全文获取类型
收费全文 | 4064篇 |
免费 | 475篇 |
国内免费 | 245篇 |
专业分类
电工技术 | 95篇 |
技术理论 | 2篇 |
综合类 | 241篇 |
化学工业 | 1502篇 |
金属工艺 | 407篇 |
机械仪表 | 175篇 |
建筑科学 | 90篇 |
矿业工程 | 53篇 |
能源动力 | 152篇 |
轻工业 | 296篇 |
水利工程 | 10篇 |
石油天然气 | 129篇 |
武器工业 | 55篇 |
无线电 | 315篇 |
一般工业技术 | 1047篇 |
冶金工业 | 141篇 |
原子能技术 | 5篇 |
自动化技术 | 69篇 |
出版年
2024年 | 7篇 |
2023年 | 79篇 |
2022年 | 99篇 |
2021年 | 167篇 |
2020年 | 150篇 |
2019年 | 153篇 |
2018年 | 164篇 |
2017年 | 214篇 |
2016年 | 194篇 |
2015年 | 176篇 |
2014年 | 248篇 |
2013年 | 246篇 |
2012年 | 285篇 |
2011年 | 322篇 |
2010年 | 219篇 |
2009年 | 216篇 |
2008年 | 180篇 |
2007年 | 259篇 |
2006年 | 257篇 |
2005年 | 260篇 |
2004年 | 230篇 |
2003年 | 206篇 |
2002年 | 179篇 |
2001年 | 107篇 |
2000年 | 57篇 |
1999年 | 37篇 |
1998年 | 24篇 |
1997年 | 18篇 |
1996年 | 11篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1993年 | 2篇 |
1992年 | 4篇 |
1991年 | 3篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1987年 | 1篇 |
排序方式: 共有4784条查询结果,搜索用时 125 毫秒
1.
An ecofriendly and biodegradable porous structure was prepared from drying aqueous foams based on nano fibrillated cellulose (NFC), extracted from softwood pulp by subcritical water/CO2 treatment (SC-NFC). The primary aim of this work was to use the modified SC-NFC as stabilizer for a water-based Pickering emulsion which upon drying, yielded porous cellulosic materials, a good dye adsorbent. In order to exploit the carboxymethylated SC-NFC (CMSC-NFC, with a degree of substitution of 0.35 and a charge density of 649 μeqv/g) as a stabilizer for water-based Pickering emulsion in subsequent step, an optimized quantity of octyl amine (30 mg/g of SC-NFC) was added to make them partially hydrophobic. A series of dry foam structures were prepared by varying the concentrations of treated CMSC-NFCs and 4 wt% was found to be the optimum concentration to yield foam with high porosity (99%) and low density (0.038 g/cc) along with high compression strength (0.24 MPa), superior to the conventionally extracted NFC. The foams were applied to capture as high as 98% of methylene blue dyes, making them a potential green candidate for treating industrial effluent. In addition, the dye adsorption kinetics and isotherms were found to be well suited with second order kinetics and Langmuir isotherm models. 相似文献
2.
《Ceramics International》2021,47(23):32610-32618
AA7075 + 6%B4C+3%ZrC nano hybrid composite was successfully fabricated, with nano reinforcements composition in AA7075 alloy selected based on previous investigation, to achieve better mechanical performance. Two different sintering techniques, namely conventional and microwave, were implemented to determine the effect on microstructural and mechanical properties. Microstructural investigation was performed with the help of W-SEM. Tensile, compression, and hardness were measured with the help of UTM and Vickers microhardness machine. Porosity was calculated by using Archimedes principle. It was observed that the added nano ZrC particles formed agglomerates and the B4C particles were distributed homogenously. Composites processed by microwave sintering showed excellent mechanical properties compared to the conventionally sintered composites. No intermetallic compounds were detected in microwave sintered composites through XRD analysis, indicating strong and clean interface bonds between matrix and reinforcement particles. High strain to fracture value of 12.24% was noted in microwave sintered nano hybrid composite, while it was 6.12% for conventional sintered one. Fractography revealed no peeling action of reinforcements from the matrix material, and the mode of failure was brittle. It was concluded that, while fabricating nano range hybrid composites, the implementation of advanced sintering technique (microwave sintering) with low sintering temperatures and low sintering times with internal heat generations, helps in eliminating defects that may develop because of high surface energies of nano range reinforcements. 相似文献
3.
