首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   3507篇
  免费   284篇
  国内免费   174篇
电工技术   94篇
综合类   202篇
化学工业   1149篇
金属工艺   472篇
机械仪表   92篇
建筑科学   130篇
矿业工程   71篇
能源动力   184篇
轻工业   346篇
水利工程   17篇
石油天然气   87篇
武器工业   7篇
无线电   161篇
一般工业技术   397篇
冶金工业   362篇
原子能技术   65篇
自动化技术   129篇
  2024年   1篇
  2023年   53篇
  2022年   107篇
  2021年   124篇
  2020年   117篇
  2019年   94篇
  2018年   96篇
  2017年   102篇
  2016年   105篇
  2015年   106篇
  2014年   197篇
  2013年   213篇
  2012年   223篇
  2011年   247篇
  2010年   163篇
  2009年   219篇
  2008年   180篇
  2007年   211篇
  2006年   230篇
  2005年   172篇
  2004年   163篇
  2003年   131篇
  2002年   126篇
  2001年   115篇
  2000年   75篇
  1999年   86篇
  1998年   47篇
  1997年   46篇
  1996年   42篇
  1995年   35篇
  1994年   32篇
  1993年   18篇
  1992年   24篇
  1991年   9篇
  1990年   12篇
  1989年   15篇
  1988年   5篇
  1987年   2篇
  1986年   3篇
  1985年   2篇
  1984年   2篇
  1983年   3篇
  1982年   2篇
  1981年   2篇
  1980年   4篇
  1979年   1篇
  1978年   1篇
  1977年   1篇
  1975年   1篇
排序方式: 共有3965条查询结果,搜索用时 78 毫秒
1.
2.
In this study, Ca/Tb co-doped HfO2 coatings were prepared by atmosphere plasma spraying. The chemical composition, morphology and infrared property of the coatings were characterized. The coatings possessed a layer-stacked morphology. When the Ca/Tb doping atomic ratio was 1:1, the phase of the coatings gradually changed from monoclinic to cubic with increasing the doping mass. The CTH2 coating had the highest emissivity which was 0.820 in 0.75–6.5 µm and 0.902 in 6.5–15 µm respectively. The enhancement in short band was mainly due to the introduction of Ca2+ and Tb3+ ions that generated oxygen vacancies in the lattice forming impurity levels within the forbidden band, moreover, the transfer of Tb3+ to Tb4+ increased the concentration of free electrons, which promoted the absorption of free carriers. The increase in long band attributed to the lattice distortion that reduced the lattice symmetry and strengthened the absorption of lattice polar vibration.  相似文献   
3.
In order to study the influence of nitrogen on the deflagration characteristics of premixed hydrogen/methane, the explosion parameters of premixed hydrogen/methane within various volume ratios and different dilution ratios were studied by using a spherical flame method at room temperature and pressure. The results are as follows: The addition of nitrogen makes the upper limit of explosion of hydrogen/methane premixed gas drop, and the lower limit rises. For explosion hazard (F-number), hydrogen/methane premixed fuel with a hydrogen addition ratio of 10% has the lowest risk, and nitrogen has a greater impact on the dangerous degree of hydrogen and methane premixed gas whose hydrogen addition ratio does not exceed 30%. In terms of flame structure, the spherical flame was affected by buoyancy instability as the percentage of nitrogen dilution increased, but the buoyancy instability gradually decreased as the percentage of hydrogen addition increased. The addition of diluent gas reduces the spreading speed of the stretching flame and reduces the stretching rate in the initial stage of flame development. The laminar flame propagation velocity calculated by the experiment in this paper is consistent with the laminar flow velocity of the hydrogen/methane premixed gas calculated by GRI Mech 3.0. Considering the explosion parameters such as flammability limit, laminar combustion rate and deflagration index, when hydrogen is added to 70%, it is the turning point of hydrogen/methane premixed fuel.  相似文献   
4.
