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1.
《Ceramics International》2021,47(19):27487-27495
ZnO nanorod arrays (NRs) with a large number of sharp tips and uniform shapes were grown on the carbon cloth (CC) by a simple hydrothermal method. Titanium nitride (TiN) nanoparticles with various thicknesses were deposited on the ZnO NRs by magnetron sputtering to obtain ZnO/TiN core-shell arrays. Field emission (FE) performance of ZnO NRs show close dependence on TiN coating thickness. The turn-on field first decreases and then increases with increasing TiN coating thickness from 60 nm to 300 nm. The arrays with a design architecture can strike a balance between increased emission sites and limited field shielding effects. ZnO/TiN240 core-shell NRs have the lower turn-on electric field at 0.79 V/μm and the higher current densities at 9.39 mA/cm2. The field enhancement factor (β) of ZnO/TiN240 is about 3.2 times that of the bare ZnO NRs. On the other hand, the electrochemical properties were improved due to the formation of core-shell heterojunction on the ZnO/TiN interface and porous structure, which makes the ion and charge transport more convenient. Hence, this work not only revealed that the ZnO/TiN core-shell structure exhibited excellent improvement in both FE and supercapacitors applications, but also that growing arrays on CC was expected to achieve flexible display.  相似文献   
2.
李琛 《江苏建材》2021,(2):54-55
概述了水泥行业碳排放的主要来源,分析了目前水泥工业碳减排的主要渠道,指出错峰生产和产能减量置换政策已成为压减水泥过剩产能的两大政策抓手。  相似文献   
3.
The trivalent rare-earth (RE3+) doped phosphors show tremendous achievement in narrow band multicolor line emission for various applications. However, the 4f–4f absorption transition of these ions is forbidden in UV and blue light excitation. Usually, a sensitizer having spin allowed transition was used as a co-dopant to excite these ions via the energy transfer phenomenon. Another approach promisingly using to excite these ions by efficient energy transfer from the intrinsic emission of the Ca2LuTaO6 double perovskite phosphors host lattice. Phosphors of Ca2LuTaO6 with double perovskite structure were synthesized by using a high-temperature solid-state reaction method. The produced Ca2LuTaO6 double perovskite phosphors show an intrinsic broad band emission centered at 424 nm under the excitation of 313 nm UV light. The origin of this broad band blue emission was deeply investigated by using computation and experimental approaches. The trivalent activator Dy3+ and Eu3+ were doped is a single and co-dopant in the produced Ca2LuTaO6 phosphors to check their excitation in UV and near-UV spectral region. X-ray diffraction and scanning electron microscopy were used to investigate the structure and phase analysis. Various characterizations such as photoluminescence excitation, emission, and CIE chromaticity coordinates were measured which illustrate the potential of Dy3+ and Eu3+ activated Ca2LuTaO6 double perovskite phosphors for narrow band multicolor line emission for various applications.  相似文献   
4.
An acoustic emission (AE) experiment was carried out to explore the AE location accuracy influenced by temperature. A hollow hemispherical specimen was used to simulate common underground structures. In the process of heating with the flame, the pulse signal of constant frequency was stimulated as an AE source. Then AE signals received by each sensor were collected and used for comparing localization accuracy at different temperatures. Results show that location errors of AE keep the same phenomenon in the early and middle heating stages. In the later stage of heating, location errors of AE increase sharply due to the appearance of cracks. This provides some beneficial suggestions on decreasing location errors of structural cracks caused by temperature and improves the ability of underground structure disaster prevention and control.  相似文献   
5.
ABSTRACT

Preparation of poly(thiophene-alt-pyrrole bearing mesogen) was carried out with Migita–Kosugi–Stille coupling type polycondensation with an aid of Pd(0) complex catalyst. The resultant polymer shows lyotropic liquid crystallinity with good film-forming property. The smectic fan-shaped texture is maintained after completion of evaporation of solvent from the polymer solution. The cast film having liquid crystal (LC) order shows light emission function upon irradiation of excitation light at 460 nm. The polymer shows LC domain emission. Mechanical orientation allows to yield LC domain aligned film with band structure. Chiral mesogenic side chain induces π-conjugated main chain helicity from distance in molecular level.  相似文献   
6.
