little deep oxidation and protect the process of H₂O₂ utilization to achieve a safer world.