采用安琪小曲复配不同比例浓香型大曲酿酒,探究浓香型大曲对小曲酒出酒率、主要风味物质及酒醅微生物群落的影响。结果表明,与纯安琪小曲酿酒比较,大曲添加量为5%时,出酒率提高4.23%;大曲添加量为20%时,所产基酒感官品质最佳,异丁醇及异戊醇含量分别降低0.44 g/L、0.40 g/L;大曲添加量为10%时,基酒中乙酸乙酯及乳酸乙酯含量分别增加0.78 g/L、0.04 g/L;大曲添加使酒醅微生物群落多样性增加,且不同大曲添加量使酒醅优势菌群与丰度发生了不同程度的变化,说明浓香型大曲的添加能提升安琪小曲酒产品质量。相关性分析表明,不动杆菌属(Acinetobacter)与乳酸杆菌属(Lactobacillus)、伊萨酵母属(Issatchenkia)与根霉属(Rhizopus)间呈显著负相关(P<0.05),出酒率及乳酸乙酯含量与伊萨酵母属相对丰度呈显著正相关(P<0.05),乳酸乙酯含量与根霉属相对丰度呈显著负相关(P<0.05)。  相似文献   
5.
镍电解液的复杂高盐基体对其中微量铜的监测产生干扰。将旋转圆盘电极原子发射光谱(RDE-AES)与标准加入法结合,无需样品前后处理,无基体效应,采用改进后的校准曲线测定镍电解液工艺流程中不同中间液中的微量铜。根据元素蒸发曲线,确定预燃时间6 s、采集时间7~30 s,预燃激发改善了盘电极的润湿性,从而保证进样量的稳定性;合理的曝光时间可以在保证分析元素强度灵敏度的前提下提高分析速度,单次检测时间小于35 s。选用Ni 324.845 7 nm为内标,校正激发行为和进样量误差。方法检出限为0.15 mg/L。按照实验方法测定镍电解液工艺流程中不同中间液中微量铜,结果的相对标准偏差(RSD,n=6)小于12%,加标回收率为98%~110%。  相似文献   
6.
A simplified low-cost approach to experimentally determine transport parameters in mountain rivers is described, with an emphasis on the longitudinal dispersion coefficient (DL). The approach is based on a slug injection of table salt (NaCl) as a tracer and specific conductance readings at different locations downstream of the injection spot. Observed specific conductance readings are fit using the advection-dispersion equation with OTIS-P, yielding estimates of cross-sectional area and longitudinal dispersion coefficient for various stream reaches. Estimates of the DL are used to assess the accuracy of several empirical equations reported in the literature. This allowed the determination of complementary transport parameters related to transient storage zones. The empirical equations yielded rather high DL values, with some reaching up an order of magnitude higher to those obtained from tracer additions and OTIS-P. Overall, the proposed approach seems reliable and pertinent for river reaches of ca. 150 m in length.  相似文献   
7.
摘要: 目的 建立一种无需标准品即可快速检测保健品中136种非法添加降血压药物的超高效液相色谱-四极杆/静电场轨道阱高分辨质谱分析方法。方法 样品经甲醇溶液适当稀释,超声处理后,经 Waters Acquity BEH C18色谱柱(100 mm×2.1 mm, 1.7 μm)分离,以0.1% (V:V)甲酸水溶液-乙腈作为流动相, 进行梯度洗脱。加热电喷雾离子源正负离子同时采集,一级母离子全扫描和数据依赖的二级子离子扫描模式检测,将采集的样品质谱信息与自建立的136种非法添加降血压药物质谱信息库通过分子离子精准质量数比对、同位素分布比对进行初筛,初筛出的阳性化合物通过二级碎片离子解析进行进一步确证。结果 该方法能够在没有标准品的情况下,在20 min内对保健食品中136种非法添加降压药物同时进行精准筛查,14种降压药物的添加回收实验表明实际样品的检出限在2.0~3.0 ?g/kg,采用本方法对市售实际样品进行检验, 1款声称具有降血脂的保健食品中有坎地沙坦酯检出。结论 该方法通量高、速度快、成本低,可用于保健食品中非法添加降血压药物的快速筛查。  相似文献   
8.
