高效液相色谱法测定化妆品中依克多因的含量

建立高效液相色谱法测定化妆品中依克多因的分析方法,采用Agilent Poroshell 120 EC-C₁₈色谱柱（100 mm×3.0 mm,2.7μm）分离,以甲醇和p H为3.0的40 mmol/L磷酸二氢钠-10 mmol/L 1-庚烷磺酸钠缓冲溶液梯度洗脱,流速0.8 m L/min,柱温30℃,检测波长210 nm。采用外标法定量测定化妆品中的依克多因含量。结果表明,依克多因在5～800 mg/L的质量浓度范围内呈现良好线性关系,相关系数为0.999 8,方法的检出限和定量限分别为0.3和1.0 mg/L。该方法具有分离效率高、分析时间短、节省溶剂等优点,解决了依克多因在C₁₈色谱柱上保留弱的问题。     

Impact of TiO2 nanoparticles and nanowires on corrosion protection performance of chemically bonded phosphate ceramic coatings

The impact of the addition of TiO₂ nanoparticles and nanowires on the morphology, phase characteristics, contact angle, and electrochemical performance of chemically bonded phosphate ceramic coatings (CBPCs) was investigated. The chemical composition and surface morphology of the TiO₂ nanoparticle and nanowire modified with and without (heptadecafluoro-1,1,2,2-tetradecyl) trimethoxysilane were characterized. Results indicated that the hydrophobic –CF₂– and –CF₃ groups were successfully introduced into the TiO₂ nanoparticles and nanowires after modification. Corrosion resistance of CBPCs with TiO₂ was evidently improved compared with that without TiO₂. Such improvement was mainly due to the combined effects of low surface energy materials and micro/nano structures. In addition, CBPCs with TiO₂ nanowires exhibited higher hydrophobicity and corrosion resistance than those with TiO₂ nanoparticles because of the special columnar structure of the nanowires.     

Predictive environmental hydrogen embrittlement on fracture toughness of commercial ferritic steels with hydrogen-modified fracture strain model

In this work, a practical numerical model with few parameters was proposed for the prediction of environmental hydrogen embrittlement. The proposed method adopts hydrogen enhanced plasticity-based mechanism in a fracture strain model to describe hydrogen embrittlement. Fracture toughness degradation of three commercial steels SA372J70, AISI4130 and X80 in high pressure hydrogen environment were investigated. Firstly, governing equations for hydrogen distribution and material damage evolution was established. Hydrogen enhanced localized flow softening effect was coupled within fracture strain dependency on stress triaxiality. Then, the numerical implementation and identification process of model parameters was described. Model parameters of the investigated steels were determined based on experiment results from literatures. Finally, with the calibrated model, fracture toughness reduction of the steels was predicted in a wide range of hydrogen pressure. The prediction results were compared with experimental results. Reasonable accuracy was reached. The proposed method is an attempt to reach balance between physical accurate prediction and engineering practicality. It is promising to provide a simplified numerical tool for the design and fit for service evaluation of hydrogen storage vessels.     

Comparative study of embrittlement of quenched and tempered steels in hydrogen environments

The study of steels which guarantee safety and reliability throughout their service life in hydrogen-rich environments has increased considerably in recent years. Their mechanical behavior in terms of hydrogen embrittlement is of utmost importance. This work aims to assess the effects of hydrogen on the tensile properties of quenched and tempered 42CrMo4 steels. Tensile tests were performed on smooth and notched specimens under different conditions: pre-charged in high pressure hydrogen gas, electrochemically pre-charged, and in-situ hydrogen charged in an acid aqueous medium. The influence of the charging methodology on the corresponding embrittlement indexes was assessed. The role of other test variables, such as the applied current density, the electrolyte composition, and the displacement rate was also studied. An important reduction of the strength was detected when notched specimens were subjected to in-situ charging. When the same tests were performed on smooth tensile specimens, the deformation results were reduced. This behavior is related to significant changes in the operative failure micromechanisms, from ductile (microvoids coalescence) in absence of hydrogen or under low hydrogen contents, to brittle (decohesion of martensite lath interfaces) under the most stringent conditions.     

