全文获取类型
收费全文 | 39937篇 |
免费 | 4484篇 |
国内免费 | 2695篇 |
专业分类
电工技术 | 2223篇 |
综合类 | 3523篇 |
化学工业 | 8063篇 |
金属工艺 | 3704篇 |
机械仪表 | 2136篇 |
建筑科学 | 1571篇 |
矿业工程 | 2233篇 |
能源动力 | 503篇 |
轻工业 | 1490篇 |
水利工程 | 270篇 |
石油天然气 | 991篇 |
武器工业 | 435篇 |
无线电 | 7173篇 |
一般工业技术 | 5777篇 |
冶金工业 | 3942篇 |
原子能技术 | 444篇 |
自动化技术 | 2638篇 |
出版年
2024年 | 137篇 |
2023年 | 609篇 |
2022年 | 936篇 |
2021年 | 1209篇 |
2020年 | 1334篇 |
2019年 | 1086篇 |
2018年 | 1105篇 |
2017年 | 1371篇 |
2016年 | 1416篇 |
2015年 | 1552篇 |
2014年 | 2218篇 |
2013年 | 2339篇 |
2012年 | 2810篇 |
2011年 | 2815篇 |
2010年 | 2058篇 |
2009年 | 2263篇 |
2008年 | 2065篇 |
2007年 | 2635篇 |
2006年 | 2578篇 |
2005年 | 2246篇 |
2004年 | 1948篇 |
2003年 | 1664篇 |
2002年 | 1460篇 |
2001年 | 1299篇 |
2000年 | 1084篇 |
1999年 | 821篇 |
1998年 | 680篇 |
1997年 | 559篇 |
1996年 | 494篇 |
1995年 | 410篇 |
1994年 | 394篇 |
1993年 | 294篇 |
1992年 | 280篇 |
1991年 | 223篇 |
1990年 | 162篇 |
1989年 | 133篇 |
1988年 | 89篇 |
1987年 | 61篇 |
1986年 | 43篇 |
1985年 | 47篇 |
1984年 | 45篇 |
1983年 | 25篇 |
1982年 | 32篇 |
1981年 | 20篇 |
1980年 | 9篇 |
1979年 | 10篇 |
1977年 | 8篇 |
1975年 | 5篇 |
1974年 | 10篇 |
1951年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
2.
《Journal of the European Ceramic Society》2020,40(1):103-107
Tunable and ultrabroadband mid-infrared (MIR) emissions in the range of 2.5–4.5 μm are firstly reported from Co2+-doped nano-chalcogenide (ChG) glass composites. The composites embedded with a variety of binary (ZnS, CdS, ZnSe) and ternary (ZnCdS, ZnSSe) ChG nanocrystals (NCs) can be readily obtained by a simple one-step thermal annealing method. They are highly transparent in the near- and mid-infrared wavelength region. Low-cost and commercially available Er3+-doped fiber lasers can be used as the excitation source. By crystal-field engineering of the embedded NCs through cation- or anion-substitution, the emission properties of Co2+ including its emission peak wavelength and bandwidth can be tailored in a broad spectral range. The phenomena can be accounted for by crystal-field theory. Such nano-ChG composites, perfectly filling the 3–4 μm spectral gap between the oscillations of Cr2+ and Fe2+ doped IIVI ChG crystals, may find important MIR photonic applications (e.g., gas sensing), or can be used directly as an efficient pump source for Fe2+: IIVI crystals which are suffering from lack of pump sources. 相似文献
3.
The surface chemistry and mineral liberation changes of a porphyry copper ore after high voltage pulse (HVP) electrical comminution have been investigated using X-ray photoelectron spectroscopy (XPS) and mineral liberation analysis (MLA). Previous studies suggest that electrical comminution has the potential to improve downstream flotation recoveries, due to increased mineral liberation. However, until now the effects on the surface chemistry have not been investigated in detail.The mineral liberation results showed that chalcopyrite was more liberated in the electrical comminution product than in mechanical comminution, noticeably in the coarser size fractions. The surface chemistry of pure chalcopyrite was investigated, using XPS, and high resolution scans of iron and sulphur showed that both comminution methods led to iron oxidising preferentially leaving behind a passivating film of copper sulphides. However, the HVP product oxidisation was more severe with more iron oxide being produced and further oxidation of the remaining copper sulphides into copper sulphate. An attrition grinding stage may be useful in removing the oxidised layer from the surface of the particles prior to flotation separation. This paper presents a new application of the HVP technology in hybrid procedures using electrical comminution and mechanical grinding to prepare the flotation feed, rather than using excessive pulse energy to fully disintegrate ore to the flotation size. Better liberation and flotation performance were achieved through the hybrid procedures than the comparative mechanical comminution. 相似文献
4.
