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1.
In this study, a kind of Ni-based superalloy specially designed for additive manufacturing (AM) was investigated. Thermo-Calc simulation and differential scanning calorimetry (DSC) analysis were used to determine phases and their transformation temperature. Experimental specimens were prepared by laser metal deposition (LMD) and traditional casting method. Microstructure, phase constitution and mechanical properties of the alloy were characterized by scanning electron microscopy (SEM), transmission scanning electron microscopy (TEM), X-ray diffraction (XRD) and tensile tests. The results show that this alloy contains two basic phases, γ/γ', in addition to these phases, at least two secondary phases may be present, such as MC carbides and Laves phases. Furthermore, the as-deposited alloy has finer dendrite, its mean primary dendrite arm space (PDAS) is about 30-45 μm, and the average size of γ' particles is 100-150 nm. However, the dendrite size of the as-cast alloy is much larger and its PDAS is 300-500 μm with secondary and even third dendrite arms. Correspondingly, the alloy displays different tensile behavior with different processing methods, and the as-deposited specimen shows better ultimate tensile stress (1,085.7±51.7 MPa), yield stress (697±19.5 MPa) and elongation (25.8%±2.2%) than that of the as-cast specimen. The differences in mechanical properties of the alloy are due to the different morphology and size of dendrites, γ', and Laves phase, and the segregation of elements, etc. Such important information would be helpful for alloy application as well as new alloy development.  相似文献   
2.
The uniform refinement mechanisms and methods of deformed mixed and coarse grains inside a solution-treatment Ni-based superalloy during two-stage annealing treatment have been investigated.The two-stage heat treatment experiments include an aging annealing treatment(AT)and a subsequent recrystallization annealing treatment(RT).The object of AT is to precipitate some δ phases and consume part of storage energy to inhibit the grain growth during RT,while the RT is to refine mixed and coarse grains by recrystallization.It can be found that the recrystallization grains will quickly grow up to a large size when the AT time is too low or the RT temperature is too high,while the deformed coarse grains cannot be eliminated when the AT time is too long or the RT temperature is too low.In addition,the mixed microstructure composed of some abnormal coarse recrystallization grains(ACRGs)and a large number of fine grains can be observed in the annealed specimen when the AT time is 3 h and RT tem-perature is 980℃.The phenomenon attributes to the uneven distribution of δ phase resulted from the heterogeneous deformation energy when the AT time is too short.In the regions with a large number of δ phases,the recrystallization nucleation rate is promoted and the growth of grains is limited,which results in fine grains.However,in the regions with few δ phases,the recrystallization grains around grain boundaries can easily grow up,and the new recrystallization nucleus is difficult to form inside grain,which leads to ACRGs.Thus,in order to obtain uniform and fine annealed microstructure,it is a prereq-uisite to precipitate even-distributed δ phase by choosing a suitable AT time,such as 12 h.Moreover,a relative high RT temperature is also needed to promote the recrystallization nucleation around δ phase.The optimal annealing parameters range for uniformly refining mixed crystal can be summarized as:900℃×12 h+990℃×(40-60 min)and 900℃×12 h+1000℃×(10-15 min).  相似文献   
3.
概述了裂解汽油一段选择加氢钯系和镍系催化剂在我国的工业化应用情况,并从载体材料、制备工艺优化以及添加助剂改性3个方面,综述了此系列钯系和镍系催化剂在国内外的研究进展,预测了今后需持续注重及改进的相关方面;最后展望指出,针对特定原料性质开发与之相匹配的选择加氢工艺及其配套专用催化剂,将是未来裂解汽油一段选择加氢催化剂研发的主方向。  相似文献   
4.
添加碳化物和难熔金属元素,可以显著提高激光熔覆技术制备Inconel 625合金涂层的耐磨性,但添加氧化物对合金涂层的高温耐磨性的影响研究较少,其作用原理尚未揭示。为此,采用高速激光熔覆技术,在20G钢板基体上成功制备了Inconel 625涂层和Inconel 625/Y2O3复合涂层,并对他们的微观组织及高温耐磨性进行了系统地研究。结果表明:在凝固过程中Y2O3作为形核剂,其可使晶粒细化及晶粒取向分布更加随机;Inconel 625涂层和Inconel 625/Y2O3复合涂层均表现出在激光熔覆层/基体界面搭接处的硬度最高,与Inconel 625涂层相比,Inconel 625/Y2O3复合涂层搭接处的硬度更高约为275 HV0.5;与基体和Inconel 625涂层相比,Inconel 625/Y2O3复合涂层具有更低的高温摩擦磨损系数,其高温摩擦系数仅为0.2;通过对比高温磨损后微观组织形貌后发现,Inconel 625/Y2O3复合涂层的耐磨性能最好。  相似文献   
5.
To clarify the transformation mechanism of secondary phase and the mechanism of intergranular corrosion in laser welding Ni-based alloy (Hastelloy C-276)/304 stainless steel with filler wire, the secondary phase was analyzed by electron probe micro-analysis (EPMA) and transmission electron microscopy (TEM). The evaluation of intergranular corrosion resistance of the welded joints was conducted by double-loop electrochemical potentiokinetic reactivation (DL-EPR) method, and at the same time the chemical compositions of the corrosion surface were analyzed by energy-dispersive spectrometry (EDS). The results show that p phase has complete coherence relationship with μ phase, and the coherent relationship is described as [001]p// and [430]p//[0001]μ. The μ phase is rapidly transformed from p phase, which is the inhomogeneous phase transformation. The transformation of secondary phase will increase the susceptibility to intergranular corrosion. Therefore, the transformation of secondary phase should be avoided in the welding process.  相似文献   
6.
