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1.
Lun Feng William G. Fahrenholtz Gregory E. Hilmas Frédéric Monteverde 《Journal of the European Ceramic Society》2021,41(1):92-100
Dense high-entropy (Hf,Zr,Ti,Ta,Nb)B2 ceramics with Nb contents ranging from 0 to 20 at% were produced by a two-step spark plasma sintering process. X-ray diffraction indicated that a single-phase with hexagonal structure was detected in the composition without Nb. In contrast, two phases with the same hexagonal structure, but slightly different lattice parameters were present in compositions containing Nb. The addition of Nb resulted in the presence of a Nb-rich second phase and the amount of the second phase increased as the Nb content increased. The relative densities were all >99.5 %, but decreased from ~100 % to ~99.5 % as the Nb content increased from 0 to 20 at%. The average grain size decreased from 13.9 ± 5.5 μm for the composition without Nb additions to 5.2 ± 2.0 μm for the composition containing 20 at% Nb. The reduction of grain size with increasing Nb content was due to the suppression of grain growth by the Nb-rich second phase. The addition of Nb increased Young’s modulus and Vickers hardness, but decreased shear modulus. While some Nb dissolved into the main phase, a Nb-rich second phase was formed in all Nb-containing compositions. 相似文献
2.
Stefanie Bußmann Harald Kruggel-Emden Mathis Reichert 《Advanced Powder Technology》2021,32(7):2171-2191
The particle based Discrete Element Method (DEM) can be applied to examine comminution processes. In this study, a DEM framework has been extended to model particle breakage without mass loss. After a breakage event occurs, spherical particles, as often considered in the DEM, are replaced by size reduced spherical fragments. During the following time steps, the fragments grow to their desired sizes, so that the mass loss can be counterbalanced. Previously defined overlaps with adjacent unbroken and broken particles (fragments) as well as walls are allowed. The breakage model has been realized in a parallelized DEM framework because comminution processes are often attributed to large numbers of particles and by parallelization the computational time can be reduced efficiently. An oedometer (one-dimensional compression in axial direction of a confined particle bed) has been modelled to investigate the parallelization efficiency and the influence of the permitted overlaps during the growth process on the growth duration. A simplified roller mill has been considered to examine the applicability of the breakage procedure considering parallelization. The results show that parallelization reduces computational time considerably. The breakage procedure is suitable to model comminution processes involving even densely packed particle systems and is superior to existing approaches. 相似文献
3.
Lei He Yan Xuan Feng Zhang Xue Wang Huaqing Pan Junfeng Ren Meina Chen 《International Journal of Hydrogen Energy》2021,46(1):1096-1105
Bulk and surface properties of proton stability and transportation in Y and Nd co-doped BaCeO3 (BCYN), especially the effect of Nd segregation, were investigated by first-principles calculations. Since the structure of doped BaCeO3 at the operating temperature of proton-conducting has been unclear for a long time, we have summarized the latest experimental results and calculated the structure of the asymmetric BCYN for the first time. The results show that compared with Y, Nd doping promotes oxygen vacancy formation, however reduces proton stability. Our calculation can also provide a possible explanation for the formation of space charge layer at the grain boundary of doped BaCeO3 in experiment. Unlike the stable Y in BCYN, Nd is calculated to be easily segregated, which can facilitate both proton hydration and proton transportation near the surface. Moreover, Nd segregation at the grain boundary is predicted to be beneficial for proton transportation between grains. 相似文献
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5.
Numerical simulation techniques such as Finite Element Analyses are essential in today's engineering design practices. However, comprehensive knowledge is required for the setup of reliable simulations to verify strength and further product properties. Due to limited capacities, design-accompanying simulations are performed too rarely by experienced simulation engineers. Therefore, product models are not sufficiently verified or the simulations lead to wrong design decisions, if they are applied by less experienced users. This results in belated redesigns of already detailed product models and to highly cost- and time-intensive iterations in product development.Thus, in order to support less experienced simulation users in setting up reliable Finite Element Analyses, a novel ontology-based approach is presented. The knowledge management tools developed on the basis of this approach allow an automated acquisition and target-oriented provision of necessary simulation knowledge. This knowledge is acquired from existing simulation models and text-based documentations from previous product developments by Text and Data Mining. By offering support to less experienced simulation users, the presented approach may finally lead to a more efficient and extensive application of reliable FEA in product development. 相似文献
6.
针对单立柱堆垛机运行过程中加减速对立柱产生的振动激励问题,以某单立柱堆垛机为研究对象进行有限元振动分析。建立该堆垛机的有限元仿真模型,基于不同加减速策略进行对比分析。分析结果表明,十五段S形加减速策略对单立柱堆垛机的振动激励最小,能够提高堆垛机的定位效率。 相似文献
7.
《Ceramics International》2020,46(10):16364-16371
β-tricalcium phosphate (β-TCP), a well-accepted synthetic bone grafting biomaterial, is confronted with limitations of poor phase stability and lacking the capacity to mediate the biological functions. In the current study, gallium (Ga) was substituted for calcium in the β-TCP, and the influences of Ga substitution on the phase stability, compressive strength and cellular response of β-TCP bioceramics were investigated. The results indicated that substitution of at least 2.5 mol% Ga for calcium prevented the β-TCP from transforming into α-TCP at 1250 °C. The β-TCP bioceramics substituted with 2.5 mol% Ga attained the highest compressive strength. The β-TCP bioceramics substituted with 2.5 and 5 mol% Ga showed good cytocompatibility, and suppressed in vitro osteoclastic activity as well as osteoblastic differentiation. Considering the favorable mechanical strength and the inhibitory effect on the osteoclastic activity, the β-TCP bioceramics substituted with 2.5 mol% Ga are promising for treating the bone defect in the pathological state of excessively rapid bone resorption. 相似文献
8.
This study is aimed at unveiling the influence of binary mixtures of nonspherical particles on hopper discharge behavior, which remains poorly understood. The discrete element method (DEM) is employed to simulate seven particle types with aspect ratios between 0 and 2 (namely, a sphere, two ellipsoids, two cylinders, and two cuboids) with the same volume. Seven monodisperse systems and twelve binary-shape mixtures are assessed. For the monodisperse systems, particle shape is the dominant factor dictating discharge rate, compared to other factors like aspect ratio, preferential orientation, and packing. Regarding the binary-shape mixtures, the discharge rates are similar for all twelve mixtures, reflecting a surprising lack of shape effects, which in turn means the negligible impact of solid volume fraction, aspect ratio, and segregation extent. Moreover, collision force is generally negatively correlated with discharge rate. 相似文献
9.
TiB2 exhibits a unique combination of excellent properties that make it promising candidate for applications in extreme environments, where retention of strength at high temperatures is essential. Tailoring grain boundary properties by segregation is believed a prominent way to design high-temperature performance of ceramics. In this work, segregation tendencies of solute elements, including Sc, Y, Zr, Hf, V, Nb, Ta, Cr, Mo, and W, in TiB2 grain boundaries and the strengthening/weakening effects induced by segregations are investigated by first-principles calculations. The results reveal that small atoms tend to segregate to grain boundary sites with local compression strains, while large atoms prefer grain boundary sites with local expansion strains. Deteriorated grain boundary strength is usually caused by additional expansion strain induced by segregation, while improved grain boundary strength results from either enhanced local bonding induced by segregation of small atoms or increased fracture strain due to segregation of large atoms. Cr and V, especially Cr, exhibit strong segregation tendency and improvement on grain boundary strength, which provides useful guidelines for the design of high performance TiB2-based materials. 相似文献
10.