《International Journal of Hydrogen Energy》2022,47(14):8716-8728
In this study, lignin was gasified in supercritical water with catalysis of CuO–ZnO synthesized by deposition precipitation, co-precipitation and sol-gel methods. Sol-gel synthesized CuO–ZnO showed the highest catalytic performance, and the gasification efficiency was increased by 37.92% with it. The XRD, SEM-EDS and N2 adsorption/desorption analysis showed that the priority of the sol-gel catalyst was the smallest crystallite size, largest specific surface area and high dispersion. For sol-gel synthesized CuO–ZnO, the increase of CuO/ZnO ratio improved the gasification efficiency but reduced H2 selectivity. And the catalytic activity was reduced with the calcination temperature above 600 °C due to enlarged crystallites and reduced pores. During sol-gel preparation, both the addition of ethanol and PEG in the solvent reduced the agglomeration and improved the catalytic activity. With CuO–ZnO prepared with 1 g PEG + water as the solvent, the highest H2 yield of 6.86 mol/kg was obtained, which was over 1.5 times of that without catalyst. 相似文献
4.
Water contamination is a global challenge impacting both the environment and human health with significant economic and social costs. The growing scarcity of usable water resources requires effective treatment of wastewater. In this context, developing cheaper, safer and more efficient wastewater treatment technologies are the need of the hour. One promising approach that several studies have reported success has been the usage of nanomaterials in water and waste water management. The rapid progress of research in nanomaterial sciences has shown their growing potential; however, there has not been a great amount of information available on their implementation. This review focuses on developments in nanotechnology that hold strong potential for wastewater treatment. The review covers key techniques in nanomaterial‐based water treatments including adsorption, filtration and photocatalysis with recent examples showing how to improve their properties and efficiencies according to the need. 相似文献
5.
6.
为探究挠性筋结构单晶硅材料的各向异性特性以及KOH腐蚀工艺对其力学性能的影响规律,进行纳米压痕实验,并结合原子力显微镜观察单晶硅表层3个主晶面上压痕裂纹形貌随晶向的变化规律,分析单晶硅材料表层弹性模量、硬度、断裂韧性等机械力学特性参数在(001)、(110)及(111)3个主要晶面上沿各个晶向的变化规律;分析挠性筋结构单晶硅材料(001)晶面的KOH腐蚀工艺对其材料表面机械特性的影响规律.结果表明:挠性筋单晶硅在(001)晶面上弹性模量的各向异性变化幅度明显,硬度及断裂韧性各向异性的变化幅度不大;挠性筋单晶硅在(110)晶面弹性模量和断裂韧性的各向异性变化幅度明显,硬度各向异性变化幅度不大;挠性筋单晶硅在(111)晶面硬度值、弹性模量及断裂韧性参数的变化幅度幅值均较小;确定了单晶硅表层3个晶面裂纹最易扩展的晶向方向,KOH腐蚀工艺使得单晶硅表面质量降低,腐蚀后暴露的表面微裂纹、缺陷等会使得单晶硅(001)晶面表层硬度、断裂韧性降低,从而降低了挠性筋结构的实际断裂强度. 相似文献
7.
Manika Chaudhary Milan Singh Ashwani Kumar Yogendra K. Gautam Anil K. Malik Yogesh Kumar Beer Pal Singh 《Ceramics International》2021,47(2):2094-2106
The current research work presents a facile and cost–effective co-precipitation method to prepare doped (Co & Fe) CuO and undoped CuO nanostructures without usage of any type of surfactant or capping agents. The structural analysis reveals monoclinic crystal structure of synthesized pure CuO and doped-CuO nanostructures. The effect of different morphologies on the performance of supercapacitors has been found in CV (cyclic voltammetry) and GCD (galvanic charge discharge) investigations. The specific capacitances have been obtained 156 (±5) Fg?1, 168(±5) Fg?1 and 186 (±5) Fg?1 for CuO, Co-doped CuO and Fe-doped CuO electrodes, respectively at scan rate of 5 mVs?1, while it is found to be 114 (±5) Fg?1, 136 (±5) Fg?1 and 170 (±5) Fg?1 for CuO, Co–CuO and Fe–CuO, respectively at 0.5 Ag-1 as calculated from the GCD. The super capacitive performance of the Fe–CuO nanorods is mainly attributed to the synergism that evolves between CuO and Fe metal ion. The Fe-doped CuO with its nanorods like morphology provides superior specific capacitance value and excellent cyclic stability among all studied nanostructured electrodes. Consequently, it motivates to the use of Fe-doped CuO nanostructures as electrode material in the next generation energy storage devices. 相似文献
8.