本文针对超瞬态凝固增材制造梯度整体涡轮叶盘高温合金叶片用合金粉末特性开展研究。根据合金的承温能力和JMatPro相平衡计算结果,选用DZ4125作为叶片材料,K418作为叶盘轮缘部位材料。采用真空感应熔炼氩气雾化制粉(VIGA)制备DZ4125高温合金粉末,筛分至53-105μm粒度范围,采用采用差示扫描量热分析(DSC)、场发射扫描电镜(FESEM)和能谱(EDS)、激光粒度仪、动态图像粒度粒形分析仪以及综合粉体性能测试仪对DZ4125高温合金粉末的相变温度、显微组织、析出相成分、元素偏析行为、粒度、粒形、松装密度、振实密度和流动性进行系统表征。结果表明:DZ4125比K418合金的固液凝固温度范围宽,过渡区DZ4125+K418混合成分合金其液相线温度和MC碳化物开始析出温度介于两种合金之间,γ′开始析出温度与两种合金相当。DZ4125合金粉末形貌主要为球形和近球形,表面和截面显微组织主要呈树枝晶结构。所含元素中偏析倾向较强的元素有Hf、Ta、Ti、Mo和W,而偏析倾向弱的元素包括Ni、Co、Cr和Al。粉末内部枝晶间区分布有细小的MC碳化物,尺寸约为200nm。激光衍射和动态图像分析法测得的DZ4125粉末粒度值接近,中位径D50分别为70.2μm和72.8μm。动态图像法测得DZ4125合金粉末具有较好的球形度,SPHT和b/l均值分别为0.91和0.86。所选DZ4125高温合金粉末具有较好的松装密度、振实密度和流动性,其松装和振实密度分别达到合金理论密度的52%和63%,压缩度为17.7%,且粉末具有较好的流动性(20.79 s?(50 g)-1)。  相似文献   
7.

K416B Ni-based superalloy with high W content has good high temperature properties and low cost, which has a great development potential. To investigate the room temperature tensile property and the deformation feature of K416B superalloy, tensile testing at room temperature was carried out, and optical microscopy (OM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used to analyze the deformation and damage mechanisms. Results show that the main room temperature tensile deformation features of the K416B nickel-based superalloy are dislocations slipping in the matrix and shearing into γ′ phase. The <110> super-dislocations shearing into γ′ phase can form the anti-phase boundary two coupled (a/2)<110> partial-dislocations or decompose into the configuration of two (a/3)<112> partial dislocations plus stacking fault. In the later stage of tensile testing, the slip-lines with different orientations are activated in the grain, causing the stress concentration in the regions of block carbide or the porosity, and cracks initiate and propagate along these regions.

  相似文献   
8.
Diamond has high hardness and good wear resistance. It is widely used in cutting tools and workpieces. Brazing is an effective method to realize high quality cemented carbide joints in various materials connection technologies. This paper analyzes the research status of diamond brazing in detail. The materials used as brazing filler in diamond brazing are reviewed. Copper base filler and nickel base filler are the most commonly used brazing filler in diamond brazing. The advantages and disadvantages of diamond grinding tools under different production methods are analyzed. In addition, a series of new brazing alloys such as amorphous Ni based brazing filler metals are analyzed. Finally, the development trend of diamond brazing is pointed out.  相似文献   
9.
Monel合金表面激光熔覆Ni基稀土合金空蚀性能   总被引:1,自引:0,他引:1  
采用激光熔覆技术在Monel 400合金表面制备Ni基稀土合金熔覆层。利用SEM、EDS、XRD、显微硬度计及超声波金属材料空蚀仪等设备对熔覆层的组织形貌、相结构、硬度、空蚀性能及失效机制进行了系统研究。结果表明:Y_2O_3细化了熔覆层的组织,其组织主要由γ-Ni固溶体、Ni_3B和高硬度的Cr_(23)C_6和Cr_7C_3组成,熔覆层平均硬度可达9040MPa,抗空蚀性能是Monel400合金的8.7倍,熔覆层空蚀过程失效机制主要为枝晶干的冲蚀剥落,Ni基稀土合金熔覆层的细晶强化及空蚀过程中产生阻断晶界网状结构是提高其耐空蚀性能的关键。  相似文献   
10.
目前拉伸载荷下的镍基单晶合金的力学性能研究较为广泛,而剪切载荷对镍基单晶合金的力学性能也十分重要但缺乏研究。本文利用分子动力学方法研究了镍基单晶合金在剪切载荷下的裂纹扩展和微观结构演化,分析了应力-应变、势能和裂纹生长速率的变化。同时,揭示了温度和剪切应变率对裂纹扩展和微观结构演化的影响。结果表明,临界分切应力随温度的降低和应变速率的增大而增大;随着温度的升高以及剪切载荷下发生剧烈的热运动,裂缝表现为加速扩展的趋势;而在较高的应变率影响下,会形成位错塞积和孪晶,出现加工硬化现象。  相似文献   
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