首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   402篇
  免费   21篇
  国内免费   50篇
电工技术   7篇
综合类   21篇
化学工业   56篇
金属工艺   126篇
机械仪表   1篇
矿业工程   5篇
能源动力   8篇
轻工业   2篇
武器工业   1篇
无线电   25篇
一般工业技术   92篇
冶金工业   78篇
原子能技术   42篇
自动化技术   9篇
  2023年   19篇
  2022年   15篇
  2021年   20篇
  2020年   18篇
  2019年   11篇
  2018年   9篇
  2017年   7篇
  2016年   10篇
  2015年   7篇
  2014年   14篇
  2013年   28篇
  2012年   29篇
  2011年   28篇
  2010年   27篇
  2009年   35篇
  2008年   39篇
  2007年   29篇
  2006年   25篇
  2005年   16篇
  2004年   21篇
  2003年   13篇
  2002年   8篇
  2001年   8篇
  2000年   6篇
  1999年   5篇
  1998年   4篇
  1997年   5篇
  1996年   1篇
  1995年   2篇
  1994年   3篇
  1993年   3篇
  1991年   2篇
  1990年   2篇
  1989年   1篇
  1988年   1篇
  1987年   1篇
  1984年   1篇
排序方式: 共有473条查询结果,搜索用时 15 毫秒
1.
Gd2O2S:Tb (GOS) phosphor screen, generally with a multilayer structure, has been widely used in digital X-ray imaging. GOS phosphor screen is fabricated via a slip casting route, which is an effective method to obtain multilayer composites with good strength. The GOS slurry was prepared using the menhaden oil, polyvinyl butyral and PEG-400 as dispersant, binder and plasticizer, respectively, and slip casted on a support layer. After the GOS scintillation layer is formed, a transparent polyethylene terephthalate film is covered on it as a protective layer. The X-ray excited emission spectra of the obtained GOS phosphor screen is well match to the spectral response of a-Si:H photodiode, and the spatial resolution was close to 3.7 LP/mm, which could meet the request of the commercial application.  相似文献   
2.
In this paper, the fabrication of novel burnable absorber fuel concepts with oxide pellets, containing either a lumped Gd2O3 rod, a mini‐pellet, or a spherical particle in the centerline of the oxide pellet, is investigated to propose the lumped Gd2O3 burnable absorber fuel concept to improve nuclear fuel performance with longer fuel cycle lengths and better fuel utilization. The unique characteristic of the lumped Gd2O3 burnable absorber fuel is its high spatial self‐shielding factor that reduces its burnout rate and, therefore, improves the reactivity control. Oxide pellets containing lumped Gd2O3 were fabricated by using a combination of cold isostatic pressing and microwave sintering at 1500°C to understand the potential technical issues in the fabrication of duplex burnable absorber fuel. The effect of the sintering temperature on the densification and phase transformation of 8 wt.% yttria‐stabilized zirconia, a surrogate for UO2, was investigated. Spherical Gd2O3 particles were fabricated by the drip casting of a Gd2O3‐based Na alginate solution. The fabrication of duplex oxide pellets by using presintered Gd2O3 mini‐pellets resulted in internal cracks at the interface between the Gd2O3 and 8 wt.% yttria‐stabilized zirconia layers because of the mismatch of their densification. However, the formation of interfacial cracks was eliminated by controlling the initial sintered density of the lumped Gd2O3.  相似文献   
3.
Diffusion bonding of as-cast Mg?6Gd?3Y magnesium alloy was carried out at temperatures of 400?480 °C with bonding pressure of 6 MPa for 90 min. Diffusion bonded joints were solution treated at 495 °C for 14 h and then aged at 200 °C for 30 h. Microstructures and mechanical properties of joints were analyzed. The results showed that rare earth elements and their compounds gathering at bonding interface hindered the grain boundary migration crossing bonding interface. Tensile strength of as-bonded and as-solution treated joints increased firstly and then decreased with the bonding temperature increasing due to the combined effects of grain coarsening and solid-solution strengthening. As-bonded and solution-treated joints fractured at matrix except the joint bonded at 400 °C, while aged joints fractured at bonding interface. The highest ultimate tensile strength of 279 MPa with elongation of 2.8% was found in joint bonded at 440 °C with solution treatment followed by aging treatment.  相似文献   
4.
采用锂盐熔剂保护熔铸Mg-8Li-4Zn-xGd(x=1,3,5)合金铸锭,研究钆含量对铸态合金组织和力学性能的影响。结果表明:Mg-8Li-4Zn-xGd合金基体由α-Mg(HCP)和β-Li(BCC)双相构成。随着钆含量的增加,Mg5Gd共晶相和Zn12Gd化合物相逐渐连成网状,将基体α+β双相隔离成20~40μm的等轴状或类似于铸铁中的共晶团状,可有效细化α-Mg相和连续的β-Li相;组织中大颗粒Mg2Zn11相弥散分布在β-Li相内,Mg51Zn20相分布在α-Mg晶界处;锌元素还可以在β-Li相中析出细小弥散分布的MgZn相,其数量随钆含量的增加而增加,可直接弥散强化β-Li相。此外,锌和钆对合金硬度的影响较大,随着钆含量的增加,合金的抗拉强度提高,但伸长率降低。  相似文献   
5.
