Lithium/V6O13 cells using silica nanoparticle-based composite electrolyte

The electrochemical behavior of Li/V₆O₁₃ cells is investigated at room temperature (22 °C) both in liquid electrolyte consisting of oligomeric poly(ethyleneglycol)dimethylether+lithium bis(trifluoromethylsulfonylimide) and composite electrolytes formed by blending the liquid electrolyte with silica nanoparticles (fumed silica). The addition of fumed silica yields a gel-like electrolyte that demonstrates the desirable property of suppressing lithium dendrite growth due to the rigidity and immobility of the electrolyte structure. The lithium/electrolyte interfacial resistance for composite gel electrolytes is less than that for the corresponding base-liquid electrolyte, and the charge-discharge cycle performance and electrochemical efficiency for the Li/V₆O₁₃ cell is significantly improved. The effect of fumed silica surface group on the electrochemical performance is discussed; the native hydrophilic silanol surface group appears better than fumed silica that is modified with a hydrophobic octyl surface moiety.     

4Cr5MoSiV1热作模具钢锻造加热工艺的改进

攀长钢生产的4Cr5MoSiV1热作模具钢锻材存在超声波探伤合格率较低的问题。分析认为主要原因是沿用较低的锻前加热温度，钢锭加热程度不足造成锻造时大锻材中心没有充分锻透。笔者对4Cr5MoSiV1钢锻造加热工艺进行了递进式改进，逐步调整钢锭加热制度从1180℃最终提高到1270℃．1290℃，同时相应调整退火工艺制度，基本解决了上述问题，探伤废品大幅降低，锻造火次也明显减少，并避免高温加热引起的粗晶降低钢材使用性能，取得了显著的工艺改进效果。另外，采用高温加热也使钢中的显微偏析明显减轻，获得了部分的均匀化扩散退火的效果：一次碳化物减少，尺寸变小，没有尖锐的棱角，冲击韧性比工艺改进前有明显提高。     

热塑型聚氨酯结构形态的研究

本文研究了两个系列的热塑型聚氨酯—聚醚酯氨(ET)和聚酯氨酯(ES)的结构形态与相分离程度,提出了一种确定硬段含量(W_h)的IR方法。与NMR法、投料比法比较,三者得到非常吻合的结果。此外本文还研究了W_h、M_(n·■)、拉伸及热历史对相分离程度的影响。     

Processing step-related upgrading of silicon-based solar cells detected by photoluminescence spectroscopy

The aim of this work was to study the effect of solar cell processing steps on the electrical quality of the material, using photoluminescence spectroscopy as a non-contact technique. It was confirmed that consecutive steps in solar cell processing not only lead to electronic quality upgrading in Ribbon and multicrystalline silicon wafers, but also to the introduction of recombining defects. Furthermore, the importance and usefulness of photoluminescence technique on the overall improvement of the substrate material is discussed.     

DMF微滤膜的应用特点

文章阐述了微滤膜在电路板废水方面的应用,并将其与传统的斜板沉淀及现行的超滤系统进行了比较,突出了微滤系统在电路板废水回用方面的优势。     

The influence of yttrium on oxide scale growth and adherence

Alloys and coatings for high-temperature service are designed to form selectively chromia scales, alumina scales, or, to a limited extent, silica scales upon exposure to the environment. For such oxide scales to be protective, they should be both slow growing and adherent. It turns out that the addition of yttrium to such alloys can often impart both characteristics to the oxide scale. However, the actual operating mechanisms continue to be a matter of controversy among researchers in the area of oxidation. In the present study, the growth and adherence of alumina and chromia scales on alloys containing yttrium, either as an oxide dispersion or as an intermetallic phase, have been investigated in conjunction with detailed oxide scale characterization using the techniques of scanning electron microscopy (SEM), transmission electron microscopy (TEM), and secondary ion mass spectrometry (SIMS). The results of the study are used for critical assessment of the proposed mechanisms, especially the more recent ones, and to suggest some new mechanisms for adherence.     

离子注入中硼在Rp缺陷的析出模型

建立了一种析出模型用来模拟硼在硅中的扩散现象,描述了硼原子与离子注入引起的R.缺陷之间的相互作用,解释了非活性硼峰形成的原因,与实验结果能够较好的吻合,为研究硼的扩散机理提供了很好的依据,为超浅结工艺模拟提供了基本模型,对于开发下一代集成电路研制的工艺模拟程序有着非常重要的意义.     

桑黄多糖分离纯化及其结构初步鉴定

本文用离子交换和凝胶层析对桑黄多糖进行了纯化,并对多糖的结构、组成及理化常数进行了分析。结果表明,经弱碱性阴离子和弱酸性阳离子交换树脂一次串联脱蛋白,蛋白脱除率达94.96%,多糖回收率为77.77%。再经凝胶层析,得到大分子量多糖组分HHM(2.84×106Da)和小分子量多糖组分HLM(5.33×104Da),HLM和HHM的旋光度分别为[α]D25= 64.8°和[α]D25= 58.4°,由IR分析,初步推测该HHM和HLM多糖为β型吡喃多糖,由TLC法测得的HHM的单糖组成为葡萄糖,HLM单糖组成分别为葡萄糖和半乳糖。