全文获取类型
收费全文 | 3223篇 |
免费 | 9篇 |
国内免费 | 37篇 |
专业分类
电工技术 | 80篇 |
综合类 | 62篇 |
化学工业 | 834篇 |
金属工艺 | 96篇 |
机械仪表 | 125篇 |
建筑科学 | 42篇 |
矿业工程 | 21篇 |
能源动力 | 1537篇 |
轻工业 | 12篇 |
水利工程 | 2篇 |
石油天然气 | 39篇 |
武器工业 | 66篇 |
无线电 | 19篇 |
一般工业技术 | 165篇 |
冶金工业 | 91篇 |
原子能技术 | 11篇 |
自动化技术 | 67篇 |
出版年
2023年 | 42篇 |
2022年 | 64篇 |
2021年 | 70篇 |
2020年 | 79篇 |
2019年 | 99篇 |
2018年 | 68篇 |
2017年 | 72篇 |
2016年 | 61篇 |
2015年 | 48篇 |
2014年 | 133篇 |
2013年 | 127篇 |
2012年 | 107篇 |
2011年 | 270篇 |
2010年 | 196篇 |
2009年 | 191篇 |
2008年 | 152篇 |
2007年 | 175篇 |
2006年 | 139篇 |
2005年 | 124篇 |
2004年 | 134篇 |
2003年 | 122篇 |
2002年 | 84篇 |
2001年 | 86篇 |
2000年 | 85篇 |
1999年 | 115篇 |
1998年 | 70篇 |
1997年 | 61篇 |
1996年 | 51篇 |
1995年 | 73篇 |
1994年 | 31篇 |
1993年 | 35篇 |
1992年 | 28篇 |
1991年 | 24篇 |
1990年 | 11篇 |
1989年 | 6篇 |
1988年 | 14篇 |
1987年 | 13篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1981年 | 2篇 |
排序方式: 共有3269条查询结果,搜索用时 31 毫秒
1.
Baowei Fan Yonghao Zeng Yaoyuan Zhang Jianfeng Pan Wenming Yang Yuanguang Wang 《International Journal of Hydrogen Energy》2021,46(13):9234-9251
The purpose of the present paper is to investigate the hydrogen injection strategy on the combustion performance of a natural gas/hydrogen rotary engine. Considering that apex seal leakage (ASL) is an inevitable problem in the actual working process of a rotary engine, the action of ASL cannot be ignored for an in-depth study of its combustion performance. Therefore, in this paper, a 3D dynamic simulation model that put the effect of ASL into consideration was established. Furthermore, based on the established 3D model, the combustion process of a natural gas/hydrogen rotary engine under various hydrogen injection angle (HIA) and hydrogen injection timing (HIT) was investigated. The results indicated that the hydrogen jet flow first impacted on the rotor wall after entering the cylinder, and then diffused under the action of the vortexes in the cylinder. Therefore, the HIA and HIT could change the hydrogen distribution by changing the hydrogen impact location and the intensities of the vortexes in the cylinder. In addition, the ideal hydrogen distribution at the ignition timing which could improve the combustion efficiency was given. That is, under the premise of ensuring minimized hydrogen leakage, the hydrogen should mainly distribute in the middle and the front of the cylinder, and a high hydrogen concentration is maintained near the spark plug. 相似文献
2.
Co-firing NH3 with H2/CO/syngas (SYN) is a promising method to overcome the low reactivity of NH3/air flame. Hence, this study aims to systematically investigate the laminar premixed combustion characteristics of NH3/air flame with various H2/CO/SYN addition loadings (0–40%) using chemical kinetics simulation. The numerical results were obtained based on the Han mechanism which can provide accurate predictions of laminar burning velocities. Results showed that H2 has the greatest effects on increasing laminar burning velocities and net heat release rates of NH3/air flame, followed by SYN and CO. CO has the most significant effects on improving NH3/air adiabatic flame temperatures. The H2/CO/SYN additions can accelerate NH3 decomposition rates and promote the generation of H and NH2 radicals. Furthermore, there is an evident positive linear correlation between the laminar burning velocities and the peak mole fraction of H + NH2 radicals. The reaction NH2 + NH <=> N2H2 + H and NH2 + NO <=> NNH + OH have remarkable positive effects on NH3 combustion. The mole fraction of OH × NH2 radicals positively affects the net heat release rates. Finally, it was discovered that H radicals play an important role in the generation of NO. The H2/CO/SYN additions can reduce the hydrodynamic and diffusional-thermal instabilities of NH3/air flame. The NH3 reaction pathways for NH3–H2/CO/SYN-air flames can be categorized mainly into NH3–NH2–NH–N–N2, NH3–NH2–HNO–NO(?N2O)–N2 and NH3–NH2(?N2H2)–NNH–N2. CO has the greatest influence on the proportions of three NH3 reaction routes. 相似文献
3.