采用高温蠕变装置,研究了Mg-6Al-1Nd-1.5Gd合金在150、175、200℃以及50、70、90 MPa条件下的高温压缩蠕变行为,分析合金在高温蠕变过程中的蠕变机制。结果表明,Mg-6Al-1Nd-1.5Gd合金的平均应力指数及蠕变激活能分别为4.64和73.87kJ/mol,其主要蠕变机制是由位错攀移和晶界扩散共同作用,合金的蠕变本构方程为:ε=1.877×10-8σ4.641exp[-73 865/(RT)];合金在高温蠕变过程中,微观组织中的位错密度逐渐增大,出现位错缠结及位错堆积,合金蠕变后的晶粒变得粗大,金属间化合物Al3Nd和Al3Gd在晶界上出现偏聚。  相似文献   
6.
In this study, different molar ratios of Nd:Ce were directly mixed with prepared pure Gd2Zr2O7 powders without space occupancy design. Samples were obtained by performing sparking plasma sintering (SPS) at 1750°C for 5 minutes. X-ray diffraction (XRD) results show that maximum solid solubility of simulated radionuclides can reach 50 mol%. In addition, all samples with the maximum solid solubility have high compactness, and all elements are evenly distributed on the surface of the samples. The samples show a better crystallization effect as the molar ratio of Nd:Ce increases. The maximum solid solubility increases from 42 mol% to 50 mol% when the amount of Nd2O3 reaches 66 mol%.  相似文献   
7.
The fabrication of Gd2O3‐MgO nanocomposite optical ceramics via hot‐pressing using sol‐gel derived cubic‐Gd2O3 and MgO nanopowders was investigated. The precursor powder calcined at 600°C had an average particle size of 12 nm. The effects of hot‐pressing temperature on constituent phases, microstructure, mid‐infrared transmittance, and microhardness were studied. The crystallographic modifications of Gd2O3 phase varied with the increase in sintering temperature from 1250 to 1350°C. The monoclinic‐Gd2O3 phase was retained for the composite sintered at 1350°C and the sample had an average grain size of 90 nm, excellent transmission (80.4%‐84.8%) over 3‐6 μm wavelength range, and enhanced hardness value of 14.1 GPa.  相似文献   
8.
La2Ce2O7(LC) 由于具有比 YSZ 更低的热导率、 更高的热膨胀系数和良好的高温相稳定性, 是一种极具前 景的热障涂层陶瓷材料。 但该材料热膨胀系数在 200~400℃温度区间存在异常下降现象, 从而引起涂层过早失效 的问题。 目前, 通过掺杂 Gd2O3 可有效解决 LC 低温段热膨胀系数下降的问题, 但是, Gd2O3 改性 La2Ce2O7 热障 涂层最优掺杂浓度及涂层性能还未见报道。 本文采用化学共沉淀法制备了三种不同浓度 Gd2O3 改性 La2Ce2O7 材 料 ((LaxGd1-x)2Ce2O7(x=0,0.1,0.2,0.3)), 研究了掺杂浓度对其热物理性能及相稳定性的影响, 采用等离子喷涂工艺 制备了(La0.8Gd0.2)2Ce2O7 (LGC)涂层, 研究了涂层的抗热震性能和涂层的失效机理。 研究结果表明: (La0.8Gd0.2)2Ce2O7 (LGC) 材料具有较低的热导率, 室温到 1400℃无相变, 并且经 1400℃长时间热处理无相变; 其制备的双陶瓷结 构 LGC/YSZ 热障涂层 1100℃热震次数可达到 109 次, 较未改性 LC/YSZ 热障涂层提升了大约 60%; 两种涂层的 失效模式相似, 均为陶瓷顶层烧结引起的片状剥落失效。  相似文献   
9.
用溶胶-凝胶法合成了固体电解质Ce0.8Gd0.2-xYxO2-δ(x=0,0.05,0.10).用X射线衍射谱、拉曼光谱分析了样品的微观结构,用交流复阻抗谱研究了样品的电学性能.结果表明:800℃焙烧的所有样品均为具有氧缺位的单相立方萤石结构,晶胞参数随钇(Y)掺杂量增加而减小.钇掺杂量x=0.05的样品Ce0.8Gd0.15Y0.05O2-δ的电导率最高,导电活化能最小,(σ700℃=5.58×10-3S·cm-1,Eα=0.92 eV),高于未掺杂Y的Ce0.8Gd0.2O2-δ样品的电导率(σ700℃=5.38×10-3S·cm-1Eα=1.09 eV).说明适量双掺杂Y提高了Ce0.8Gd0.2-xYxO2-δ的电导率并且降低了其活化能.  相似文献   
10.
采用共沉淀-水热法合成Tb3+掺杂Gd2Sn2O7纳米荧光材料,并采用X射线衍射(XRD)、扫描电镜(SEM)、透射电镜(TEM)、傅里叶变换红外光谱(FT-IR)、拉曼光谱(Raman)和荧光光谱对合成产物的晶体结构、颗粒尺寸、形貌和光学性能进行研究。研究结果表明水热合成产物为单一相立方烧绿石结构Gd2Sn2O7:Tb3+晶体,产物由尺寸约为50~70 nm的一次纳米颗粒团聚而成的不规则球。激发光谱和发射光谱测试结果表明,Gd2Sn2O7:Tb3+样品可以被379 nm的紫外光有效地激发而发射出纯度高的Tb3+离子特征的绿光,在高浓度Tb3+掺杂时可观察到Tb3+发光浓度猝灭现象。在样品的激发光谱中观察到不同激发带的猝灭浓度并不相同,并对其原因进行了分析。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号