Yb3+/Er3+codoped La10W22O81 (LWO) nanophosphor rods have been successfully synthesized by a facile hydrothermal assisted solid state reaction method, and their upconversion photoluminescence properties were systematically studied. X-ray diffraction patterns revealed that the nanophosphors have an orthorhombic structure with space group Pbcn (60). A microflowers-like morphology with irregular hexagonal nanorods was observed using field emission scanning electron microscopy for the Yb3+(2 mol%)/Er3+(2 mol%):LWO nanophosphor. The shape and size of the nanophosphor and the elements along with their ionic states in the material were confirmed by TEM and XPS studies, respectively. A green upconversion emission was observed in the Er3+: LWO nanophosphors under 980 nm laser excitation. A significant improvement in upconversion emission has been observed in the Er3+: LWO nanophosphors by increasing the Er3+ ion concentration. A decrease in the upconversion emission occurred due to concentration quenching when the doping concentration of Er3+ ions was greater than 2 mol%. An optimized Er3+(2 mol%): LWO nanophosphor exhibited a strong near infrared emission at 1.53 μm by 980 nm excitation. The green upconversion emission of Er3+(2 mol%): LWO was remarkably enhanced by co-doping with Yb3+ ions under 980 nm excitation because of energy transfer from Yb3+ to Er3+. The naked eye observed this upconversion emission when co-doping with 2 mol% Yb3+. In order to obtain the high upconversion green emission, the optimized sensitizer concentration of Yb3+ ions was found to be 2 mol%. The upconversion emission trends were studied as a function of stimulating laser power for an optimized sample. Moreover, the NIR emission intensity has also been enhanced by co-doping with Yb3+ ions due to energy transfer from Yb3+ to Er3+. The energy transfer dynamics were systematically elucidated by energy level scheme. Colorimetric coordinates were determined for Er3+ and Yb3+/Er3+: LWO nanophosphors. The energy transfer mechanism was well explained and substantiated by several fluorescence dynamics of upconversion emission spectra and CIE coordinates. The results demonstrated that the co-doped Yb3+(2 mol%)/Er3+(2 mol%): LWO nanophosphor material is found to be a suitable candidate for the novel upconversion photonic devices.  相似文献   
7.
针对加工重质和劣质原油带来的焦化装置高硫焦出厂不合格问题,开发了劣质渣油高效转化工程解决方案,集成了多项催化裂化新技术,包括沉降器防结焦技术、原料油新型乳化雾化技术、10 MPa等级蒸汽发生技术、LCO和HCO组分分离及加工技术、吸收稳定综合节能技术和烟气净化组合技术等,可对炼油厂劣质渣油进行高效催化裂化,部分替代延迟焦化装置,解决低附加值高硫石油焦出路问题,并提高液体产品收率、降低装置和全厂能耗,环境友好,有助于国内催化裂化工艺突破原料加工瓶颈,提升炼油厂经济效益。  相似文献   
8.