A Ti3C2Tx-carbon black-acrylic epoxy coating for 304SS bipolar plates with enhanced corrosion resistant and conductivity

A conducting and anticorrosive coating is crucial for the application of metal bipolar plates (BP) in proton exchange membrane fuel cell (PEMFC). In this work, a Ti₃C₂T_x (T)-carbon black (C)-acrylic epoxy (AE) coating is prepared on 304 stainless steel (SS) with enhanced corrosion resistance and conductivity. The corrosion resistance of the T-C-AE coating is investigated in a 0.5 M H₂SO₄ solution as compared to the AE, T, and T-AE coatings. The T-C-AE coated 304SS exhibits the strongest corrosion resistance with the most positive corrosion potential and the lowest corrosion current density of 0.00673 μA cm^?2 in all the samples, while retaining intact and compact surface morphology with the lowest metal ion dissolution even after immersed for 720 h. The addition of Ti₃C₂T_x and carbon black into the AE matrix greatly decreases interfacial contact resistance (ICR), and the T-C-AE coating achieves a low ICR of 15.5 mΩ cm^?2 under 140 N cm^?2 compaction force. The excellent anticorrosion performance is mainly attributed to the physical barrier and the cathodic protection provided by the stacked Ti₃C₂T_x (MXene) nanosheets in the T-C-AE coating. This eco-friendly, conducting, and anticorrosive T-C-AE coating has a good application prospect on SS BP of PEMFC.     

Ammonia mitigation and induction effects on hydrogen environment embrittlement of SCM440 low-alloy steel

The effect of ammonia (NH₃) contained in hydrogen (H₂) gas on hydrogen environment embrittlement (HEE) of SCM440 low-alloy steel was studied in association with the NH₃ concentration, loading rate, and gas pressure. NH₃ worked as both mitigator of the HEE and inducer of hydrogen embrittlement (HE) depending on the testing conditions. The mitigation of the HEE was achieved by the deactivation of the iron (Fe) surface for H₂ dissociation caused by the preferential adsorption of NH₃ on the Fe surface, which is enhanced by the increase in the NH₃ concentration and decrease in the H₂ gas pressure. NH₃ induced HE was caused due to creating hydrogen by the NH₃ decomposition. Since the NH₃ decomposition rate is low, the induction effect was observed when the loading rate was low. The effect of NH₃ was determined by the competition of the mitigation and induction effects.     

Cheese ripening in nonconventional conditions: A multiparameter study applied to Protected Geographical Indication Canestrato di Moliterno cheese

A multiparameter study was performed to evaluate the effect of fondaco, a traditional ripening cellar without any artificial temperature and relative humidity control, on the chemical, microbiological, and sensory characteristics of Protected Geographical Indication Canestrato di Moliterno cheese. Ripening in such a nonconventional environment was associated with lower counts of lactococci, lactobacilli, and total viable bacteria, and higher presence of enterococci, in comparison with ripening in a controlled maturation room. Moreover, fondaco cheese underwent accelerated maturation, as demonstrated by faster casein degradation, greater accumulation of free AA, and higher formation of volatile organic compounds. Secondary proteolysis, as assessed by liquid chromatography-mass spectrometry of free AA and low molecular weight peptides, did not show any qualitative difference among cheeses, but fondaco samples evidenced an advanced level of peptidolysis. On the other hand, significant qualitative differences were observed in the free fatty acid profiles and in the sensory characteristics. Principal component analysis showed a clear separation of the fondaco and control cheeses, indicating that ripening in the natural room conferred unique sensory features to the product.     

配分工艺对中碳Ti-Mo高强Q&P钢组织和性能的影响

摘要：采用盐浴实验、扫描电镜、透射电镜、拉伸实验和磨损实验等手段，研究了配分工艺对中碳Ti Mo钢组织和性能的影响，分析了不同配分工艺处理下的组织演变和性能变化。结果表明，显微组织主要由回火马氏体、渗碳体、(Ti，Mo)C粒子组成。随着配分时间的延长和配分温度的升高，板条马氏体数量减少，马氏体板条厚度增加，边界钝化。此外，随着配分温度从310℃提高至400℃，抗拉强度、硬度和低温冲击韧性同时下降，分别降低约250MPa、56HV和15J。最后，Ms以下温度配分（310℃）试样的耐磨损性能明显优于Ms以上温度配分（400℃）试样。Ms以下温度配分试样磨损表面形貌以塑性变形为主，Ms以上温度配分试样磨损表面以犁沟为主。     

A Smart Deep Convolutional Neural Network for Real-Time Surface Inspection

A proper detection and classification of defects in steel sheets in real time have become a requirement for manufacturing these products, largely used in many industrial sectors. However, computers used in the production line of small to medium size companies, in general, lack performance to attend real-time inspection with high processing demands. In this paper, a smart deep convolutional neural network for using in real-time surface inspection of steel rolling sheets is proposed. The architecture is based on the state-of-the-art SqueezeNet approach, which was originally developed for usage with autonomous vehicles. The main features of the proposed model are: small size and low computational burden. The model is 10 to 20 times smaller when compared to other networks designed for the same task, and more than 700 times smaller than general networks. Also, the number of floating-point operations for a prediction is about 50 times lower than the ones used for similar tasks. Despite its small size, the proposed model achieved near-perfect accuracy on a public dataset of 1800 images of six types of steel rolling defects.