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A general numerical model is described for the dissolution kinetics of spherical particles in binary systems for any combination of first order reactions at the particle-matrix interface and long distance diffusion within the matrix. The model is applicable to both finite and infinite media and handles both complete and partial particle dissolution. It is shown that interfacial reactions can have a strong effect on the dissolution kinetics, the solute concentration at the particle-matrix interface and the solute concentration profile in the matrix. 相似文献
3.
应用音平化渣图象分析和指导转炉造渣操作 总被引:3,自引:1,他引:2
利用音平化渣图象可以清晰地看出在转炉造渣过程中何时发生喷溅,何时发生炉渣返干和何时化渣正常。应用音平化渣图象和炉渣三元相图,可以正确地分析发生喷溅和返干的原因,从而找到避免突发性喷溅和严重返干的方法。正确的枪位和炉渣碱度控制是实现平稳吹炼的保证,而音平化渣图象能帮助操作工实现这一目标。 相似文献
4.
RM Martín‐Aranda E Ortega‐Cantero ML Rojas‐Cervantes MA Vicente‐Rodríguez MA Baares‐Muoz 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(2):234-238
α,β‐Unsaturated nitriles have been synthesized by Knoevenagel condensation of a carbonylic compound with malononitrile, assisted by sonochemical irradiation. Two alkaline‐promoted clays (Li+‐ and Cs+‐exchanged saponites) have been employed as catalysts. The influence of the carbonylic compound (benzaldehyde or cyclohexanone) and the use of a solvent on the catalytic activity have been studied. Remarkable increase in the conversion values has been found when the reaction is activated by ultrasound, as compared with the thermal activation. In this green, solvent‐free procedure, α,β‐unsaturated nitriles have been produced in very high yields (97%) when the Cs+‐saponite is used as catalyst. Copyright © 2004 Society of Chemical Industry 相似文献
5.
This investigation proposes a fixed collision rate (FCR) back-off algorithm for wireless networks. The proposed scheme takes advantage of the central unit (CU) in a wireless network to broadcast a common back-off window size to all the users, significantly alleviating the unfairness of bandwidth utilization in conventional binary exponential back-off (BEB) algorithms. It is shown that, when maximum throughput is achieved, collision rate is almost a constant for any traffic load. In the operation of the FCR, the CU dynamically adjusts the back-off window size to keep the collision rate at a constant level for maximum throughput. Simulation results demonstrate that the unfairness of bandwidth utilization in the BEB is significantly lessened and the throughput can be maintained at e-1≈0.368 when the number of users approaches infinity. The capture effect even further improves system performance. 相似文献
6.
中碱值硫化烷基水杨酸钙的制备及性能研究 总被引:1,自引:0,他引:1
介绍了一种碱值达170mgKOH/g以上、硫含量大于3.0%、钙含量大于6.0%的硫化烷基水杨酸钙盐润滑油添加剂的制备过程及其性能。实验中重点考察了促进剂及硫磺加入量对产品碱值及硫含量的影响;通过冷冻蚀刻电镜法观察了含碳酸盐的胶体粒子结构及粒度分布情况;应用凸轮挺校、四球试验机等考察了硫化烷基水杨酸钙盐产品的极压抗磨性能。结果表明,硫化烷基水杨酸钙产品不但具有良好的高温洁净性、抗氧化安定性、胶体稳定性,而且具有突出的极压抗磨性及热稳定性。 相似文献
7.
Terry WindeattAuthor Vitae 《Pattern recognition》2003,36(12):2743-2756
Various measures, such as Margin and Bias/Variance, have been proposed with the aim of gaining a better understanding of why Multiple Classifier Systems (MCS) perform as well as they do. While these measures provide different perspectives for MCS analysis, it is not clear how to use them for MCS design. In this paper a different measure based on a spectral representation is proposed for two-class problems. It incorporates terms representing positive and negative correlation of pairs of training patterns with respect to class labels. Experiments employing MLP base classifiers, in which parameters are fixed but systematically varied, demonstrate the sensitivity of the proposed measure to base classifier complexity. 相似文献
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Andrew Klapper 《Journal of Cryptology》1994,7(1):33-51
A new method of cryptologic attack on binary sequences is given, using their linear complexities relative to odd prime numbers. We show that, relative to a particular prime number p, the linear complexity of a binary geometric sequence is low. It is also shown that the prime p can be determined with high probability by a randomized algorithm if a number of bits much smaller than the linear complexity is known. This determination is made by exploiting the imbalance in the number of zeros and ones in the sequences in question, and uses a new statistical measure, the partial imbalance.This project was sponsored by the National Security Agency under Grant No. MDA904-91-H-0012. The United States Government is authorized to reproduce and distribute reprints notwithstanding any copyright notation hereon. 相似文献