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2.
Bai-Xin Dong Xu-Dong Ma Tian-Shu Liu Qiang Li Hong-Yu Yang Shi-Li Shu Bing-Qi Zhang Feng Qiu Qi-Chuan Jiang 《Journal of the American Ceramic Society》2021,104(6):2820-2835
Titanium carbide (TiC) nanoparticles with well-designed exposed crystal planes perform intriguing prospects for functional and engineering applications. In this study, a simple and controllable in situ synthesis strategy was proposed for the synthesis of TiC nanoparticles with specific morphology. Reaction behaviors suggested that most of TiC nanoparticles were formed by an instantaneous reaction between Al3Ti and Al4C3 in the Al-rich melt and the resultant morphology was controlled by the discrepant growing rates of (100) and (111) crystal planes. In addition, a growth morphology control model was presented for the prediction and manipulation of the morphology of TiC nanoparticles by the doping of different alloying elements Me (Me = Cu, Mg, Mn, Zn, and Si). According to the morphological observations and density functional theory analyses including the interface energy, charge density differences, and orbital hybridization: Cu, Mg, and Zn atoms could stabilize the Al/TiC(111) interface, whereas Mn and Si atoms promoted the rapid growing and disappearance of the TiC(111) planes in the Al melt. This work provides a feasible way to intelligently design and manipulate TiC nanoparticles with desirable exposed crystal planes, and exhibits a promising prospect for personalized applications. 相似文献
3.
《Advanced Powder Technology》2022,33(2):103390
In the present work, a comprehensive study of mechanical alloying of Ni-carbon nanotubes (CNT) and Ni-Graphite equiatomic powder mixtures under the same technological modes has provided to reveal the features of using different types of carbon (CNT or graphite) as a charge component. The as-milled powders were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and magnetometric study. A novel nanoscale fcc NiC monocarbide was synthesized regardless the type of the charge used. According to the XRD study the formation of this phase takes place in two stages. A two-step carbide formation mechanism has been proposed. The associated changes in the nickel lattice, such as changes in the lattice parameter, lattice strain and residual stresses, which led to the formation of NiC monocarbide were also evaluated and discussed. Parameters of the electronic structure of NiC were calculated using the MStudio MindLab 7.0 software package with the experimental data on the crystal structure of the NiC phase obtained as input. Temperature dependencies of magnetic susceptibility of NiC synthesized have been studied up to 950 K. Carbides synthesized were found to be weak ferromagnets at the room temperature and their Curie temperature TC ranges within 670 – 725 K. The calculated value of the magnetic moment per nickel atom (2.83μB) is higher than that of a bulk Ni (1.3μB). Likely, the observed increase of μ is caused by the presence of a certain amount of residual single-domain ferromagnetic Ni nanoparticles in the samples synthesized. 相似文献
4.
《Ceramics International》2022,48(8):10921-10931
Coatings were obtained by vacuum electro-spark alloying (VESA), pulsed cathodic arc evaporation (PCAE), magnetron sputtering (MS) techniques and VESA-PCAE-MS hybrid technology using Cr3C2–NiAl electrodes. The structure of the coatings was analyzed using scanning and transmission electron microscopy, X-ray diffraction and energy-dispersive spectroscopy. Mechanical properties were determined by nanoindentation, while tribological properties were assessed using pin-on-disk tribometer. Corrosion resistance was estimated by voltammetry in 1 N H2SO4 and 3.5%NaCl solutions. Oxidation resistance tests were performed at 800°С in air. The VESA coating had the highest thickness, low friction coefficient and high wear resistance. PCAE coating demonstrated the highest hardness (24 GPa) and elastic recovery (59%), oxidation resistance and superior corrosion resistance both in 1 N H2SO4 (icorr = 70 μА/cm2) and 3.5%NaCl (icorr = 0.74 μА/cm2) solutions. The MS coating had average mechanical properties and low corrosion current density (71 μА/cm2) in 1 N H2SO4. Deposition of coatings using VESA-PCAE-MS hybrid technology led to an increase in corrosion and oxidation resistance at least by 1.5 times in comparison with the VESA coating. 相似文献
5.
用机械合金化和放电等离子烧结(SPS)工艺制备名义成分为Fe-18Mn-0.6C的高锰钢,对其组织及力学性能进行分析。结果表明:SPS烧结制备的Fe-18Mn-0.6C块体为平均晶粒尺寸为1μm的超细晶单一奥氏体合金钢,晶粒内部存在较多的层错及退火孪晶,还分布着大量的纳米级弥散颗粒。Fe-18Mn-0.6C块体硬度为475HV、抗拉强度为925 MPa,较多的孔隙缺陷导致块体致密度低,仅为96.27%。孔隙与晶粒内部大尺寸颗粒在拉应力作用下易萌生裂纹发生撕裂,造成沿晶脆断,塑性较差。850℃/1 h的热处理能显著改善块体韧性,伸长率由4%升至13%,以脆断为主、韧断为辅的混合断裂模式。 相似文献
6.
