海底管道测温探头的研制

温度对于金属在不同环境下的腐蚀都有着直接或者间接的影响,对于海底管道而言,不仅管道内的流体性质影响腐蚀,流体的温度更是一个不容忽视的因素。本文采用TMP35作为温度敏感元件,研制开发了海底管道测温探头。利用该测温探头采集的数据,绘制了温度与电位关系变化曲线,并依据温度与电位关系变化曲线:E=9.0159 T-87.139或者T=0.1109 E+9.665,编译了测温应用软件。目前该管道测温探头已在海底管道腐蚀检测中得到了应用。     

撬块制造中仪表专业施工管理

基于石油化工产业中的撬块制造过程,介绍了仪表专业在撬块制造中的施工管理工作,目的是用来提高自控仪表专业工程施工的技术和管理水平,保质保量的完成撬块制造中仪表专业的施工任务和进度。     

Dramatic influence of carbamate-linked double chain organosilane with different length on zeolite morphology control

A series of rationally designed carbamate-linked organosilanes with double alkyl chain lengths from C₈ to C₁₄ were synthesized as novel template agents to prepare hierarchically porous zeolites. The variable chain lengths had strong affects on zeolite morphology control process in the given synthesis condition as indicated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and nitrogen adsorption–desorption analyses. The addition of the organosilanes with C₈, C₁₀ and C₁₄ lengths (5 mol % of the total silica source) into the synthesis compositions gave zeolites with isolated crystals. While the organosilane with C₁₂ length caused dramatic change in the product morphology and gave mesoporous ZSM-5 crystals with a chain-like morphology. XRD patterns, nitrogen sorption isotherm and SEM images of the samples taken during crystallization clearly showed the change of crystallinity, texture properties and forming process of this morphology.     

Synthesis,characterization and desulfurization performance of MCM-41 functionalized with Cu by direct synthesis and organosilanes by grafting

Cu-incorporated MCM-41 was prepared by the direct synthesis method. The Cu-incorporated MCM-41 was then organically functionalized by grafting of organosilanes followed by the complexation of copper ions. The results of powder X-ray diffraction, Fourier transform infrared, and temperature-programmed reduction suggest the incorporation of Cu into the framework of MCM-41 during the direct synthesis process. The mesostructure of prepared samples is preserved after functionalization. The sulfur capacities for tert-butyl mercaptan, dimethyl sulfide, and dimethyl disulfide decrease in the same order (40)Cu–M > (40)Cu–M–N–Cu. The (40)Cu–M synthesized through the direct synthesis method also shows better desulfurization performance than M–Cu prepared by the incipient wetness impregnation method. This is attributed to the incorporated Cu species in the framework and well-dispersed CuO species of (40)Cu–M.     

The influence of the acidic scouring treatment on the wastewater treatment of TiO<Subscript>2</Subscript> loaded activated carbon electrode

Activated carbon (AC) electrodes were loaded with TiO₂ by using sol–gel method after a pretreatment process, the effect of the acidic pretreatment of the TiO₂ loaded electrode on its deionization efficiency of the wastewater containing NaCl solutions was studied; the physical, chemical and electrochemical properties of the electrode were characterized. The physical and chemical properties of the activated carbon before and after loaded with TiO₂ nanoparticles are characterized by using scanning electron microscopy, energy dispersion spectrum analyzer, Brunauer–Emmett–Teller gas adsorption method, thermal gravimetric analysis, Fourier transform infrared spectroscopy respectively. Electrochemical properties were characterized by employing electrochemical workstation and electrical adsorption deionization test. It was found that both the specific capacitance and the ions removal efficiency of the activated carbon loaded with TiO₂ had an increase of 16.4 and 49.8 % respectively in comparison with original activated carbon electrode. It was believed that this is due to the presence of crystal anatase TiO₂ nanoparticles (the mass content of titanium element in the TiO₂/AC complex is about 24.91 %) on the surface and pores in the activated carbon; while Ti–O–C bonds was found on the surface of the activated carbon, its surface wetting properties was significantly improved. However, it was also noticed that and the specific surface area of the activated carbon was decreased from 680.5 to 523.35 m² g^?1. This might lead to the decrease of the physical adsorption properties of the activated carbon electrodes, but its Electrical double-layer capacitance increases, electrical adsorption efficiency was improved.     

A Comparative Study on the Biosorption of Cd2+ onto Paecilomyces lilacinus XLA and Mucoromycote sp. XLC

The filamentous fungi XLA and XLC isolated from Cd-contaminated soil were identified morphologically and phylogenetically as Paecilomyces lilacinus and Mucoromycote sp., respectively. The minimum inhibitory concentrations (MICs) of Cd²⁺, Co²⁺, Cu²⁺, Zn²⁺, Cr³⁺ and Cr⁶⁺ in minimum mineral (MM) medium agar plates were 29,786, 2945, 9425, 5080, 1785 and 204 mg·L⁻¹ for XLA and 11,240, 884, 9100, 2540, 3060 and 51 mg·L⁻¹ for XLC, respectively. Favorable biosorption conditions for adsorption of Cd²⁺ by the tested fungi were investigated. Efficient performances of the biosorbents were described using Langmuir isotherm model, and the predicted maximum biosorption capacities for Cd²⁺ were 77.61 mg·g⁻¹ of XLA and 79.67 mg·g⁻¹of XLC. Experiments on desorption potential of biosorbents validated their efficacy at a large scale. Results showed that XLA obtained a desorption rate of 84.7% by 2% EDTA and XLC gained a desorption rate of 78.9% by 0.1 M HCl. Analysis by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM/EDS) and X-ray photoelectron spectroscopy (XPS) suggested that groups of C–N, COO– for XLA and C–N, CH₂ and phosphate for XLC were the dominant binding sites for Cd²⁺ biosorption. Our results indicated that the fungus XLA, rather than XLC, could potentially be used as an inexpensive, eco-friendly and effective bioremediation agent for the removal of Cd²⁺ from wastewater.