《International Journal of Hydrogen Energy》2021,46(73):36515-36527
Numerical investigation on the premixed H2/air combustion in a micro heat-recirculation combustor inserted with/without block is conducted. Effects of block setting, heat-recirculation, and flow rate on combustion characteristics and thermal performance are depicted and analyzed. The results demonstrate that the block enhances the flame stability and preheating effect, which also reduces the heat loss via exhaust gas, while it shortens reactants residence time. The combustor setting with a transverse block gains a better thermal performance than that inserted with a longitudinal block. With the increase of transverse block height, the high-temperature zone is broadened and radiation is improved. However, the block with a height of 10 mm separates the fluid field and weakens the effects of heat recirculation, leading to a lower outer wall temperature. Furthermore, the appropriate block insertion method and height contribute to the significant improvement of heat transfer, radiant efficiency and further optimization of micro power generator. 相似文献
4.
Samira Chamyani Alireza Salehirad Nasrin Oroujzadeh Davod Sadeghi Fateh 《Ceramics International》2018,44(7):7754-7760
Due to importance and wide applications, CoCr2O4 ceramic pigment nanoparticles were synthesized via low-temperature solution combustion route by different fuels including ethylenediamine/oxalic acid, ethylenediamine/citric acid, oxalic acid/citric acid and ethylenediamine/oxalic acid/citric acid. Physicochemical properties of the synthesized samples were determined by different techniques such as fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and energy dispersive X-ray spectroscopy (EDX) and color/optical properties were evaluated based on CIELAB system by spectrophotometer. Moreover, thermodynamic considerations of combustion reactions for CoCr2O4 nanopigments formation in terms of calculated adiabatic flame temperature and enthalpy of combustion reaction were studied. The Comparison of results and data showed that cobalt chromite pigment nanoparticles synthesized by using ethylenediamine/citric acid and ethylenediamine/oxalic acid/citric acid fuels exhibited higher purity, smaller crystallite size and lower degree agglomeration. 相似文献
5.
The air and oxy-fuel combustion processes of two low-grade lignite coals were investigated by thermogravimetric analysis (TGA) method. Coals were provided from two different coal mines in the Aegean region of Turkey. Oxy-fuel combustion experiments were carried out with three different gas mixtures of 21% O2–79% CO2; 40% O2–60% CO2 and 50% O2–50% CO2 at 950 °C and heating rates of 10 °C/min, 20 °C/min and 40 °C/min. The kinetics of the oxy-fuel combustion of coals were studied by using four different methods namely, Coats-Redfern (model-fitting method), Friedman (FR), Flynn–Wall–Ozawa's (FWO) and Kissinger–Akahira–Sunose's (KAS) methods. The apparent activation energies of combustion process calculated by FWO method are slightly but systematically higher than that calculated by the KAS and FR methods for the oxy-fuel atmospheres. Combustion behavior of both coals in the oxy-fuel combustion environment could vary significantly, likely due to their characteristics such ash and volatile matter contents. 相似文献
6.
《Ceramics International》2020,46(11):19228-19231
As a promising high-temperature ceramic, aluminum silicon carbide (Al4SiC4) has attracted much attention. Al4SiC4 is usually synthesized at high temperatures with a long reaction time in an electric furnace. Self-propagating high-temperature synthesis (SHS) is a promising technique for rapid synthesis. In this study, Al4SiC4 was prepared by the SHS method from a mixture of silicon, aluminum and carbon black with the addition of poly(tetrafluoroethylene) (PTFE) as an exothermic promoter. The experimental results showed that the use of a high-pressure Ar atmosphere could retain the gaseous materials in the pellet mixture, and the PTFE additive promoted the formation of silicon carbide. In addition, the oxide layer present on the surface of silicon particles inhibited the reaction between silicon and carbon. As a result, high-purity Al4SiC4 could be synthesized from aluminum, silicon, and carbon black with 15 wt% PTFE under 1.0 MPa Ar atmosphere in several seconds by the SHS method. 相似文献
7.
