首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   11088篇
  免费   492篇
  国内免费   688篇
电工技术   100篇
综合类   488篇
化学工业   681篇
金属工艺   5317篇
机械仪表   346篇
建筑科学   26篇
矿业工程   122篇
能源动力   411篇
轻工业   7篇
水利工程   1篇
石油天然气   9篇
武器工业   87篇
无线电   285篇
一般工业技术   3305篇
冶金工业   838篇
原子能技术   101篇
自动化技术   144篇
  2024年   11篇
  2023年   215篇
  2022年   184篇
  2021年   362篇
  2020年   343篇
  2019年   329篇
  2018年   271篇
  2017年   307篇
  2016年   232篇
  2015年   252篇
  2014年   427篇
  2013年   763篇
  2012年   492篇
  2011年   986篇
  2010年   549篇
  2009年   682篇
  2008年   610篇
  2007年   642篇
  2006年   674篇
  2005年   540篇
  2004年   532篇
  2003年   466篇
  2002年   323篇
  2001年   277篇
  2000年   259篇
  1999年   226篇
  1998年   172篇
  1997年   200篇
  1996年   133篇
  1995年   143篇
  1994年   113篇
  1993年   89篇
  1992年   80篇
  1991年   52篇
  1990年   58篇
  1989年   48篇
  1988年   23篇
  1987年   28篇
  1986年   27篇
  1985年   15篇
  1984年   22篇
  1983年   17篇
  1982年   21篇
  1981年   15篇
  1980年   14篇
  1979年   9篇
  1978年   14篇
  1977年   5篇
  1976年   7篇
  1975年   7篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
超临界二氧化碳是一种特殊的流体,具有粘度低、扩散系数大、密度大和溶解性较好等特点,因此被认为是第四代核反应堆能量传递的首选材料。由于核反应堆的工作环境十分苛刻,超临界二氧化碳应用于核反应堆系统中易造成材料腐蚀,为确保核反应堆安全有效地运行,对超临界二氧化碳腐蚀行为进行系统研究,介绍了核反应堆的发展历程,重点探讨超临界二氧化碳对合金材料腐蚀的机理,详细阐述了温度、压力、杂质和流速等因素对材料在超临界二氧化碳中腐蚀行为的影响,针对目前的研究提出了亟待解决的问题。  相似文献   
2.
Intermetallic materials are bestowed by diverse ordered superlattice structures together with many unusual properties. In particular, the advent of chemically complex intermetallic alloys (CCIMAs) has received considerable attention in recent years and offers a new paradigm to develop novel metallic materials for advanced structural applications. These newly emerged CCIMAs exhibit synergistic modulations of structural and chemical features, such as self-assembled long-range close-packed ordering, complex sublattice occupancy, and interfacial disordered nanoscale layer, potentially allowing for superb physical and mechanical properties that are unmatched in conventional metallic materials. In this paper, we critically review the historical developments and recent advances in ordered intermetallic materials from the simple binary to chemically complex alloy systems. We are focused on the unique multicomponent superlattice microstructures, nanoscale grain-boundary segregation, and disordering, as well as the various extraordinary mechanical and functional properties of these newly developed CCIMAs. Finally, perspectives on the future research orientation, challenges, and opportunities of this new frontier are provided.  相似文献   
3.
