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1.
相邻工作面开采会导致复杂的漏风情况,浮煤易自燃,增大防火工作的难度。为明确相邻采空区自燃“三带”分布特征及确定最佳注氮防灭火参数,以贵州某矿4244工作面为背景,结合现场实测,应用Fluent流场分析软件,模拟研究不同注氮方案下采空区氧气浓度场分布规律。结果表明,实测结果与模拟相吻合,验证了模拟的可靠性;当注氮位置为X=50 m,注氮流量为100 m3/h时,采空区进、回风巷侧氧化带宽度分别为7 m和38 m,能明显减少本采空区氧化带面积,且能防止氧化带距工作面太近;此工作面进风侧注氮对相邻采空区氧化带影响范围较小,这要求在回采过程中需要对煤柱进行加固,降低孔隙率,控制漏风,减少氧气进入相邻采空区,降低煤自燃风险。模拟结果为相邻采空区灾害防治工作提供了的理论指导。 相似文献
2.
为了研究黄铁矿对煤自然氧化的影响,在煤中添加四类黄铁矿自然氧化产物,通过程序升温实验分析黄铁矿对煤自然氧化特性的影响。实验得到:不同浓度的Fe3+和Fe2+均降低了煤的三个特征点的温度,且随着浓度的升高,三个特征点的温度降低的越大。H+导致煤样在氧化过程中质量突变。Fe(OH)3对煤低温氧化具有抑制作用。对煤样进行FTIR测试,可得Fe3+和Fe2+对加速了煤中活性结构的氧化。H+对-OH、-CH2-的氧化具有促进作用。Fe(OH)3则对煤中活性基团的影响变化不大,对煤自然氧化起物理阻化作用。 相似文献
3.
《Advanced Powder Technology》2022,33(11):103833
Eliminating the gold preg-robbing effect of carbonaceous matter in carbonaceous gold ores is crucial for gold leaching. In this study, suspension oxidation roasting was proposed to accelerate the decarbonization of carbonaceous gold ore. The characteristics of oxidation reaction process and gas release were analyzed by TG-DTA-FTIR. The phase transformation and microstructure evolution of samples during roasting were analyzed by XRD, SEM and BET. The results show that the gold preg-robbing effect was eliminated after the gasification of carbonaceous matter, and the CaO generated by decomposition of carbonates can effectively capture the SO2. After roasting for 75 min at 650 °C in a 20% O2 atmosphere, the total carbon removal rate reached 99.42%, the distribution of exposed gold increased from 28.85% to 77.10% and the gold leaching efficiency increased from 4.55% to 84.83%. In addition, about 70% sulfur was mainly fixed in the roasted products in the form of sulfate. Therefore, the suspension oxidation roasting process is an efficient and clean pretreatment method for carbonaceous gold ores. 相似文献
4.
《International Journal of Hydrogen Energy》2022,47(95):40407-40414
The present work addresses the potentialities of Pt–Ru nanoparticles deposited on a graphene oxide (RGO) and TiO2 composite support towards electrochemical oxidation of ethanol in acidic media relevant for fuel cell applications. To immobilize platinum–ruthenium bimetallic nanoparticles on to an RGO-TiO2 nanohybrid support a simple solution-phase chemical reduction method is utilized. An examination using electron microscopy and energy dispersive X-ray spectroscopy (EDS) indicated that Pt–Ru particles of 4–8 nm in diameter are dispersed on RGO-TiO2 composite support. The corresponding Pt–Ru/RGO-TiO2 nanocomposite electrocatalyst was studied for the electrochemical oxidation of ethanol in acidic media. Compared to the commercial Pt–Ru/C and Pt/C catalysts, Pt–Ru/RGO-TiO2 nanocomposite yields higher mass-specific activity of about 1.4 and 3.2 times, respectively towards ethanol oxidation reaction (EOR). The synergistic boosting provided by RGO-TiO2 composite support and Pt–Ru ensemble together contributed to the observed higher EOR activity and stability to Pt–Ru/RGO-TiO2 nanocomposite compared with other in-house synthesized Pt–Ru/RGO, Pt/RGO and commercial Pt–Ru/C and Pt/C electrocatalysts. Further optimization of RGO-TiO2 composite support provides opportunity to deposit many other types of metallic nanoparticles onto it for fuel cell electrocatalysis applications. 相似文献
5.
