全文获取类型
收费全文 | 516篇 |
免费 | 76篇 |
国内免费 | 6篇 |
专业分类
电工技术 | 11篇 |
综合类 | 6篇 |
化学工业 | 182篇 |
金属工艺 | 83篇 |
机械仪表 | 1篇 |
建筑科学 | 3篇 |
能源动力 | 43篇 |
轻工业 | 31篇 |
水利工程 | 2篇 |
石油天然气 | 2篇 |
无线电 | 66篇 |
一般工业技术 | 139篇 |
冶金工业 | 3篇 |
原子能技术 | 5篇 |
自动化技术 | 21篇 |
出版年
2023年 | 4篇 |
2022年 | 7篇 |
2021年 | 4篇 |
2020年 | 17篇 |
2019年 | 19篇 |
2018年 | 26篇 |
2017年 | 31篇 |
2016年 | 62篇 |
2015年 | 21篇 |
2014年 | 14篇 |
2013年 | 14篇 |
2012年 | 20篇 |
2011年 | 13篇 |
2010年 | 5篇 |
2009年 | 51篇 |
2008年 | 41篇 |
2007年 | 33篇 |
2006年 | 36篇 |
2005年 | 19篇 |
2004年 | 19篇 |
2003年 | 24篇 |
2002年 | 6篇 |
2001年 | 21篇 |
2000年 | 12篇 |
1999年 | 12篇 |
1998年 | 13篇 |
1997年 | 9篇 |
1996年 | 7篇 |
1995年 | 16篇 |
1994年 | 8篇 |
1993年 | 3篇 |
1992年 | 1篇 |
1991年 | 4篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1986年 | 1篇 |
1984年 | 1篇 |
排序方式: 共有598条查询结果,搜索用时 15 毫秒
1.
Mitsuo Miyazawa Hideki Kawazoe Mitsuro Hyakumachi 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2003,78(6):620-625
The microbial transformation of l‐menthol ( 1 ) was investigated by using 12 isolates of soil‐borne plant pathogenic fungi, Rhizoctonia solani (AG‐1‐IA Rs24, Joichi‐2, RRG97‐1; AG‐1‐IB TR22, R147, 110.4; AG‐1‐IC F‐1, F‐4, P‐1; AG‐1‐ID RCP‐1, RCP‐3, and RCP‐7) as a biocatalyst. Rhizoctonia solani F‐1, F‐4 and P‐1 showed 89.7–99.9% yields of converted product from 1 , RCP‐1, RCP‐3, and RCP‐7 26.0–26.9% and the other isolates 0.1–12.0%. In the cases of F‐1, F‐4 and P‐1, substrate 1 was converted to (?)‐(1S,3R,4S,6S)‐6‐hydroxymenthol ( 2 ), (?)‐(1S,3R,4S)‐1‐hydroxymenthol ( 3 ) and (+)‐(1S,3R,4R,6S)‐6,8‐dihydroxymenthol ( 4 ), which was a new compound. Substrate 1 was converted to 2 and/or 3 by RRG97‐1, 110.4, RCP‐1, RCP‐3 and RCP‐7. The structures of the metabolic products were elucidated on the basis of their spectral data. In addition, metabolic pathways of the biotransformation of 1 by Rhizoctonia solani are discussed. Finally, from the main component analysis and the differences in the yields of converted product from 1 , the 12 isolates of Rhizoctonia solani were divided into three groups based on an analysis of the metabolites. Copyright © 2003 Society of Chemical Industry 相似文献
2.