孙杨慧  陈勇  王少辉  侯乃先  孙建刚 《表面技术》2022,51(6):248-254, 290
目的 获得铝硅聚苯酯涂层在发动机不同碰磨条件下磨削物的尺寸、内部结构与其热分解特性的关系,进而揭示有毒气体产生的机理。方法 应用LS–DYNA软件计算压气机在不同运行工况下叶片的伸长量与伸长率,定义碰磨场景。应用等离子喷涂技术(APS)制备铝硅聚苯酯涂层,利用高温超高速可磨耗试验机模拟碰摩场景并开展碰摩试验。利用扫描电镜(SEM)、能谱仪(EDS)表征不同碰摩场景下磨削物颗粒的尺寸、形貌与成分。利用气相色谱–质谱连用仪对不同尺寸、形貌及内部结构的磨削物颗粒开展热分解试验,获得热分解规律及导致客舱引气污染的有害物质。结果 高转速(183 m/s)、低进给率(28μm/s)条件下,磨削物颗粒的平均尺寸约为30.8μm;高转速(183 m/s)、高进给率(257μm/s)条件下,磨削物颗粒的平均尺寸约为74μm;低转速(52 m/s)、低进给率(28μm/s)条件下,磨削物颗粒的平均尺寸约为101.8μm;低转速(52 m/s)、高进给率(257μm/s)条件下,磨削物颗粒的平均尺寸约为119.4μm。当涂层磨削物颗粒尺寸大于100μm时,在210℃附近未发生热解,仅在550℃附近有明显的热...  相似文献   
4.
RM3 compounds (R = rare earth metals, M = transition metals) have rarely been studied for gaseous hydrogen storage applications because of unfavorable thermodynamics. In this work, the hydrogen storage properties of a single-phase YFe3 alloy were improved by non-stoichiometric composition and alloying with Sc and Zr. Only the Y1.1–yScyFe3 (y = 0.22, 0.33) alloys consist of a single rhombohedral phase. The Sc substitution for Y leads to the reduction in the unit cell volume of the YFe3 phase, and thus significantly increases the dehydriding equilibrium pressure and decreases the dehydrogenation temperature. The alloy Y0.77Sc0.33Fe3 delivers a decomposition enthalpy change of 33.54 kJ/mol and a lowest dehydrogenation temperature of 135 °C, in comparison with 38.99 kJ/mol and 165 °C for the alloy Y1.1Fe3. The Zr substitution causes a similar thermodynamic destabilization effect, but the composition and microstructure of Y–Zr–Fe alloys need to be further optimized.  相似文献   
5.
钛作为食品接触材料不具备抑菌功能,使用过程中易滋生细菌对人体健康不利。文章主要介绍了钛及钛合金抑菌处理常用方法及最新的研究进展,包括合金化处理,离子注入、热喷涂、微弧氧化等表面处理方式。对抑菌钛合金的研究方向及其在日用餐具、炊具、水具等行业的应用前景作了展望。  相似文献   
6.
通过熔化极气体保护焊技术制备了Fe-C-Mo-V堆焊合金磨损试样,基于滚动三体磨粒环境下进行了干砂橡胶轮磨损试验,利用扫描电子显微镜、能谱分析、维氏硬度计等显微分析和性能测试方法,对Fe-C-Mo-V堆焊合金熔敷金属的磨损失重和磨痕形貌进行检测与表征,研究了不同法向载荷条件下该熔敷金属的磨损行为变化规律。结果表明:随法向载荷的增加,磨损失重逐渐增加,但增幅逐渐变缓;磨损机制主要为磨粒对奥氏体基体的切削及VC硬质相和层片状合金碳化物的破碎剥落;磨损后表面硬度随法向载荷的增大逐渐增加,磨痕亚表面产生显著的加工硬化,奥氏体基体转变为马氏体组织,材料的硬度增强,使得熔敷金属在高载荷下表现出较好的耐磨性。  相似文献   
7.
Laser aided additive manufacturing(LAAM)was used to fabricate bulk Fe49.5Mn30Co10Cr10C0.5 interstitial multicomponent alloy using pre-alloyed powder.The room temperature yield strength(σy),ultimate tensile strength(σUTS)and elongation(εUST)were 645 MPa,917 MPa and 27.0%respectively.The as-built sample consisted of equiaxed and dendritic cellular structures formed by elemental segregation.These cellular structures together with oxide particle inclusions were deemed to strengthen the material.The other contributing components include dislocation strengthening,friction stress and grain bound-ary strengthening.The high εUTS was attributed to dislocation motion and activation of both twinning and transformation-induced plasticity(TWIP and TRIP).Tensile tests performed at-40℃and-130℃demonstrated superior tensile strength of 1041 MPa and 1267 MPa respectively.However,almost no twinning was observed in the fractured sample tested at-40℃and-130℃.Instead,higher fraction of strain-induced hexagonal close-packed(HCP)ε phase transformation of 21.2%were observed for fractured sample tested at-40℃,compared with 6.3%in fractured room temperature sample.  相似文献   
8.