《International Journal of Hydrogen Energy》2020,45(17):10602-10612
Owing to high specific energy and low emissions production, hydrogen is a desirable alternative fuel. The combustion and emission performance can be improved by hydrogen addition injected in-cylinder, intake manifold and aspirated with air. However, engine loads and hydrogen-air ration have a significant effect on the performance, combustion and emission of the diesel-hydrogen (high speed direct injection) HSDI engine. In this paper, the CFD method is used to calculate the combustion process of a diesel-hydrogen dual HSDI engine working at constant speed of 4000 rpm, at different hydrogen added from intake port (hydrogen volume fraction of 0%–10%) and five engine loads (equivalent to 20%, 40%, 60%, 80% and 100% of its maximum output power), respectively. The modelling results showed that the in-cylinder pressure and temperature under low engine load were more affected by hydrogen addition. With increasing hydrogen volume fraction, the indicated expansion work and in-cylinder peak pressure increased, and combustion duration decreased due to faster fuel-air mixing and spray flame speed. 相似文献
8.
《International Journal of Hydrogen Energy》2020,45(39):20419-20425
Detailed hydrogen-air chemical reaction mechanisms were coupled with three dimension grids of an experimental hydrogen fueled internal combustion engine (HICE) to establish a combustion model based on CONVERGE software. The influence of excess hydrogen coefficient on the combustion and emission characteristics of HICE under full load was studied based on the CFD model. Simulation results showed that excess hydrogen leaded to higher concentration of OH species in flame front, and quicker hydrogen-oxygen reaction and flame propagation speed, which in turn leaded to higher pressure and temperature in cylinder. The rise of pressure and temperature in turn contributed to the increase of indicate power but un-burned hydrogen leaded to decrease of efficiency. NOx, especially NO emissions decreased significantly with excess hydrogen under full load not only because increased of H concentration, and decreased of O and OH concentration, which leaded to reverse reaction of NO formation through thermal NO routes. Low excess hydrogen coefficient can achieve a good trade-off between power and emissions under full load. 相似文献
9.
《International Journal of Hydrogen Energy》2022,47(2):1306-1318
The effective and efficient utilization of low-calorific value (LCV) gases has gained increasing attention in scientific research and industrial fields. In this study, the combustion characteristics of three LCV gases in practical devices are analyzed by using a nonadiabatic perfectly stirred reactor model. The complete steady-state solution in the temperature-residence time parameter space is obtained with arc-length continuation. The stable operation region is quantified by the eigenvalue analysis. The transition of solution curves is quantified with heat loss coefficient. Five key system parameters are systematically investigated on their effects on stability limits. With the combustion performance being quantified by a combustion state index, a combustion state regulation method is proposed to find the optimal regulation path of system parameters. Active subspace method is further applied to shorten the regulation step by identifying the active direction. The proposed method and findings are useful for optimal regulation of burning LCV gases in industrial burners. 相似文献
10.
《International Journal of Hydrogen Energy》2022,47(88):37635-37647
Biofuels extracted from non-edible oil is sustainable and can be used as an alternative fuel for internal combustion engines. This study presents the performance, emission and combustion characteristic analysis by using simarouba oil (obtained from Simarouba seed) as an alternative fuel along with hydrogen and exhaust gas recirculation (EGR) in a compression ignition (CI) engine operating on dual fuel mode. Simarouba biofuel blend (B20) was prepared on volumetric basis by mixing simarouba oil and diesel in the proportion of 20% and 80% (v/v), respectively. Hydrogen gas was introduced at the flow rate of 2.67 kg/min, and EGR concentration was maintained at 30% of total air introduction. Performance, combustion and emission characteristics analysis were examined with biodiesel (B20), biodiesel with hydrogen substitution and biodiesel, hydrogen with EGR and were compared with neat diesel operation. Results indicate that BTE of the engine operating with biodiesel B20 was decreased when compared to neat diesel operation. However, introducing hydrogen along with B20 blend into the combustion chamber shows a slight increase in the BTE by 1%. NOx emission was increased to 18.13% with the introduction of hydrogen than that of base fuel (diesel) operation. With the introduction of EGR, there is a significant reduction in NOx emission due to decrease in in-cylinder temperature by 19.07%. A significant reduction in CO, CO2, and smoke emissions were also noted with the introduction of both hydrogen and EGR. The ignition delay and combustion duration were increased with the introduction of hydrogen, EGR with biodiesel than neat diesel operation. Hence, the proposed biodiesel B20 with H2 and EGR combination can be applied as an alternative fuel in CI engines. 相似文献