Mitsuo Miyazawa Tomohiko Takahashi Kazuki Sakata Isao Horibe 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(7):1006-1011
BACKGROUND: The biotransformation of sesquiterpenoids, which are a large class of naturally occurring compounds, using microorganisms as a biocatalyst to produce useful novel organic compounds was investigated. The biotransformation of sesquiterpenoids, (+)‐aromadendrene ( 1 ), (−)‐alloaromadendrene ( 2 ) and (+)‐ledene ( 3 ) has been investigated using Aspergillus wentii as a biocatalyst. Results: Compound 1 was converted to (−)‐(10S,11S)‐10,13,14‐trihydroxyaromadendrane ( 4 ). Compound 2 was converted to (+)‐(1S,11S)‐1,13‐dihydroxyaromadendrene ( 5 ) and (−)‐5,11‐epoxycadin‐1(10)‐en‐14‐ol ( 6 ). Compound 3 was converted to compound 6 , (+)‐(10R,11S)‐10,13‐dihydroxyaromadendr‐1‐ene ( 7 ) and (+)‐(10S,11S)‐10,13‐dihydroxyaromadendr‐1‐ene ( 8 ). The structure of the metabolic products has been elucidated on the basis of their spectral data. CONCLUSION: Compound 1 gave only one product that was hydroxylated at C‐10, C‐13 and C‐14. By contrast, compounds 2 and 3 gave a number of products, one of which was common. The differences in oxidation of 1–3 are due to the configuration of the C‐1 position. Compounds 4–8 were new compounds. Copyright © 2008 Society of Chemical Industry 相似文献
3.
A. Andreev L. Prahov M. Gabrovska A. Eliyas V. Ivanova 《Applied catalysis. B, Environmental》1996,8(4):365-373
The catalytic activity of a wide range of transition metal oxides in oxidation of sulphide ions by air in aqueous medium was studied. Some specific features of the reaction mechanism on some of the studied oxides were considered. The transition metal oxides are promising catalysts for practical application. Some of these oxides will allow the preparation of catalysts possessing activity comparable to that of the cobalt phthalocyanine based catalysts, popular in industrial practice. 相似文献
4.
A. N. Iyer U. Balachandran L. R. Motowidlo J. G. Hoehn P. Haldar 《Journal of Electronic Materials》1994,23(11):1087-1091
Pb0.4Bi1.8Sr2Ca2.2Cu3Ox (Bi-2223) precursor powder was prepared by a solid-state reaction of carbonates and oxides of lead, bismuth, strontium, calcium,
and copper, and the powder was then used to fabricate silver-clad tapes by the powder-in-tube technique. Transport critical
current density (Jc) values>4×104 A/cm2 at 77K and 2×105 A/cm2 at 4.2 and 27K have been achieved in short tape samples. Long lengths of tape were tested by winding them into pancake coils.
Recently, we fabricated a test magnet by stacking ten pancake coils, each containing three 16m lengths of rolled tape, and
tested it at 4.2, 27 and 77K. A maximum generated field of 2.6 T was measured in zero applied field at 4.2K and the test magnet
generated significant self-field in background fields up to 20 T. The results are discussed in this paper. 相似文献
5.
A. Goyal E. D. Specht Z. L. Wang D. M. Kroeger J. A. Sutliff J. E. Tkaczyk J. A. Deluca L. Masur G. N. Riley 《Journal of Electronic Materials》1994,23(11):1191-1197
Microstructural origins for reduced weak-link behavior in high-Jc melt-processed YBCO, spray pyrolyzed thick films of Tl-1223, metallic precursor Y-124 polycrystalline powder-in-tube (PIT)
wires and PIT Bi-2212/2223 are discussed. Since the materials studied are the highest Jc, polycrystalline, high-Tc superconductors fabricated worldwide, the results provide important guidelines for further improvements in superconducting
properties, thereby enabling practical applications of these materials. It is found that strongly linked current flow within
domains of melt-processed 123 occurs effectively through a single crystal path. In c-axis oriented, polycrystalline Tl-1223
thick films, local in-plane texture has been found to play a crucial role in the reduced weak-link behavior. Formation of
“colonies” of grains with a common c-axis and modest in-plane misorientation was observed. Furthermore, a colony boundary
in general has a varying misorientation along the boundary. Large regions comprised primarily of low angle boundaries were
observed. Percolative transport through a network of such small angle boundaries appears to provide the nonweak-linked current
path. Although powder-in-tube BSCCO 2212 and 2223 also appear to have a “colony” microstructure, there are some important
differences. Colonies in BSCCO consist of stacks of grains with similar c-axis orientation in contrast to colonies in Tl-1223
films where few grains are stacked on top of one another. Furthermore, most grains within a colony in BSCCO have the same
lateral dimensions as that of the colony, resulting largely largely in “twist” boundaries. Further microstructural characterization
of high-Jc PIT 2212 and 2223 is currently underway. In the case of Y-124 wires, weak macroscopic in-plane texture is found. Additional
measurements are underway to determine if a sharper, local in-plane texture also exists. It is found that in three of the
four types of superconductors studied, reduced weak-link behavior can be ascribed to some degree of biaxial alignment between
grains, either on a “local” or a “global” scale. 相似文献
6.