To enhance the display quality of light-emitting diodes (LEDs), it is of great significance to exploit green/yellow-emitting phosphors with narrow emission band, high quantum yield, and excellent color purity to satisfy the application. Herein, orthophosphate-based green/yellow-emitting Na3Tb(PO4)2:Ce3+/Eu2+ (NTPO:Ce3+/Eu2+) phosphors have been successfully synthesized by a facile solid-state reaction method. The absorption band of NTPO samples was extended to the near-ultraviolet region and the absorption efficiency was significantly improved owing to a highly efficient energy transfer from Ce3+/Eu2+ ion to Tb3+ ion in NTPO host certified by time-resolved PL spectra. Upon 300 nm excitation, the NTPO:Ce3+ is characterized by ultra-narrow-band green emission of Tb3+ with an absolute quantum yield of 94.5%. Unexpectedly, NTPO:Eu2+ emits bright yellow light with a color purity of 73% as a result of the blending of green light emission from Tb3+ and red light emission from Eu3+. The thermal stability has been improved by controlling the stoichiometric ratio of Na+. The prototype white LED used yellow-emitting NTPO:Eu2+ phosphor has higher color-rendering index (Ra = 83.5), lower correlated color temperature (CCT = 5206 K), and closer CIE color coordinates (0.338, 0.3187) to the standard white point at (0.333, 0.333) than that used green-emitting NTPO:Ce3+ phosphor, indicating the addition of the yellow light component improved the Ra of the trichromatic (RGB) materials.  相似文献   
9.
为了确定反硝化聚糖菌(DGAOs)的脱氮性能及N2O释放特性,采用序批式生物反应器,分别以乙酸钠和葡萄糖为碳源(反应器分别记作SBRAc和SBRGl),考察其脱氮过程中的碳源变化以及N2O释放特性。结果表明,SBRAc和SBRGl的总氮去除率分别为(80.2±2.8)%和(63.4±3.5)%,N2O产率分别为(7.16±1.43)%和(13.35±2.46)%。以乙酸钠为碳源时,聚糖菌厌氧阶段吸收的有机物主要以胞内聚-β-羟基烷酸(PHA)形式储存;以葡萄糖为碳源时,部分有机物用于胞内糖原(Gly)的积累,PHA合成量减少。聚糖菌内源反硝化过程中,依次利用胞内PHA和Gly作为内碳源,且PHA提供电子的速率远大于Gly,导致SBRGl内NO2-大量积累、N2O释放量增加。NO2-对氧化亚氮还原酶活性的抑制效应是导致聚糖菌内源反硝化过程释放N2O的主要因素。与葡萄糖相比,乙酸钠更易被反硝化聚糖菌吸收为易利用的内碳源PHA,并降低反硝化过程中N2O的释放量。  相似文献   
10.
与推行超低排放前的2013年相比,2019年中国火电装机容量、发电量分别增长36.7%和19.5%,但烟尘、SO2、NOx排放量却分别下降87.3%、88.6%、88.8%。同期,全国火力发电行业厂用电率维持在6.01%,供电煤耗从321 g/(kW·h)下降到306.4 g/(kW·h),相当于2019年减排CO2约27015万t,是国内目前最大的15万t/年碳捕集工程的1 801倍。为总结中国燃煤电厂超低排放和节能改造取得的重大成就,指导其他行业的污染治理及碳达峰与碳中和目标的高效经济的实现,系统研究最严排放标准、企业需求、国家重视、技术创新、经济激励政策等对燃煤电厂超低排放和节能改造成功实践的重要作用。结果表明,燃煤电厂超低排放工程、碳捕集工程等烟气治理工程不仅投资高,而且运行费用可观。烟气治理工程的顶层设计与持续推进是关键,技术突破和规范应用是保障,环保电价与激励政策是重点。就超低排放而言,超低电价等经济激励政策不能因为超低排放全面完成而取消,而应进一步优化,激励超低排放工程的高效运行。其他工业行业在推行超低排放过程中,应借鉴电力行业的成功经验,制定可行技术路线、工程技术规范、运行管理技术规范等国家环保标准,同时出台相关的经济激励政策,以确保超低排放工程建设好、运行好,真正实现减排效果。节能改造工程完成后,其运行不仅具有一定的经济效益,而且减排CO2的能力较大,在碳达峰与碳中和的约束条件下,燃煤电厂应优先实施节能改造工程。在碳捕集工程能耗、成本、风险不能大幅下降的前提下,碳捕集工程不宜盲目推广。  相似文献   
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