《International Journal of Hydrogen Energy》2022,47(82):35003-35016
A new route of materials synthesis, namely, high-temperature, high-pressure reactive planetary ball milling (HTPRM), is presented. HTPRM allows for the mechanosynthesis of materials at fully controlled temperatures of up to 450 °C and pressures of up to 100 bar of hydrogen. As an example of this application, a successful synthesis of magnesium hydride is presented. The synthesis was performed at controlled temperatures (room temperature (RT), 100, 150, 200, 250, 300, and 325 °C) while milling in a planetary ball mill under hydrogen pressure (50 bar). Very mild milling conditions (250 rpm) were applied for a total milling time of 2 h, and a milling vial with a relatively small diameter (φ = 53 mm, V = ~0.06 dm3) was used. The effect of different temperatures on the synthesis kinetics and outcome were examined. The particle morphology, phase composition, reaction yield, and particle size were measured and analysed by scanning electron microscopy, X-ray diffraction, differential scanning calorimetry (DSC) techniques. The obtained results showed that increasing the temperature of the process significantly improved the reaction rate, which suggested the great potential of this technique for the mechanochemical synthesis of materials. 相似文献
7.
由于煤矿刮板运输机服役的恶劣环境,对传统NM360耐磨钢的耐蚀及耐磨性能提出了更高的要求。综合考虑合金元素对钢材耐蚀性的提升作用,在传统耐磨钢成分的基础上,采取添加一定量的Cu、Ni合金元素的方法,开发了耐腐蚀NM360钢板。采用场发射扫描电镜,透射电子显微镜以及布氏硬度仪对耐腐蚀NM360钢板的组织及硬度进行分析研究;通过干砂/橡胶轮磨损试验机测试了耐腐蚀NM360钢板的磨损性能;利用腐蚀挂片试验测试了耐腐蚀NM360钢板的腐蚀性能。结果表明,虽然添加Cu、Ni元素后耐腐蚀NM360钢板与传统耐磨钢板硬度相当,但耐腐蚀性能及耐磨性能均有一定程度的提升。 相似文献
8.
以微米级氧化钒(V2O5)、氧化铬(Cr2O3)和纳米碳黑为原料,采用机械合金化及微波辅助加热法制备了纳米碳化钒/碳化铬复合粉末。利用XRD、XPS、TG-DSC、SEM、TEM和BET对产物进行了分析表征。结果表明,:纳米碳化钒/碳化铬复合粉末的最佳合成条件为:碳的质量分数为35%,反应温度为900℃,保温时间为1h。在该条件下的反应产物主要由V3Cr2C5、Cr2VC2和Cr3C2组成,颗粒为球形或类球形,分散性较好,无明显团聚现象,平均颗粒尺寸约为50nm,复合粉末的比表面积为115.53m2/g。添加纳米碳化钒/碳化铬复合粉末可以提高陶瓷结合剂cBN磨具的力学性能和磨削效率,降低磨具的损耗,并且对磨具具有减摩作用。 相似文献
9.
Panpan Zhang Yuhai Sun Yueliang Wang Yafeng Zheng Xiaofeng Zhang Qunli Zhang Jianhua Yao 《Journal of the American Ceramic Society》2022,105(10):6345-6358
Aiming to improve the thermal shock resistance of thermal barrier coatings (TBCs), the plasma-sprayed 7YSZ TBCs were modified by selective laser remelting and selective laser alloying, respectively, in this study. A self-healing agent TiAl3 was introduced into the 7YSZ TBCs by selective laser alloying to fill cracks during thermal cycling. The thermal shock experiments of the plasma-sprayed, laser-remelted, and laser-alloyed TBCs were conducted by a means of heating and water-quenching method. Results revealed that some segmented microcracks were distributed on the surface of the laser-remelted and the laser-alloyed zones, showing a dense columnar crystal structure. After thermal shock tests, the numbers of segmented microcracks on the laser-remelted coating increased, whereas, in the laser-alloyed condition, some irregular particles formed, leading to the decreased numbers of segmented microcracks. The laser-alloyed coating exhibited the best thermal shock resistance, followed by the laser-remelted condition, with the thermal shock lifetime 3.3 and 2.7 times higher than that of the as-sprayed coating, respectively. On the one hand, both columnar grains and segmented microcracks in the laser-treated zone could effectively improve the strain tolerance of coatings. On the other hand, the oxidation products of TiAl3 under high-temperature condition could seal the microcracks to postpone the crack connection. Thus, the thermal shock resistance of the laser-treated coatings was significantly improved. 相似文献
10.
Two kinds of Cu-Al_2O_3 composites(with and without La) were prepared via mechanical alloying-spark plasma sintering(MA-SPS) method. Microstructure, mechanical properties and electrical resistivity were investigated systematically using metallography, scanning electron microscopy, transmission electron microscopy, mechanical and electrical properties testing. The results indicate that an appropriate amount of La can homogenize the distribution of Al_2O_3. As such, yield strength, ultimate tensile strength and elongation of Cu-Al_2O_3-La are greatly increased. Some semi-coherent interface between Cu and Al_2O_3 is found, which means a low interface energy. The grain shape of Cu changes to irregular band with the addition of La. This change results in a density decrease of grain boundary and reduces electrical resistance. Lanthanum may exist in the form of La_2O_3. 相似文献