7.
The PbO2 and F−-doped PbO2 (F-PbO2) film electrodes have been prepared by an electrodeposition process onto platinum substrate. The changes of their electrochemical activity for oxygen evolution (OE) reaction with accelerated electrolysis time have been studied. The results show that the activity of the electrodes decreases with increasing electrolysis time. This can be attributed to the conductivity variations, which are caused by the decrease of the oxygen vacancy concentration in PbO2 films during OE. The mechanism of the decrease of the oxygen vacancies has been investigated. For F-PbO2 film electrodes, though its electrochemical activity is somewhat lower than that of undoped one, its activity stability is much higher in comparison with that of PbO2. The influence of F− doping on the activity of PbO2 film electrodes has been also discussed. 相似文献
8.
Wei Li Mercedes Coughlin Robert L. Albright Richard H. Fish 《Reactive and Functional Polymers》1995,28(1)
We report on the synthesis and reactivity of a polymer-supported o-phenylenediamine hydrochloride ligand, PS-PDHC, using macroporous 6% crosslinked polystyrene-divinylbenzene beads. The PS-PDHC ligand was found to be highly selective to AuCl4− ions in strongly acidic solutions in the presence of other precious metal ions, PdCl42−, PtCl42−, RhCl63−, and RuCl52− (selectivity values: 2.5, Au/Pd; 7.5, Au/Pt; 7, Au/Rh; 2.2, Au/Ru) as well as other transition metal ions, Fe 3+, Cr3+, CU2+, Nit+, and Mn2+. The sorption capacity, selectivity, kinetics of removal and recovery, and solution isotherms have been determined for AuCl4− ions in competition with the above-mentioned metal ions. The relative ease of formation of the anionic complex in 0.5 M HCI, AuCl4− was thought to be the primary reason for its selective ability to bind to the PS-PDHC ligand by an anion-exchange mechanism. Therefore, the effect of the HCI concentration on the kinetics of AuCl4− ion removal from solution was also investigated to clearly show that raising the pH from 0 to 5 caused a dramatic decrease in rate. The AuCl4− ion can be recovered quantitatively from the PS-PDHC beads using a 5% thiourea solution in 0.1 M HCl, allowing the polymer-supported ligand to be reused. 相似文献
9.
Michael Wrle Hans-Joachim Muhr Holger Meyer zu Altenschildesche Reinhard Nesper 《Journal of Alloys and Compounds》1997,260(1-2):80-87
Ca15(CBN)6(C2)2O contains CBN4− anions as well as C2− units and isolated O2− anions. The compound is obtained by heating a stoichiometric mixture of CaO, C and BN with an excess of Ca in sealed niobium ampoules to 1270 K. It crystallizes in the space group Ia
d with a = 1656.84(9) pm. Preparation, crystal structure, NMR and IR-spectroscopic properties are discussed. 相似文献
10.
LU XY A. NAGATA K. SUGAWARA K. WATANABE T. NOJIMA 《中国有色金属学会会刊》2006,16(B01):11-19
The microstructure and superconducting properties of Bi-2223 superconductor fabricated in high magnetic fields were investigated. The results shows that the Bi-2212 grains with their c-axis parallel to the magnetic field were formed after the partial-melting and solidification in 8 T magnetic field, and transformed into the Bi-2223 grains with c-axis alignment during the further sintering process at 840 ℃ without magnetic field. The conversion of Bi-2212 grains to Bi-2223 grains has the heredity in grain alignment. The mixed structures of the Bi-2223 and the Bi-2212 grains with their c-axis parallel to the magnetic field are formed in samples sintered at 850-855 ℃ in 10 T magnetic field. When sintered in 10 T below 845 ℃, a high proportion of Bi-2223 phase is obtained, however no preferred orientation is observed. The Bi-2223 grains with their c-axis parallel to the axial direction of the vertical tube furnace are formed not only on the surface, but also in the center of the sample sintered at 850 ℃ for 120 h in a 15 ℃/cm temperature gradient without magnetic field. Moreover, the samples sintered in the temperature gradient and in a 10 T magnetic field have a stronger c-axis alignment ofbi-2223 phase. 相似文献