Luca Pezzato Leonardo Bertolucci Coelho Rachele Bertolini Alessio Giorgio Settimi Katya Brunelli Marjorie Olivier Manuele Dabal 《工业材料与腐蚀》2019,70(11):2103-2112
Plasma electrolytic oxidation (PEO) coatings were produced on AZ80 magnesium alloy in a solution containing silicates and phosphates and working at high current densities with short treatment times. The effect of a sealing treatment in boiling water on corrosion and mechanical properties of the coatings were investigated. Moreover, the corrosion mechanism of the samples with and without the sealing treatment was evaluated. The microstructure of the coatings was characterized with scanning electron microscope observation and X‐ray diffraction analysis. The mechanical properties were evaluated with nanoindentation tests and the corrosion resistance was studied by potentiodynamic polarization, electrochemical impedance spectroscopy, and scanning vibrating electrode technique. The results showed that the sealing did not influence the microstructure and the mechanical properties of the samples and instead produced a remarkable increase in the corrosion resistance. The crevice corrosion, present in the sample without the sealing, was avoided with the treatment in boiling water. 相似文献
9.
Akihiro Nishiguchi Fumisato Sasaki Hidehito Maeda Masayuki Kabayama Akio Ido Tetsushi Taguchi 《Small (Weinheim an der Bergstrasse, Germany)》2019,15(35)
Endoscopic submucosal dissection (ESD) provides strong therapeutic benefits for early gastrointestinal cancer as a minimally invasive treatment. However, there is currently no reliable treatment to prevent scar contracture resulting from ESD which may lead to cicatricial stricture. Herein, a multifunctional colloidal wound dressing to promote tissue regeneration after ESD is demonstrated. This sprayable wound dressing, composed of hydrophobized microparticles, exhibits the multifunctionality necessary for wound healing including tissue adhesiveness, blood coagulation, re‐epithelialization, angiogenesis, and controlled inflammation based on hydrophobic interaction with biological systems. An in vivo feasibility study using swine gastric ESD models reveals that this colloidal wound dressing suppresses fibrosis and accelerates wound healing. Multifunctional colloidal and sprayable wound dressings have an enormous therapeutic potential for use in a wide range of biomedical applications including accelerated wound healing after ESD, prevention of perforation, and the treatment of inflammatory diseases. 相似文献
10.
Multicellular tumor spheroid models (MCTS) are often coined as 3D in vitro models that can mimic the microenvironment of tissues. MCTS have gained increasing interest in the nano‐biotechnology field as they can provide easily accessible information on the performance of nanoparticles without using animal models. Considering that many countries have put restrictions on animals testing, which will only tighten in the future as seen by the recent developments in the Netherlands, 3D models will become an even more valuable tool. Here, an overview on MCTS is provided, focusing on their use in cancer research as most nanoparticles are tested in MCTS for treatment of primary tumors. Thereafter, various types of nanoparticles—from self‐assembled block copolymers to inorganic nanoparticles, are discussed. A range of physicochemical parameters including the size, shape, surface chemistry, ligands attachment, stability, and stiffness are found to influence nanoparticles in MCTS. Some of these studies are complemented by animal studies confirming that lessons from MCTS can in part predict the behaviour in vivo. In summary, MCTS are suitable models to gain additional information on nanoparticles. While not being able to replace in vivo studies, they can bridge the gap between traditional 2D in vitro studies and in vivo models. 相似文献