In order to determine the effect of heat treatment on the mechanical and wear properties of Zn–40Al– 2Cu–2Si alloy, different heat treatments including homogenization followed by air-cooling (H1), homogenization followed by furnace-cooling (H2), stabilization (T5) and quench–aging (T6 and T7) were applied. The effects of these heat treatments on the mechanical and tribological properties of the alloy were studied by metallography and, mechanical and wear tests in comparison with SAE 65 bronze. The wear tests were performed using a block on cylinder type test apparatus. The hardness, tensile strength and compressive strength of the alloy increase by the application of H1 and T6 heat treatments, and all the heat treatments except T6, increase its elongation to fracture. H1, T5 and T6 heat treatments cause a reduction in friction coefficient and wear volume of the alloy. However, this alloy exhibits the lowest friction coefficient and wear volume after T6 heat treatment. Therefore, T6 heat treatment appears to be the best process for the lubricated tribological applications of this alloy at a pressure of 14 MPa. However, Zn–40Al–2Cu–2Si alloy in the as-cast and heat-treated conditions shows lower wear loss or higher wear resistance than the bronze.  相似文献   
9.
High-entropy alloys (HEAs) are composed of multiple principal elements and exhibit not only remarkable mechanical properties,but also promising potentials for developing numerous new compositions.To fully realize such potentials,high-throughput preparation and characterization technologies are especially useful;thereby,the fast evaluations of mechanical properties will be urgently required.Revealing the relation between strength and hardness is of significance for quickly predicting the strength of materials through simple hardness testing.However,up to now the strength-hardness relation for HEAs is still a puzzle.In this work,the relations between tensile or compressive strength and Vickers hardness of vari-ous HEAs with hundreds of compositions at room temperature are investigated,and finally,the solution for estimating the strengths of HEAs from their hardness values is achieved.Data for hundreds of different HEAs were extracted from stud-ies reported in the period from 2010 to 2020.The results suggested that the well-known three-time relation (i.e.,hardness equals to three times the magnitude of strength) works for nearly all HEAs,except for a few brittle HEAs which show quite high hardness but low strength due to early fracture.However,for HEAs with different phase structures,different strengths should be applied in using the 3-time relation,i.e.,yield strength for low ductility body-centered cubic (BCC) HEAs and ultimate strength for highly plastic and work-hardenable face-centered cubic (FCC) HEAs.As for dual-phase or multi-phase HEAs,similar 3-time relations can be also found.The present approach sheds light on the mechanisms of hardness and also provides useful guidelines for quick estimation of strength from hardness for various HEAs.  相似文献   
10.
The objective of this study is to establish the corrosion behaviour of the most important structural constituents of the aluminium alloy 2017 in orthophosphoric acid solutions containing heteropolyoxomolybdate, tungstate and vanadate. These are potential candidates for replacing toxic hexavalent chromium species in stripping solution for anodic coatings. The corrosion rate of the alloy is estimated with linear polarisation method. It decreases from 0.58 mA cm−2 in uninhibited solution to 0.10 mA cm−2 in a solution containing heteropolyoxomolybdate species. Microscopic studies reveal that heteropolyoxomolybdate species inhibit corrosion of the matrix and intermetallic Al15(Fe,Mn)3(Si,Cu)2 but not Mg2Si. Intermetallic Al2Cu remains not corroded. Heteropolyoxotungstate species virtually do not inhibit the corrosion of the alloy. The solution containing vanadium species is not stable with time and the corrosion rate is not determined. Nevertheless, corrosion of the matrix is inhibited, but intermetallics Al15(Fe,Mn)3(Si,Cu)2 together with Mg2Si are dissolved. X-ray photoelectron spectroscopy is used for examination of a corrosion product precipitated on the surface.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号