5.
P(DBF-VA)型柴油低温流动性改进剂的研制 总被引:1,自引:1,他引:0
针对新疆地产柴油蜡含量较高的特点,以游离基聚合法合成了富马酸双链混合酯和醋酸乙烯酯共聚物型[P(DBF-VA)]柴油低温流动改进剂,利用正交实验研究了单体配比,引发剂用量,溶剂用量,聚合温度对聚合物降冷滤效果的影响。共聚物用IR进行表征,利用XRD初步探讨了该降凝剂的降凝机理。结果表明:该剂能使吐哈—10~#、0~#柴油冷滤点降低10℃和7℃;使独山子0~#柴油冷滤点下降12℃;使石化0~#柴油冷滤点下降8℃;使克拉玛依0~#柴油的冷滤点下降8℃。 相似文献
6.
针对甲醇液相氧化羰基化法合成碳酸二甲酯(DMC)工艺,开发了新型Cu基络合催化剂(CuB rnLm)。对CuB rnLm催化剂的活性及其稳定性进行了研究。实验结果表明,采用该催化剂,甲醇转化率和DMC选择性较高;元素价态和物质结构分析表明,CuB rnLm催化剂循环使用5次后仍保持较好的稳定性。采用正交设计和中心响应曲面法设计实验,并使用S tatistica软件进行统计分析,寻求出反应的主要影响因素,并得到优化的工艺条件:反应温度100~110℃、反应压力3.0~3.5M Pa、反应时间4~6h、CuB rnLm催化剂质量浓度(以甲醇的体积计)0.15~0.20g/mL。在此工艺条件下,甲醇转化率可达23%以上,DMC的选择性为96%~98%。 相似文献
7.
2.4GHz动态CMOS分频器的设计 总被引:1,自引:0,他引:1
对现阶段的主流高速CMOS分频器进行分析和比较,在此基础上设计一种采用TSPC(truesingle phase clock)和E-TSPC(extended TSPC)技术的前置双模分频器电路.该分频器大大提高了工作频率,采用0.6μm CMOS工艺参数进行仿真的结果表明,在5V电源电压下,最高频率达到3GHz,功耗仅为8mW. 相似文献
8.
9.
《Nuclear instruments & methods in physics research. Section A, Accelerators, spectrometers, detectors and associated equipment》2003,510(3):248-261
The energy dependence of the energy and position resolutions of the electromagnetic calorimeter prototype made of lead tungstate crystals produced in Bogoroditsk (Russia) and Shanghai (China) is presented. These measurements were carried out at the Protvino accelerator using a 1–45 GeV electron beam. The crystals were coupled to photomultiplier tubes. The dependence of energy and position resolutions on different factors as well as the measured electromagnetic shower lateral profile are presented. 相似文献
10.
Hisakatsu HamaKohji Tashiro 《Polymer》2003,44(22):6973-6988
Structural evolution in the isothermal crystallization process of polyoxymethylene from the molten state has been investigated by carrying out the time-resolved measurements of infrared spectra and synchrotron small angle X-ray scattering (SAXS) and wide angle X-ray scattering. In case of isothermal crystallization at 130 °C, for example, the infrared bands intrinsic of folded chain crystal (FCC) morphology appeared at first, and then the bands of extended chain crystal (ECC) morphology were detected with time delay of ca. 150 s. In the SAXS experiment at 130 °C, the lamellar stacking structure of the long period of ca. 15 nm was observed at first, which changed rapidly to ca. 12 nm in a short time. The SAXS peak with the long period of ca. 6 nm started to appear with a time delay of ca. 150 s after the initial lamellae appeared and coexisted with the initially-observed 12 nm peak. Judging from the timing to detect these characteristic infrared and SAXS signals, a good correspondence was found to exist between the stacked lamellar structure of 12 nm long period and FCC morphology and between the structure of 6 nm long period and ECC morphology. The quantitative analysis was made for the SAXS data on the basis of the lamellar insertion model combined with the paracrystalline theory of the second-kind of disorder. The following structural evolution was deduced from all these results. Immediately after the temperature jump from the melt to 130 °C, the stacked lamellar structure of FCC morphology was generated at first. New lamellae were formed from the amorphous region in between the originally-existing lamellae about 150 s later, where the random chain segments bridging the adjacent lamellae were extended to form the taut tie chains, giving infrared bands of ECC morphology. This inserted lamellar structure of 6 nm long period coexisted at a population of ca. 6% with the initially-formed lamellar stacking structure of 12 nm long period. When the experiment was made at 150 °C, only the formation of stacked lamellar structure of FCC morphology was observed and the insertion of new lamella did not occur. 相似文献