四川某低品位金矿非氰浸出试验研究

对金品位为1.55 g/t的氧化矿采用非氰药剂进行浸金的工艺流程,考察了磨矿细度、药剂DZC浓度和浸出时间对金浸出率的影响。确定该金矿适宜的非氰浸出条件:磨矿细度-74μm含量占69.90%、石灰用量4 000g/t、矿浆液固比为2∶1、浸出药剂DZC浓度0.08%、浸出时间8 h,可获得金的浸出率为93.33%的良好指标。表明该氧化金矿在常温常压下,采用非氰浸出工艺是可行的。     

Microstructure,tribological behavior and magnetic properties of Fe−Ni−TiO2 composite coatings synthesized via pulse frequency variation

The Fe−Ni−TiO₂ nanocomposite coatings were electrodeposited by pulse frequency variation. The results showed that the nanocomposite with a very dense coating surface and a nanocrystalline structure was produced at higher frequencies. By increasing the pulse frequency from 10 to 500 Hz, the iron and TiO₂ nanoparticles contentswere increased in expense of nickel content. XRD patterns showed that by increasing the frequency to 500 Hz, an enhancement ofBCC phase was observed and the grain size of deposits was reduced to 35 nm. The microhardness and the surface roughness were increased to 647 HV and 125 nm at 500 Hz due to the grain size reduction and higher incorporation of TiO₂ nanoparticles into the Fe−Ni matrix (5.13 wt.%). Moreover, the friction coefficient and wear rate values were decreased by increasing the pulse frequency;while the saturation magnetization and coercivity values of the composite deposits were increased.     

Design of tailored biodegradable implants: The effect of voltage on electrodeposited calcium phosphate coatings on pure magnesium

Magnesium, as a biodegradable metal, offers great potential for use as a temporary implant material, which dissolves in the course of bone tissue healing. It can sufficiently support the bone and promote the bone healing process. However, the corrosion resistance of magnesium implants must be enhanced before its application in clinical practice. A promising approach of enhancing the corrosion resistance is deposition of bioactive coating, which can reduce the corrosion rate of the implants and promote bone healing. Therefore, a well-designed substrate-coating system allowing a good control of the degradation behavior is highly desirable for tailored implants for specific groups of patients with particular needs. In this contribution, the influence of coating formation conditions on the characteristics of potentiostatically electrodeposited CaP coatings on magnesium substrate was evaluated. Results showed that potential variation led to formation of coatings with the same chemical composition, but very different morphologies. Parameters that mostly influence the coating performance, such as the thickness, uniformity, deposits size, and orientation, varied from produced coating to coating. These characteristics of CaP coatings on magnesium were controlled by coating formation potential, and it was demonstrated that the electrodeposition could be a promising coating technique for production of tailored magnesium-CaP implants.     

Pulse electrodeposited PtSn electrocatalyst on a PEDOT/graphene-based electrode for ethanol oxidation in an acidic medium

Pulse electrodeposition of Pt and Sn using 10 mM H₂PtCl₆?6H₂O in 0.10 M H₂SO₄ and 10 mM SnCl₂?2H₂O in 0.10 M HCl was conducted on a support matrix consisting of electropolymerized poly (3,4-ethylenedioxythiophene) (PEDOT) and electrochemically exfoliated graphene oxide (EGO). The Field Emission – Scanning Electron Microscopy (FE-SEM) studies of PtSn/PEDOT/EGO (i.e., PEDOT on EGO) showed a homogeneous globular composite, while PtSn/EGO/PEDOT (i.e., EGO on PEDOT) revealed a heterogeneous composite with wrinkled and globular surface morphologies. An Energy Dispersive X-ray (EDX) analysis (as a percentage of Pt and Sn) of PtSn/PEDOT/EGO is in agreement with the X-ray Photoelectron Spectroscopy (XPS) analysis, indicative of a homogeneous surface for the dispersion of metallic particles. However, the EDX and XPS analyses of PtSn/EGO/PEDOT showed variations in the amount of Pt and Sn, indicative of possible mixing of the EGO and PEDOT support matrices. Cyclic voltammetry (CV) and chronoamperometry using 1.0 M ethanol in 0.1 M H₂SO₄ demonstrated higher electrocatalytic activity (83.7 mA/cm²) and electrochemical stability (29.0% current retention) in PtSn/PEDOT/EGO than PtSn/EGO/PEDOT.     

Novel porous carbon felt cathode modified by cyclic voltammetric electrodeposited polypyrrole and anthraquinone 2-sulfonate for an efficient electro-Fenton process

A novelty two-step synthesized porous carbon felt (PCF) cathode modified by cyclic voltammetric (CV) electrodeposited polypyrrole (Ppy) and anthraquinone 2-sulfonate (AQS) (PCF/Ppy/AQS) for an efficient electro-Fenton process has been investigated. Brunauer Emmett Teller (BET) and scanning electron microscope (SEM) measurements verified the three-dimensional porous structure of the PCF, revealing that the specific surface area was approximately 2.5 times higher than that of the bare carbon felt (CF), which ensured more active sites available for oxygen reduction reaction (ORR). In addition, the electrodeposited Ppy decreases the charge transfer resistance (R_ct) of the PCF cathode. AQS, a type of anthraquinone that can serve as an oxygen reduction catalyzer, could accelerate the ORR process and subsequently improve the performance of the electro-Fenton system. Rotating disk electrode (RDE) analysis confirmed that the ORR catalyzed by AQS was a double-electron reduction process, which contributed to hydrogen peroxide (H₂O₂) generation. The removal efficiency of total organic carbon (TOC) from Rhodamine B (RhB) could reach 51% within 1 h in the electro-Fenton system equipped with the PCF/Ppy/AQS, resulting in an improvement of approximately 24% compared with the bare CF cathode without porous treatment. The cycle experiment showed a good stability of the PCF/Ppy/AQS cathode. Additionally, the possible mechanism of degradation process in the electro-Fenton equipped with the PCF/Ppy/AQS cathode was proposed based on the electron paramagnetic resonance (EPR) analysis and quenching experiment. The novel fabricated PCF/Ppy/AQS provides an alternative as a high-efficiency cathode, yielding energy savings in the electro-Fenton system.     

A comparative study on the catalytic activities and stabilities of atomic-layered platinum on dispersed Ti0.9Cu0.1N nanoparticles supported by N-doped carbon nanotubes (N-CNTs) and reduced graphene oxide (N-rGO)

In our previous research, titanium-based nitride with high conductivity and superior corrosion resistance were developed as an ideal core material for replacing noble metal to form Pt-based core-shell catalysts by pulse electrodeposition. Meanwhile, the smaller sizes of nitride cores would also be available for pulse electrodeposition by dispersing them on carbon nanotubes (CNT). To achieve a better practice on the preparation of the Pt-based core-shell catalysts, in this work, both nitrogen-doped carbon nanotubes (N-CNT) and reduced graphene oxide (N-rGO) were used to support the copper-doped titanium nitride (Ti_0.9Cu_0.1N) cores. In the course of pulse electrodeposition, their influences as supports on the electronic states of electrodeposited Pt as well as their catalytic activities were compared. The results showed that the Pt preferred to electrodeposit on Ti_0.9Cu_0.1N cores supported by N-CNT and formed a core-shell structure. While with the same electrodeposition process, the Pt was found to be electrodeposited not only on the Ti_0.9Cu_0.1N cores supported by N-rGO with heavy aggregations but also on the N-rGO support. Raman spectroscopy analysis indicated that the higher degree of structural defects on N-rGO, as support, might have contributed to such divergence observation.