首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   10456篇
  免费   855篇
  国内免费   709篇
电工技术   528篇
综合类   513篇
化学工业   1519篇
金属工艺   1791篇
机械仪表   632篇
建筑科学   463篇
矿业工程   127篇
能源动力   210篇
轻工业   382篇
水利工程   148篇
石油天然气   199篇
武器工业   78篇
无线电   1232篇
一般工业技术   2471篇
冶金工业   691篇
原子能技术   121篇
自动化技术   915篇
  2024年   22篇
  2023年   254篇
  2022年   361篇
  2021年   466篇
  2020年   404篇
  2019年   303篇
  2018年   217篇
  2017年   332篇
  2016年   341篇
  2015年   308篇
  2014年   575篇
  2013年   562篇
  2012年   669篇
  2011年   894篇
  2010年   620篇
  2009年   718篇
  2008年   659篇
  2007年   678篇
  2006年   516篇
  2005年   457篇
  2004年   415篇
  2003年   371篇
  2002年   308篇
  2001年   200篇
  2000年   209篇
  1999年   167篇
  1998年   190篇
  1997年   163篇
  1996年   111篇
  1995年   84篇
  1994年   75篇
  1993年   72篇
  1992年   68篇
  1991年   61篇
  1990年   29篇
  1989年   42篇
  1988年   23篇
  1987年   18篇
  1986年   11篇
  1985年   5篇
  1984年   8篇
  1983年   4篇
  1982年   4篇
  1981年   3篇
  1980年   9篇
  1979年   2篇
  1978年   5篇
  1976年   1篇
  1975年   4篇
  1962年   1篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
在液压支架对接焊缝缺陷的检测中,传统的超声相控阵二维检测得到的缺陷信息单一,无法直观反映缺陷在三维空间中的位置、形态及尺寸。采用全聚焦相控阵三维成像技术对对接焊缝中的缺陷进行检测。设计了含有内部裂纹、根部未焊透、夹渣3种缺陷的试块,分别用线阵探头与面阵探头对试块进行了检测,以此来验证全聚焦三维成像对缺陷的检测效果。通过比较得出,全聚焦三维成像能够更准确地检测出缺陷的位置、大小信息。  相似文献   
2.
针对热镀锌机组连续退火过程中带钢C翘导致镀层不均的问题,研究了热镀锌冷却过程核心工艺对带钢C翘板形的影响机理,建立了喷嘴冷却模型、喷嘴与带钢实际垂直距离分布模型等关键工艺模型,提出以翘曲抑制率、翘曲控制灵敏度为量化指标的C翘影响模型,给出了完整的风机关键工艺参数综合优化方法,实现了带钢精细化分区冷却控制。某热镀锌机组的应用表明该方法可有效降低机组出口带材翘曲程度。  相似文献   
3.
4.
《Ceramics International》2022,48(6):8297-8305
Pure and Sn/Fe co-doped (0.2 at.% Sn and 0.6 at.% Fe, 0.6 at.% Sn and 0.2 at.% Fe, 1.0 at.% Sn and 1.0 at.% Fe) TiO2 nanoparticles were synthesized via a sol-gel method and subsequently calcined at different temperatures. Furthermore, the particles were analyzed by TG-DSC, XRD, TEM, HRTEM, EDS, SAED and UV–Vis for investigating the influences of dopant and calcination temperature on the thermal effect, composition, morphology, energy band gap (Eg) and the degradation efficiency of methyl orange (MO) under various light irradiations respectively. Results indicated that Sn/Fe co-doping inhibited the crystallization transformation from anatase to rutile phase of TiO2 and decreased the Eg. The increased calcination temperature and Sn/Fe co-doped effect brought about the abnormal grain growth of TiO2 nanoparticles. 0.6 at.% Sn/0.2 at.% Fe and 1.0 at.% Sn/1.0 at.% Fe co-doped TiO2 nanoparticles presented better photocatalytic performance than pure and 0.2 at.% Sn/0.6 at.% Fe co-doped TiO2 nanoparticles under visible light irradiation mainly due to the decreased Eg. On the contrary, 0.2 at.% Sn and 0.6 at.% Fe co-doped TiO2 nanoparticles calcined at 650 °C showed the most excellent photocatalytic performance under UV light irradiation, which was about twice as large as that of pure TiO2 possibly due to the formed hybrid structure of anatase and rutile phase as well as the h+-mediated decomposition pathway.  相似文献   
5.