PurposeAs presbyopia occurs, new visual demands create a need for clear vision at multiple distances. Many spectacle wearers adapt into progressive addition lenses (PAL) in order to see clearly at distance, intermediate, and near. A multifocal contact lens provides the ability to see at these same distances without the prismatic effects of a spectacle lens or the peripheral obstruction of a spectacle frame. No studies have been done to date comparing the effect of these types of presbyopic vision correction on a variety of tests of visual performance representative of everyday tasks.MethodsA battery of visual performance tasks were completed by subjects while wearing their habitual PAL spectacles. These subjects were then fit with a multifocal contact lens and wore lenses for 2 weeks or more before completing the tasks again. These functional vision tests included assessments of coincidence anticipation timing, peripheral search and hand-eye coordination, and dynamic visual acuity. Following functional vision testing, subjects completed a preference survey comparing both types of refractive correction while performing common activities of daily living.ResultsPerformance on the majority of the tests of visual performance were equivalent (P < 0.05) when comparing PAL spectacles and multifocal contact lenses. Survey results demonstrated a preference for multifocal contact lenses overall.ConclusionPAL spectacles are widely prescribed for presbyopic patients. The findings of this study suggest that in addition to providing excellent vision, multifocal contact lenses provide functional vision performance equal to PAL spectacle wear and patients may prefer them over PAL spectacles.  相似文献   
9.
通过硅烷偶联和自由基聚合反应,合成了以SiO2为核、聚4-乙烯基吡啶(P4VP)为壳的聚合物刷(P4VP@SiO2)。采用红外光谱(FT-IR)、热重分析(TGA)、透射电镜(TEM)和扫描电镜(SEM)等手段对P4VP@SiO2的结构进行了表征。将P4VP@SiO2用于脱除原油中的镍和钙,分析了电脱盐工艺条件对其原油脱镍率和脱钙率的影响,并考察了P4VP@SiO2的再生性能,提出了聚合物刷的脱金属机理。结果表明:随着P4VP@SiO2加入量和沉降时间的增加,P4VP@SiO2对原油的脱镍率和脱钙率先升高后趋于稳定;随着水/油质量比、乳化剪切强度、电脱盐温度和电场强度的增加,P4VP@SiO2对原油的脱镍率和脱钙率先升高后降低。当P4VP@SiO2用量为6000 μg/g、水/油质量比为0.15、电脱盐温度为120 ℃、乳化剪切强度为8 kr/min、电脱盐低压电场强度为500 V/cm、高压电场强度为1000 V/cm、沉降时间为60 min时,P4VP@SiO2对原油的脱镍率和脱钙率分别达到68.4%和62.2%。此外,经过5次电脱盐循环使用过程,P4VP@SiO2对原油中镍和钙均保持了初始脱除能力的95%。因此,吡啶基聚合物刷是一种应用前景广阔、对镍和钙具有高吸附容量的非酸性和可再生原油脱金属剂。  相似文献   
10.
以3-羟基丙胺和丙烯酸甲酯为起始原料,在微波辅助下进行Michael加成、Dieckmann环合和脱羧反应合成了1-(3-羟丙基)-4-哌啶酮.并对Michael加成、Dieckmann环合和脱羧反应的工艺参数进行了优化,通过核磁共振波谱对目标化合物和中间体的结构进行表征.得到的最优Michael加成工艺条件为:n(3-羟基丙胺):n(丙烯酸甲酯)=1.0:2.4,微波辐射功率为120 W,反应温度40℃,反应时间30 min.在该条件下制备3-[(2-甲氧羰乙基)(3-羟丙基)氨基]丙酸甲酯的收率为92.6%;在微波辐射功率为200 W下,Dieckmann环合反应和脱羧反应分别为20和25 min,以88.5%的收率得到1-(3-羟丙基)-4-哌啶酮;目标产物总收率为82.0%.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号