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《Ceramics International》2022,48(6):8297-8305
Pure and Sn/Fe co-doped (0.2 at.% Sn and 0.6 at.% Fe, 0.6 at.% Sn and 0.2 at.% Fe, 1.0 at.% Sn and 1.0 at.% Fe) TiO2 nanoparticles were synthesized via a sol-gel method and subsequently calcined at different temperatures. Furthermore, the particles were analyzed by TG-DSC, XRD, TEM, HRTEM, EDS, SAED and UV–Vis for investigating the influences of dopant and calcination temperature on the thermal effect, composition, morphology, energy band gap (Eg) and the degradation efficiency of methyl orange (MO) under various light irradiations respectively. Results indicated that Sn/Fe co-doping inhibited the crystallization transformation from anatase to rutile phase of TiO2 and decreased the Eg. The increased calcination temperature and Sn/Fe co-doped effect brought about the abnormal grain growth of TiO2 nanoparticles. 0.6 at.% Sn/0.2 at.% Fe and 1.0 at.% Sn/1.0 at.% Fe co-doped TiO2 nanoparticles presented better photocatalytic performance than pure and 0.2 at.% Sn/0.6 at.% Fe co-doped TiO2 nanoparticles under visible light irradiation mainly due to the decreased Eg. On the contrary, 0.2 at.% Sn and 0.6 at.% Fe co-doped TiO2 nanoparticles calcined at 650 °C showed the most excellent photocatalytic performance under UV light irradiation, which was about twice as large as that of pure TiO2 possibly due to the formed hybrid structure of anatase and rutile phase as well as the h+-mediated decomposition pathway. 相似文献
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《Ceramics International》2022,48(10):14349-14359
The influence of heat-treatment temperatures (700 °C, 900°C, 1200 °C) on the phase, physical properties, crystallization rate, and in vitro properties of the solution combustion synthesized silicon-doped calcium phosphates (CaPs) were investigated. The thermodynamic aspects (enthalpy, entropy, and free energy) of the synthesis process and the crystallographic properties of the final samples were first predicted and then confirmed using density functional theory (DFT). Results demonstrated that the crystallization rate was controlled by the fuel(s) type (glycine, citric acid, and urea) and the amounts of Si4+ ions (0, 0.1, 0.4 mol). The highest calculated crystallization rate values of the un-doped, 0.1, and 0.4 mol Si-doped samples were 64%, 22%, 38%, respectively. The obtained results from the DFT simulation revealed that crystal growth in the direction of c-axis of hydroxyapatite (HAp) structure could change the stability of (001) surface of (HAp). Also, the computational data confirmed the adsorption of Si–OH groups on the (001) surface of HAp during the SCS process with an adsorption energy of 1.53 eV. AFM results in line with DFT simulation showed that the observed change in the surface roughness of Si-doped CaPs from 2 to 8 nm could be related to the doping of Si4+ ions onto the surface of CaPs. Besides, the theoretical and experimental investigation showed that crystal growth and doping of Si4+ ions could decrease the activation energy of oxygen reduction reaction (ORR). Furthermore, the results showed that the crystallized HAp structure could have great potential to efficiently reduce oxidative stress in human body. 相似文献
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在大规模工业生产中,动力电池零部件的激光焊接容易产生气孔、成形不良、炸孔等缺陷,大大降低车辆运行的安全性与可靠性。文中分析了动力电池中激光焊接应用的具体位置,依据不同的焊接部位分类介绍了缺陷种类,讨论了未焊透、气孔、下塌、炸孔、裂纹等缺陷的产生原因。针对电池壳体与盖板连接、电池防爆阀密封、电池注液孔密封、电池极柱焊接及极耳与汇流排连接等具体的应用场景,总结了减少缺陷、提高焊接质量的手段,主要包括工艺改进、光源特性调控、焊接顺序优化等。在此基础上,进一步介绍了智能化制造技术在动力电池激光加工中的应用,并对动力电池领域未来激光焊接技术的发展进行了展望。
创新点: (1)以焊接位置分类介绍了动力电池部件在激光焊接过程中的缺陷种类和产生原因。
(2)按照工艺、光源和焊接顺序等分类总结了减少动力电池激光焊接缺陷的主要方法。
(3)归纳了智能化激光焊接技术在动力电池中的应用,并展望了其发展前景。 相似文献
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《中国稀土学报(英文版)》2022,40(4):660-669
