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1.
《Journal of the European Ceramic Society》2022,42(14):6614-6623
Low-thermal conductivity ceramics play an indispensable role in maximizing the efficiency and durability of hot end components. Pyrochlore, particularly zirconate pyrochlore, is currently a highly promising and widely studied candidate for its extremely low thermal conductivity. However, there are still few pyrochlores that offer both stiffness, insulation, and good thermal expansion properties. In this work, the solidification method was innovatively introduced into the preparation of titanate pyrochlore, and combined it with the compositional design of high-entropy. Through careful composition design and solidification control, the high-density and uniform elements distributed high-entropy titanate pyrochlore ceramics were successfully prepared. These samples possess high hardness (15.88 GPa) and Young’s modulus (295.5 GPa), low thermal conductivity (0.947 W·m?1·K?1), excellent thermal expansion coefficient (11.6 ×10?6/K) and an exquisite balance between stiffness and insulation (E/κ, 312.1 GPa·W?1·m·K), in which the E/κ exhibits the highest value among the current reported works. 相似文献
2.
针对薄板坯在凝固过程中容易出现铸坯裂纹、疏松、缩孔等质量问题,以某厂生产的高拉速薄板坯为研究对象,通过建立传热凝固有限元和元胞自动机相结合的CAFE模型,基于ProCAST平台开展凝固传热全过程数值计算,探究不同拉速下的结晶器末端坯壳生长情况、不同拉速对凝固传热过程的温度场和三维凝固组织的影响。结果表明,在不同的拉速下,坯壳在结晶器内不同高度处的厚度差异逐步分化,越是接近结晶器下口,坯壳减薄越发明显。拉速每增加0.2 m/min,结晶器末端的坯壳厚度减薄约0.2 mm,凝固末端液相穴的长度增加0.3 m。拉速提高时,铸坯横截面上晶粒总数目会随之减少,平均晶粒面积也呈现出减少的趋势。 相似文献
3.
《中国有色金属学会会刊》2021,31(10):3063-3074
The transient liquid phase (TLP) bonding of CoCuFeMnNi high entropy alloy (HEA) was studied. The TLP bonding was performed using AWS BNi-2 interlayer at 1050 °C with the TLP bonding time of 20, 60, 180 and 240 min. The effect of bonding time on the joint microstructure was characterized by SEM and EDS. Microstructural results confirmed that complete isothermal solidification occurred approximately at 240 min of bonding time. For samples bonded at 20, 60 and 180 min, athermal solidification zone was formed in the bonding area which included Cr-rich boride and Mn3Si intermetallic compound. For all samples, the γ solid solution was formed in the isothermal solidification zone of the bonding zone. To evaluate the effect of TLP bonding time on mechanical properties of joints, the shear strength and micro-hardness of joints were measured. The results indicated a decrement of micro-hardness in the bonding zone and an increment of micro-hardness in the adjacent zone of joints. The minimum and maximum values of shear strength were 100 and 180 MPa for joints with the bonding time of 20 and 240 min, respectively. 相似文献
4.
分别从热力学和动力学方面研究了低碳含钛微合金钢凝固过程选分结晶对TiN夹杂物析出的影响。热力学分析表明,液相线温度以上不会有TiN析出;由于凝固过程凝固前沿Ti、N元素富集,凝固分数达到0.377时,凝固前沿固相中开始析出TiN;凝固末期,Ti和N的富集程度进一步增大,固液相中均有TiN析出。动力学分析表明,随着冷却速度的降低,凝固过程TiN夹杂物的尺寸显著增加,当冷速高于50 K/s时,TiN的理论半径为5.5 μm,当冷速低于5 K/s时,TiN的理论半径在17.5 μm以上;固相中析出的TiN为纳米级别。铸坯中TiN析出物主要尺寸为1~5 μm,且大尺寸夹杂主要在铸坯厚度方向的1/4处和中心处析出,这表明铸坯中的大尺寸夹杂物是在凝固过程中析出的。 相似文献
5.
Jiancheng Shu Xiangfei Zeng Danyang Sun Yong Yang Zuohua Liu Mengjun Chen Daoyong Tan 《中国化学工程学报》2022,49(9):205-212
Electrolytic manganese metal residue (EMMR) harmless treatment has always lacked a low-cost and quick processing technology. In this study, surfactants, namely tetradecyl trimethylammonium chloride (TTC), sodium dodecyl benzene sulfonate (SDBS), sodium lignin sulfonate (SLS), and octadecyl trimethylammonium chloride (OTC), were used in the solidification of Mn2+ and removal of NH4+-N from EMMR. The Mn2+ and NH4+-N concentrations under different reaction conditions, Mn2+ solidification and NH4+-N removal mechanisms, and leaching behavior were studied. The results revealed that the surfactants could enhance the Mn2+ solidification and NH4+-N removal from EMMR, and the order of enhancement was as follows: TTC > SDBS > OTC > SLS. The NH4+-N and Mn2+ concentrations were 12.3 and 0.05 mg·L-1 with the use of 60.0 mg·kg-1 TTC under optimum conditions (solid–liquid ratio of 1.5:1, EMMR to BRM mass ratio of 100:8, temperature of 20 ℃, and reaction duration of 12 h), which met the integrated wastewater discharge standard (GB8978-1996). Mn2+ was mainly solidified as Mn(OH)2, MnOOH and MnSiO3, and NH4+-N in EMMR was mostly removed in the form of ammonia. The results of this study could provide a new idea for cost-effective EMMR harmless treatment. 相似文献
6.
7.
研究了高硅铝硅合金(45wt% Si)熔体电磁分离过程中,Sb添加量、下拉速率、温度等对分离效果的影响,对Sb在高硅铝硅合金电磁分离过程中的变质机理进行了分析。结果表明,在1500℃、下拉速率为10 μm/s时,过共晶铝硅合金熔体中加入Sb进行定向凝固后,合金部分硅铝比从11.53%降至11.21%,初晶硅富集区的硅含量从86wt%增至90wt%;当1500℃、下拉速率为40 μm/s时,合金部分硅铝比从12.56%降至12.13%,初晶硅富集区的硅含量从81wt%增至86.5wt%;加入变质剂后合金部分共晶硅相在α-Al基体中分布均匀且连续,形貌有所细化。 相似文献
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10.
采用真空感应熔炼与铜模喷铸相结合,制备出不同成分的Cu_(100-x)Zr_x(x=5,30,50)合金。利用光学显微镜、扫描电镜、能谱分析及X射线衍射技术,对比研究了快冷合金的晶粒形貌、元素分布、相组成及类型等组织演化规律。结合差热分析技术研究了合金实时凝固过程。结果表明,随Zr含量增加,非平衡凝固Cu-Zr合金中初生相体积分数不断提高,分别呈现非小平面→小平面→非小平面的转变。由于铜模激冷效应,Cu_(70)Zr_(30)合金中Cu_(51)Zr_(14)+L→Cu_8Zr_3包晶转变与Cu_(50)Zr_(50)合金中CuZr→Cu_(10)Zr_7+CuZr_2共析转变均受到抑制。热分析曲线中未出现包晶相变峰和共析相变峰,合理解释了Cu-Zr合金非平衡组织的形成。 相似文献