高度有序多孔氧化铝模板的制备工艺与生长机制的研究

采用二次氧化法制备出高度有序的多孔氧化铝模板，结合扫描电镜和原子力显微镜对其结构、形貌进行观察和表征。研究了铝箔预处理和温度等对多孔氧化铝模板孔洞有序性的影响，讨论了有序孔洞的自组织生长机理。     

Strength, strain-rate sensitivity and ductility of copper with nanoscale twins

We present a comprehensive computational analysis of the deformation of ultrafine crystalline pure Cu with nanoscale growth twins. This physically motivated model benefits from our experimental studies of the effects of the density of coherent nanotwins on the plastic deformation characteristics of Cu, and from post-deformation transmission electron microscopy investigations of dislocation structures in the twinned metal. The analysis accounts for high plastic anisotropy and rate sensitivity anisotropy by treating the twin boundary as an internal interface and allowing special slip geometry arrangements that involve soft and hard modes of deformation. This model correctly predicts the experimentally observed trends of the effects of twin density on flow strength, rate sensitivity of plastic flow and ductility, in addition to matching many of the quantitative details of plastic deformation reasonably well. The computational simulations also provide critical mechanistic insights into why the metal with nanoscale twins can provide the same level of yield strength, hardness and strain rate sensitivity as a nanostructured counterpart without twins (but of grain size comparable to the twin spacing of the twinned Cu). The analysis also offers some useful understanding of why the nanotwinned Cu with high strength does not lead to diminished ductility with structural refinement involving twins, whereas nanostructured Cu normally causes the ductility to be compromised at the expense of strength upon grain refinement.     

Electrodeposition of smooth and adherent film of polypyrrole on lead electrode

Electropolymerization of pyrrole on lead substrate electrode was studied. Due to electrochemical activity of Pb in acidic media, this process is only possible at basic pHs. For this purpose, electropolymerization process was performed in an aqueous solution of Na₂SO₄ with pH 12. Potentiodynamic cycling shows the Pb oxidation at the first cycles. In subsequent cycles, polypyrrole film grows on the oxidized lead substrate. Of course, as the passive film is highly porous, a composite of polypyrrole/PbSO₄ is formed in the first layers. However, subsequent cycling leads to the formation of pure polypyrrole film. According to this structure and strong connection of the polymer film to the substrate surface via this composite layer, the polypyrrole film deposited on the lead surface has enhanced mechanical stability. AFM measurements showed peculiar smoothness of both composite and lateral polypyrrole films. This synthesis approach is of particular interest for the preparation of highly stable polymer films and fabrication of supercapacitors with a polymer/PbSO₄ conductive structure.     

Crack initiation in relation to the tool edge radius and cutting conditions in nanoscale cutting of silicon

In cutting of brittle materials, experimentally it was observed that there is a ductile–brittle transition when the undeformed chip thickness is increased from smaller to larger than the tool cutting edge radius of the zero rake angle. However, how the crack is initiated in the ductile–brittle mode transition as the undeformed chip thickness is increased from smaller to larger than the tool cutting edge radius has not been fully understood. In this study, the crack initiation in the ductile–brittle mode transition as the undeformed chip thickness is increased from smaller to larger than the tool cutting edge radius has been simulated using the Molecular Dynamics (MD) method on nanoscale cutting of monocrystalline silicon with a non-zero edge radius tool, from which, for the first time, a peak deformation zone in the chip formation zone has been found in the transition from ductile mode to brittle mode cutting. The results show that as the undeformed chip thickness is larger than the cutting edge radius, in the chip formation zone there is a peak deformation depth in association with the connecting point of tool edge arc and the rake face, and there is a crack initiation zone in the undeformed workpiece next to the peak deformation zone, in which the material is tensile stressed and the tensile stress is perpendicular to the direction from the connecting point to the peak. As the undeformed chip thickness is smaller than the cutting edge radius, there is no deformation peak in the chip formation zone, and thus there is no crack initiation zone formed in the undeformed workpiece. This finding explains well the ductile–brittle transition as the undeformed chip thickness increases from smaller to larger than the tool cutting edge radius.     