《Ceramics International》2022,48(10):14349-14359
The influence of heat-treatment temperatures (700 °C, 900°C, 1200 °C) on the phase, physical properties, crystallization rate, and in vitro properties of the solution combustion synthesized silicon-doped calcium phosphates (CaPs) were investigated. The thermodynamic aspects (enthalpy, entropy, and free energy) of the synthesis process and the crystallographic properties of the final samples were first predicted and then confirmed using density functional theory (DFT). Results demonstrated that the crystallization rate was controlled by the fuel(s) type (glycine, citric acid, and urea) and the amounts of Si4+ ions (0, 0.1, 0.4 mol). The highest calculated crystallization rate values of the un-doped, 0.1, and 0.4 mol Si-doped samples were 64%, 22%, 38%, respectively. The obtained results from the DFT simulation revealed that crystal growth in the direction of c-axis of hydroxyapatite (HAp) structure could change the stability of (001) surface of (HAp). Also, the computational data confirmed the adsorption of Si–OH groups on the (001) surface of HAp during the SCS process with an adsorption energy of 1.53 eV. AFM results in line with DFT simulation showed that the observed change in the surface roughness of Si-doped CaPs from 2 to 8 nm could be related to the doping of Si4+ ions onto the surface of CaPs. Besides, the theoretical and experimental investigation showed that crystal growth and doping of Si4+ ions could decrease the activation energy of oxygen reduction reaction (ORR). Furthermore, the results showed that the crystallized HAp structure could have great potential to efficiently reduce oxidative stress in human body.  相似文献   
6.
在大规模工业生产中,动力电池零部件的激光焊接容易产生气孔、成形不良、炸孔等缺陷,大大降低车辆运行的安全性与可靠性。文中分析了动力电池中激光焊接应用的具体位置,依据不同的焊接部位分类介绍了缺陷种类,讨论了未焊透、气孔、下塌、炸孔、裂纹等缺陷的产生原因。针对电池壳体与盖板连接、电池防爆阀密封、电池注液孔密封、电池极柱焊接及极耳与汇流排连接等具体的应用场景,总结了减少缺陷、提高焊接质量的手段,主要包括工艺改进、光源特性调控、焊接顺序优化等。在此基础上,进一步介绍了智能化制造技术在动力电池激光加工中的应用,并对动力电池领域未来激光焊接技术的发展进行了展望。 创新点: (1)以焊接位置分类介绍了动力电池部件在激光焊接过程中的缺陷种类和产生原因。 (2)按照工艺、光源和焊接顺序等分类总结了减少动力电池激光焊接缺陷的主要方法。 (3)归纳了智能化激光焊接技术在动力电池中的应用,并展望了其发展前景。  相似文献   
7.
The table-like magnetocaloric effect is significant for the magnetic refrigeration applications above 20 K based on the Ericsson cycle. Herein, we prepared a series of Nd6Fe13Pd1–xCux (x = 0.05, 0.1, 0.15) compounds by the arc-melting method. These compounds show the single crystalline phase in the tetragonal Nd6Fe13Si-type structure with the space group I4/mcm. A magnetic phase transition from ferromagnetism to antiferromagnetism and a metamagnetic transition from the antiferromagnetic state to the ferromagnetic state are observed in each of the compounds. The compounds exhibit table-like magnetocaloric effects with large refrigerant capacities. A constant ΔSM in a temperature span of 40 K in the Nd6Fe13Pd0.85Cu0.15 compound are observed. For a field change of 0–5 T, the peak values of –ΔSM for the Nd6Fe13Pd0.95Cu0.05, Nd6Fe13Pd0.90Cu0.10, and Nd6Fe13Pd0.85Cu0.15 compounds are estimated to be 4.8, 4.6 and 4.4 J/(kg·K) with corresponding refrigerant capacity values of 323, 331 and 316 J/kg, respectively. The obtained table-like magnetocaloric effects with large refrigerant capacities as well as fairly small thermal and magnetic hysteresis deem these series of compounds good candidates for single-phase magnetic refrigeration based on the Ericsson cycle.  相似文献   
8.
