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排序方式: 共有10000条查询结果,搜索用时 234 毫秒
1.
《Ceramics International》2022,48(6):8069-8080
Homogeneous thin films of Molybdenum oxide (MoO3) were grown on quartz and glass substrates using the thermal evaporation method. XRD results showed that the MoO3 powder has a polycrystalline structure with an orthorhombic crystal system whereas the MoO3 thin films have amorphous nature. SEM images showed that the MoO3 thin films have a nearly uniform surfaces with worm-like shape grains. The film thickness influences on the linear and nonlinear optical characteristics of MoO3 thin films that were examined using spectrophotometric measurements and from which, the linear optical constants of the MoO3 thin films were estimated. The electronic transition type was determined as a direct allowed one. The values of the optical band gap were obtained to be in the range of 3.88–3.72 eV. The dispersion parameters, third-order nonlinear optical susceptibility, and the nonlinear refractive index of the MoO3 thin films were determined and interpreted in the light of the single oscillator model. The temperature dependence of the DC electrical conductivity and the corresponding conduction mechanism for the MoO3 films were investigated at temperatures ranging from 303 to 463 K. 相似文献
2.
3.
《International Journal of Hydrogen Energy》2022,47(57):23909-23918
The hydrogel electrolyte is an important part of safety and development potential in zinc-based energy storage equipment due to its inherent low mechanical strength and voltage decomposition. However, hydrogel electrolytes possess a reduced working life for zinc dendrites growth and a narrow voltage window. In this study, a hydrogel electrolyte prepares by the zwitterionic monomer [2-(methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl) (MS) and sodium alginate (SA) alleviate these problems. The zwitterionic double-network hydrogel has good mechanical strength, inhibits the growth of zinc dendrites, enhances practicability, greatly increases the voltage window (0–2.4 V), and has self-healing properties to its rich functional groups. The assembled zinc-ion hybrid supercapacitors (ZHSs) have a high-power density of 172.33 W kg?1 and an energy density of 88.56 Wh·kg?1 at 0.5 A g?1. The assembled zinc-ion battery also has good electrochemical performance. Flexible ZHSs and batteries provide power to the timer stably under different bending angles. The zwitterionic double-network hydrogel can be applied to both zinc-based supercapacitors and batteries. 相似文献
4.
针对传统冷却系统与柴油机冷却需求不匹配的问题,进行了冷却系统电控化设计仿真研究。基于Simulink软件设计了电控冷却系统仿真模型,提出了电控冷却控制策略,并开展了变柴油机工况条件下电控冷却控制策略验证仿真。对传统冷却部件进行电控化改造(电控海水泵、电控淡水泵和电子节温器),搭建电控冷却系统试验台架,通过试验分析了电控冷却对柴油机耗油率和热平衡的影响,结果表明:相对于传统冷却系统,电控冷却系统在900 r/min、负荷率30%,1 200 r/min、负荷率60%,1 500 r/min、负荷率90%这3个工况点的耗油率分别降低9.4 g/(kW·h)、6.8 g/(kW·h)和3.9 g/(kW·h),燃油经济性和热量分配得到改善。 相似文献
5.
《Ceramics International》2022,48(8):10704-10712
A combination of high wear-resistance and low-friction is crucial for improving the wear performance of self-lubricating coatings, which is generally determined by an excellent lubricating effect and mechanical strength. In this study, the Mo–V–Cu–N coatings were prepared by HIPIMS technique with a spliced target of Mo–V–Cu at various charge voltages. The results revealed that Mo–V–Cu–N coatings presented a solid solution phase of B1–MoVN with (200) preferred orientation, and the preferred orientation was enhanced at high charge voltages. Whereas the Cu atoms formed an amorphous phase in Mo–V–Cu–N coatings due to a low Cu content of 2.3–3.6 at.%. As the charge voltage increased to 750 V, more charged metallic ions were accelerated and bombarded substrate surface efficiently, forming smooth and dense Mo–V–Cu–N coatings with a high hardness of 31.0 GPa. All the coatings presented a low friction coefficient of 0.34–0.39 due to the formation of MoO2, VO2 and CuO mixed oxides, and the wear mechanism was dominated by abrasive and tribo-oxidation wear at room temperature. 相似文献
6.
J. Thomas BRENNA 《粮油食品科技》2022,30(3):7-15
人体大脑和身体的发育,需要从食物中摄取均衡的营养物质。人类大脑是区分人类和其他动物的特征。食物中的必需脂肪酸是机体组织结构和功能的必要组成部分。Omega-6(O6)亚油酸(LA6)是皮肤组织的组成成分,且是炎症、血栓形成、免疫和其他信号分子的前体;Omega-3(O3)α-亚麻酸(ALA3),特别是其长链代谢产物——二十二碳六烯酸(DHA3),是大脑、视网膜和部分神经组织中的关键组分。从富含LA6脂肪酸(缺乏O3脂肪酸)的植物籽中提取出的廉价而优质油脂,是20世纪的西方国家食品工业生产的主要脂肪来源。在代谢通路中,高浓度的LA6脂肪酸可拮抗O3脂肪酸代谢,造成O3脂肪酸不足,因此,在给怀孕动物的饲料中,只提供富含LA6但缺乏O3脂肪酸的油脂作为唯一的脂肪来源,会导致幼崽大脑发育不良。过去20~30年的研究表明,低含量LA6且含DHA3的油脂可改善大脑的功能。近年来的研究较多集中在营养因素对大脑发育的影响,最新研究数据表明,脂肪酸平衡对营养不良儿童的大脑发育尤为重要。世界卫生组织(WHO)越来越重视大脑的营养健康,通过其下属的食品法典委员会,建议用于治疗严重急性营养不良儿童的即食治疗食品中,使用含有均衡脂肪酸组成/构成的脂肪。同样,脂肪酸均衡对老年人可能也很重要。目前,业界已经有了调整油脂成分的方法,以确保脂肪酸均衡,从而维持人体整个生命周期的大脑健康。 相似文献
7.