Control of frictional dynamics of a one-dimensional particle array

Control of frictional forces is required in many applications of tribology. While the problem is approached by chemical means traditionally, a recent approach was proposed to control the system mechanically to tune frictional responses. We design feedback control laws for a one-dimensional particle array sliding on a surface subject to friction. The Frenkel-Kontorova model describing the dynamics is a nonlinear interconnected system and the accessible control elements are average quantities only. We prove local stability of equilibrium points of the un-controlled system in the presence of linear and nonlinear particle interactions, respectively. We then formulate a tracking control problem, whose control objective is for the average system to reach a designated targeted velocity using accessible elements. Sufficient stabilization conditions are explicitly derived for the closed-loop error systems using the Lyapunov theory based methods. Simulation results show satisfactory performances. The results can be applied to other physical systems whose dynamics is described by the Frenkel-Kontorova model.     

A new method for in situ measurement of parameters and degradation processes in modern nanoscale programmable devices

This paper presents a new method and results from measurement of internal parameters of programmable nanoscale circuits, namely Xilinx FPGA devices and especially Zynq SoC devices designed on 28 nm TSMC’s technology and older 45 nm Spartan 6 device as well as Xilinx Virtex product lines. The method utilizes a new undersampling approach for frequency measurement and an easy way of processing BRAM data streams. The proposed flexible circuits have been used in various measurements of timing parameters and delays in FPGAs, including measurements or detection of the aging issues. The paper presents results of measurements under various core voltage values as performed on selected Xilinx FPGA platforms, including key results about limited usability of the latest 28 nm devices under accelerated conditions and possibility of studying or mitigating aging effects in FPGAs. The paper presents rare results of experiments, real measurements and data available from current as well as previous technology nodes and it attempts to uncover new facts and areas of the latest high-end technologies, including the area of aging and degradation processes in general. The new methodology, presented approach and results can also be used in various dependable systems, including selected aerospace, medical, automotive or transportation ones. It is also directly and easily applicable to modern processor and multicore systems.     

Modeling of nanoscale friction using molecular dynamics simulation

利用分子动力学方法模拟了刚性金刚石压头在Ni单晶体上的滑动过程, 讨论了压入深度对 摩擦力的影响(压入深度对滑动过程中压头下方的微结构演化(能否发射位错环)有很大影响). 结 合摩擦过程中的塑性行为和能量耗散机制, 解释了产生摩擦力锯齿形曲线的原因, 证实了位错的形 核及湮灭是黏--滑机制的原因之一. 不同滑动速度对摩擦力影响的模拟表明, 压头的滑动速度决定 了压头下方位错环的运动和演化形式: 在高速滑动下, 形成的位错环依次沿着滑移面很快向Ni单晶 基体内扩展; 在低速滑动下, 压头下方产生的位错环互相发生作用, 在材料的亚表面形成较低能量的 大位错环, 由此产生的塑性变形主要集中在材料的亚表面.     

Structure modification of rapidly solidified Al-11 wt% Si alloy by the addition of 2 wt% Fe

An investigation of the structure formation of as-cast Al-11 wt% Si (AlSi11) and Al-11 wt% Si-2 wt% Fe (AlSi11Fe2) rapidly solidified (RS) ribbons is performed. Ribbon samples are examined in detail using Auger electron spectroscopy (AES) and transmission electron microscopy (TEM). A nanoscale thickness layer of Si-precipitations, at both Al-grains boundary and oxide/Al-matrix interface, is found to be characteristic for “pure” AlSi11 ribbons. For Fe-doped ribbons, this layer comprises Fe-containing phase also, which appears to possess amorphous nature and is situated between the Si-grains and Al-matrix. A possible mechanism of altering the thermally activated volume diffusion of elements, due to the effect of Fe on the structure modification, is speculated based on the obtained results.     

Increase of hardness and thermal stability of TiAlN coating by nanoscale multi-layered structurization with a BN phase

This study investigated the effects of a nanoscale multi-layered structure on the hardness and thermal stability of Ti-Al-B-N coating. Bilayer period of nanoscale multi-layered TiAlN/BN coating, prepared by alternating deposition of TiAlN and BN layers, was controlled by changing BN target power. The hardness value of TiAlN coating increased through nanoscale multi-layered structurization with a thin (∼ 0.6 nm) BN phase. The intensity of low angle XRD peaks and hardness of the nanoscale multi-layered TiAlN/BN coatings increased after heat-treatment in an N₂ atmosphere. The nanoscale multi-layered TiAlN/BN coating showed better thermal stability than that of TiAlN coating.