Due to the demand of miniaturization and integration for ceramic capacitors in electronic components market, TiO2-based ceramics with colossal permittivity has become a research hotspot in recent years. In this work, we report that Ag+/Nb5+ co-doped (Ag1/4Nb3/4)xTi1−xO2 (ANTOx) ceramics with colossal permittivity over a wide frequency and temperature range were successfully prepared by a traditional solid–state method. Notably, compositions of ANTO0.005 and ANTO0.01 respectively exhibit both low dielectric loss (0.040 and 0.050 at 1 kHz), high dielectric permittivity (9.2 × 103 and 1.6 × 104 at 1 kHz), and good thermal stability, which satisfy the requirements for the temperature range of application of X9R and X8R ceramic capacitors, respectively. The origin of the dielectric behavior was attributed to five dielectric relaxation phenomena, i.e., localized carriers' hopping, electron–pinned defect–dipoles, interfacial polarization, and oxygen vacancies ionization and diffusion, as suggested by dielectric temperature spectra and valence state analysis via XPS; wherein, electron-pinned defect–dipoles and internal barrier layer capacitance are believed to be the main causes for the giant dielectric permittivity in ANTOx ceramics.  相似文献   
9.
压塑与注塑采用不同类型的塑料,前者采用热固性塑料,后者采用热塑性塑料。压塑成型工艺及模具设计是一门不断发展的综合科学,不仅随着高分子材料合成技术的提高,压塑成型设备的更新,成型工艺的成熟而改进,而且随着计算机技术,快速造型技术,数值模拟技术,数字化应用技术,智能技术等在压塑成型加工领域渗透而发展。本讲座内容主要包括:压制成型工艺及分类,压制件设计,压制模结构设计及其零件设计,压制成型设备,压制塑件质量控制及缺陷分析,压制成型模应用举例;压注成型原理及工艺过程,压注成型模具结构设计,压注成型压力的计算,压注成型设备的选择,压注塑件质量及缺陷分析,压注成型模应用举例。  相似文献   
10.
《Ceramics International》2022,48(10):13719-13731
Li0.04Ca0.96-xSiO3:Smx orange?red emitting phosphors were synthesized using the sol-gel method. X-ray diffraction, Rietveld refinement of XRD patterns, Fourier transform infrared spectroscopy and ?uorescence spectrophotometry were used to characterize the crystal structure, sites of cationic Ca and luminescence properties of the prepared phosphors. The relationship of the different Ca sites in the matrix with the luminescence properties was analysed. The results indicate that the prepared phosphors reveal a β-CaSiO3 phase with a monoclinic crystal structure and space Group P21/a. As the Sm3+ concentration increases, the unit cell volume of phosphors and the Ca–O band lengths of different Ca sites decrease due to substitution of Ca2+ by smaller Sm3+ ions. By excitation at 404 nm, Li0.04Ca0.96-xSiO3:Smx phosphors exhibit warm orange?red light, corresponding to the electron transitions from 4G5/2 → 6H5/2 (567 nm), 4G5/2 → 6H7/2 (605 nm) and 4G5/2 → 6H9/2 (651 nm) of Sm3+. The concentration quenching phenomenon appears at Sm3+ concentrations beyond 0.02. The refinement results demonstrate that three cationic Ca sites, named Ca1, Ca2 and Ca3, exist in the β-CaSiO3 host lattice. The Ca2+ ions at Ca1 and Ca2 sites are coordinated with six oxygen ions, leading to the same coordination number (CN). The Ca2+ ion located at Ca3 site has seven coordination numbers. The Ca1 site possesses a smaller lattice distortion and better symmetry than those of Ca2 and Ca3 sites. However, the Ca3 site exhibits the largest lattice distortion and poor symmetry. The Sm3+ present in symmetric Ca1 sites in the matrix illustrates the strong emission intensity, long luminescence lifetimes and good thermal stability.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号