Form selection of concomitant polymorphs: A case study informed by crystallization kinetics modeling
Weiwei Tang Yufeng Quan Junbo Gong Jingkang Wang Qiuxiang Yin Tonglei Li 《American Institute of Chemical Engineers》2021,67(4):e17129
Molecular mechanisms and process kinetics of crystallizing concomitant polymorphs remain poorly understood. Solvent-mediated phase transformation and concomitant crystallization are difficult to be distinguished in practice, as multiple forms can be detected at the same time. Herein, we developed a population balance model to simulate a concomitant crystallization process of two polymorphs of tolfenamic acid. Our kinetic modeling aims to understand concomitant crystallization and help guide form selection of such a molecular system. Crystallization kinetics of ethanolic solutions were uncovered from induction time measurements, as well as seeded and unseeded crystallization experiments. Experimental and simulation results demonstrate that the stable form I crystallizes concomitantly with the metastable form II. The faster growing form II results in an intermediate decline in the composition of form I in crystallized samples, a characteristic feature of the concomitantly crystallized system. A four-quadrant scheme of attainable polymorph outcome was simulated under various crystallization conditions. 相似文献
8.
花生粕是重要的蛋白饲料原料,但由于其氨基酸不平衡,特别是精氨酸与赖氨酸比例严重失衡(精氨酸与赖氨酸含量比值在3~4,理想的精氨酸与赖氨酸含量比值为1.0),限制了其在动物养殖中的应用。研究了复合酶预处理结合乳酸菌发酵花生粕对其品质的改善。结果表明:经菌酶协同处理后,花生粕粗蛋白质含量由46.4%提高至506%,大分子蛋白明显降解为小分子蛋白,酸溶蛋白质含量由2.3%提高至17.8%,多肽含量由1.6%提高至15.7%,蛋氨酸和赖氨酸含量分别提高了77.1%和42.0%,精氨酸降解率为18.7%,精氨酸与赖氨酸含量比值从3.7降低至2.1,总酸含量由06%提高到4.7%,其中乳酸含量由0.64 mg/g提高至14.63 mg/g。菌酶协同处理后的花生粕抗氧化性明显增强,其中每克菌酶协同处理后的花生粕对羟自由基的清除能力与171.6 mg VC相当,比花生粕(与47.6 mg VC相当)提高了2.6倍。 相似文献
9.
Dr. Remya Rajan Dr. Dirk Schepmann Ruben Steigerwald Dr. Julian A. Schreiber Dr. Ehab El-Awaad Prof. Joachim Jose Prof. Guiscard Seebohm Prof. Bernhard Wünsch 《ChemMedChem》2021,16(20):3201-3209
Recent studies have shown the involvement of GluN2A subunit-containing NMDA receptors in various neurological and pathological disorders. In the X-ray crystal structure, TCN-201 ( 1 ) and analogous pyrazine derivatives 2 and 3 adopt a U-shape (hairpin) conformation within the binding site formed by the ligand binding domains of the GluN1 and GluN2A subunits. In order to mimic the resulting π/π-interactions of two aromatic rings in the binding site, a [2.2]paracyclophane system was designed to lock these aromatic rings in a parallel orientation. Acylation of [2.2]paracyclophane ( 5 ) with oxalyl chloride and chloroacetyl chloride and subsequent transformations led to the oxalamide 7 , triazole 10 and benzamides 12 . The GluN2A inhibitory activities of the paracyclophane derivatives were tested with two-electrode voltage clamp electrophysiology using Xenopus laevis oocytes expressing selectively functional NMDA receptors with GluN2A subunit. The o-iodobenzamide 12 b with the highest similarity to TCN-201 showed the highest GuN2A inhibitory activity of this series of compounds. At a concentration of 10 μM, 12 b reached 36 % of the inhibitory activity of TCN-201 ( 1 ). This result indicates that the [2.2]paracyclophane system is well accepted by the TCN-201 binding site. 相似文献
10.
《Ceramics International》2022,48(22):33115-33121
As a critical topological phase transition material, SrFeOx could play an essential role in the field of resistive memory. How to implement resistance-switching more softly and ensure the stability of materials has always been a relevant research hotspot. Regulating the oxygen environment during the deposition process of the films can effectively control the stoichiometry of the functional layer and then improve the resistance-switching characteristics of the device. In this paper, a SrFeOx hetero-film was prepared by oxygen pretreatment on the SrRuO3 surface before SrFeOx deposition, and the as-assembled micrometer-scale device exhibits a low set operating voltage of 0.6 V and favorable cycling characteristics. The SrFeOx hetero-film reveals a vertical brownmillerite superlattice-like structure with ~20 nm perovskite buffer layer, which benefits the connection and rupture of conductive filament. Additionally, XPS and UV–vis were used to analyze the bonding energy and band gap of SrFeOx hetero-film, and offers the experimental basis for the explanation of the conductive mechanism. Therefore, the device based on SrFeOx hetero-film with low operation voltage provides a reference for low power consumption research on topological phase transition material. 相似文献