《International Journal of Hydrogen Energy》2022,47(61):25595-25607
Electrolysis of water for producing hydrogen instead of traditional fossil fuels is one of the most promising methods to alleviate environmental pollution and energy crisis. In this work, Fe and F ion co-doped Ni3S2 nanoarrays grown on Ni foam substrate were prepared by typical hydrothermal and sulfuration processes for the first time. Density functional theory (DFT) calculation demonstrate that the adsorption energy of the material to water is greatly enhanced due to the doping of F and Fe, which is conducive to the formation of intermediate species and the improvement of electrochemical performance of the electrode. The adsorption energy of anions (F and S) and cations (Fe and Ni) to water in each material was also calculated, and the results showed that F ion showed the most optimal adsorption energy of water, which proved that the doping of F and Fe was beneficial to improve the electrochemical performance of the electrode. It is worth noting that the surface of Fe–F–Ni3S2 material will undergo reconstruction during the process of water oxidation reaction and urea oxidation reaction, and amorphous oxides or hydroxides in situ would be formed on the surface of electrode, which are the real active species. 相似文献
6.
某铅锌矿原矿铅含量为1.26%,含锌6.53%,含硫30.38%。生产上采用“铅锌依次优先浮选-中矿顺序返回”工艺流程,生产指标为铅精矿铅品位50.69%,含锌12.61%,铅回收率75.53%,锌精矿锌品位48.77%,含铅1.59%,锌回收率73.91%。铅锌互含较高,锌精矿指标不理想。为了解决该问题,本文在了解现场生产工艺流程及矿石性质的基础上,针对该铅锌矿开展了详细的选矿工艺优化试验,通过对部分药剂制度进行优化,采用特效捕收剂BK-LY11,同时在锌浮选回路采用中矿再磨工艺,显著改善了铅锌互含情况,有效提高了铅锌选别指标,并成功应用于生产实践,优化后获得的铅、锌回收率分别提高了5.83、8.46个百分点。 相似文献
7.
本文以工业纯铝和混合稀土RE(Ce和La)为原料,制备出Al-8RE、Al-10RE和Al-15RE中间合金,并探讨了Al-RE中间合金对变形铝合金3102的细化机理。结果表明:Al-RE中间合金由α-Al、Al11RE3(Al11Ce3和Al11La3)、Ce和La组成,不同稀土含量Al-RE中间合金微观组织形貌不同,Al-8RE、Al-10RE和Al-15RE中间合金组织分别为亚共晶组织,伪共晶组织和过共晶组织,随稀土含量增加,Al-RE中间合金中Al11RE3相数量增多,尺寸增大;Al-RE中间合金对3102合金具有显著的细化效果,其中Al-10RE中间合金的细化效果最好;添加Al-RE中间合金可以提高产品性能,当添加10%RE时,性能提升最大。 相似文献
8.
采用合适的渗铝氧化处理工艺在CLAM钢基体表面制备了铝化物涂层,然后利用XRD、EPMA、SEM、纳米压痕仪、室温拉伸试验机等手段研究了渗铝氧化处理前后组织和力学性能变化,尤其是涂层的相组成变化,进而详细分析了硬度变化和拉伸断口的断裂机制。结果表明,渗铝氧化处理后在CLAM钢表面形成了由约30.8 μm厚的FeAl相层和约70.7 μm厚的α-Fe(Al)固溶体层组成的铝化物涂层,最外层FeAl相的硬度最大为834.7 HV,由外向内硬度逐渐降低至315.1 HV,基体内部的硬度出现略微回升。CLAM钢在渗铝氧化前后的抗拉强度分别为581.38 MPa和555.83 MPa,断后伸长率分别为30%和28%,断裂模式由渗铝氧化前的韧性断裂变成准解理断裂。由于渗铝及氧化热处理导致的晶粒尺寸增大和第二相粒子聚集,CLAM钢在渗铝氧化后拉伸性能下降,同时在表面涂层处易产生裂纹源从而加速材料断裂。 相似文献
9.
Alexander Van-Brunt Patrick E. Farrell Charles W. Monroe 《American Institute of Chemical Engineers》2022,68(5):e17599
We present the Onsager–Stefan–Maxwell thermodiffusion equations, which account for the Soret and Dufour effects in multicomponent fluids. Unlike transport laws derived from kinetic theory, this framework preserves the structure of the isothermal Stefan–Maxwell equations, separating the thermodynamic forces that drive diffusion from the force that drives heat flow. The Onsager–Stefan–Maxwell transport-coefficient matrix is symmetric, and the second law of thermodynamics imbues it with simple spectral characteristics. This new approach allows for heat to be considered as a pseudo-species and proves equivalent to both the intuitive extension of Fick's law and the generalized Stefan–Maxwell equations popularized by Bird, Stewart, and Lightfoot. A general inversion process facilitates the unique formulation of flux-explicit transport equations relative to any choice of convective reference velocity. Stefan–Maxwell diffusivities and thermal diffusion factors are tabulated for gaseous mixtures containing helium, argon, neon, krypton, and xenon. The framework is deployed to perform numerical simulations of steady three-dimensional thermodiffusion in a ternary gas. 相似文献
10.