The table-like magnetocaloric effect is significant for the magnetic refrigeration applications above 20 K based on the Ericsson cycle. Herein, we prepared a series of Nd6Fe13Pd1–xCux (x = 0.05, 0.1, 0.15) compounds by the arc-melting method. These compounds show the single crystalline phase in the tetragonal Nd6Fe13Si-type structure with the space group I4/mcm. A magnetic phase transition from ferromagnetism to antiferromagnetism and a metamagnetic transition from the antiferromagnetic state to the ferromagnetic state are observed in each of the compounds. The compounds exhibit table-like magnetocaloric effects with large refrigerant capacities. A constant ΔSM in a temperature span of 40 K in the Nd6Fe13Pd0.85Cu0.15 compound are observed. For a field change of 0–5 T, the peak values of –ΔSM for the Nd6Fe13Pd0.95Cu0.05, Nd6Fe13Pd0.90Cu0.10, and Nd6Fe13Pd0.85Cu0.15 compounds are estimated to be 4.8, 4.6 and 4.4 J/(kg·K) with corresponding refrigerant capacity values of 323, 331 and 316 J/kg, respectively. The obtained table-like magnetocaloric effects with large refrigerant capacities as well as fairly small thermal and magnetic hysteresis deem these series of compounds good candidates for single-phase magnetic refrigeration based on the Ericsson cycle. 相似文献
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Pengfei Liang Jie Zhu Di Wu Hui Peng Xiaolian Chao Zupei Yang 《Journal of the American Ceramic Society》2021,104(6):2702-2710
Due to the demand of miniaturization and integration for ceramic capacitors in electronic components market, TiO2-based ceramics with colossal permittivity has become a research hotspot in recent years. In this work, we report that Ag+/Nb5+ co-doped (Ag1/4Nb3/4)xTi1−xO2 (ANTOx) ceramics with colossal permittivity over a wide frequency and temperature range were successfully prepared by a traditional solid–state method. Notably, compositions of ANTO0.005 and ANTO0.01 respectively exhibit both low dielectric loss (0.040 and 0.050 at 1 kHz), high dielectric permittivity (9.2 × 103 and 1.6 × 104 at 1 kHz), and good thermal stability, which satisfy the requirements for the temperature range of application of X9R and X8R ceramic capacitors, respectively. The origin of the dielectric behavior was attributed to five dielectric relaxation phenomena, i.e., localized carriers' hopping, electron–pinned defect–dipoles, interfacial polarization, and oxygen vacancies ionization and diffusion, as suggested by dielectric temperature spectra and valence state analysis via XPS; wherein, electron-pinned defect–dipoles and internal barrier layer capacitance are believed to be the main causes for the giant dielectric permittivity in ANTOx ceramics. 相似文献
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压塑与注塑采用不同类型的塑料,前者采用热固性塑料,后者采用热塑性塑料。压塑成型工艺及模具设计是一门不断发展的综合科学,不仅随着高分子材料合成技术的提高,压塑成型设备的更新,成型工艺的成熟而改进,而且随着计算机技术,快速造型技术,数值模拟技术,数字化应用技术,智能技术等在压塑成型加工领域渗透而发展。本讲座内容主要包括:压制成型工艺及分类,压制件设计,压制模结构设计及其零件设计,压制成型设备,压制塑件质量控制及缺陷分析,压制成型模应用举例;压注成型原理及工艺过程,压注成型模具结构设计,压注成型压力的计算,压注成型设备的选择,压注塑件质量及缺陷分析,压注成型模应用举例。 相似文献
10.
《Ceramics International》2022,48(10):13719-13731
Li0.04Ca0.96-xSiO3:Smx orange?red emitting phosphors were synthesized using the sol-gel method. X-ray diffraction, Rietveld refinement of XRD patterns, Fourier transform infrared spectroscopy and ?uorescence spectrophotometry were used to characterize the crystal structure, sites of cationic Ca and luminescence properties of the prepared phosphors. The relationship of the different Ca sites in the matrix with the luminescence properties was analysed. The results indicate that the prepared phosphors reveal a β-CaSiO3 phase with a monoclinic crystal structure and space Group P21/a. As the Sm3+ concentration increases, the unit cell volume of phosphors and the Ca–O band lengths of different Ca sites decrease due to substitution of Ca2+ by smaller Sm3+ ions. By excitation at 404 nm, Li0.04Ca0.96-xSiO3:Smx phosphors exhibit warm orange?red light, corresponding to the electron transitions from 4G5/2 → 6H5/2 (567 nm), 4G5/2 → 6H7/2 (605 nm) and 4G5/2 → 6H9/2 (651 nm) of Sm3+. The concentration quenching phenomenon appears at Sm3+ concentrations beyond 0.02. The refinement results demonstrate that three cationic Ca sites, named Ca1, Ca2 and Ca3, exist in the β-CaSiO3 host lattice. The Ca2+ ions at Ca1 and Ca2 sites are coordinated with six oxygen ions, leading to the same coordination number (CN). The Ca2+ ion located at Ca3 site has seven coordination numbers. The Ca1 site possesses a smaller lattice distortion and better symmetry than those of Ca2 and Ca3 sites. However, the Ca3 site exhibits the largest lattice distortion and poor symmetry. The Sm3+ present in symmetric Ca1 sites in the matrix illustrates the strong emission intensity, long luminescence lifetimes and good thermal stability. 相似文献