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1.
海上风电作为可再生清洁能源之一,受到世界各国的高度重视与大力发展。我国将海上风电提升至解决能源危机、减缓气候变化、调整能源结构的国家战略高度,到2030年我国单位国内生产总值二氧化碳排放将比2005年下降65%以上,非化石能源占一次能源消费比重将达到25%左右。安装平台不足将是我国海上风电场无法如期建成投产的主要障碍。对自升自航式海上风电安装平台系列高端装备及其设计制造的三大技术难题——腿站立作业易“失稳”、大平台大跨距大倾覆力矩自升易“失控”、高空吊装巨型叶片逾百螺栓精准定位易“失准”,以及焊缝缺陷修复和局部裂纹损伤的激光锻造修复再制造进行了介绍,研制的具有不同规格的系列装备在中国、英国、丹麦、德国等国家的著名海上风电场建设应用情况良好。 相似文献
2.
Haiyue Xu Ji Zou Weimin Wang Hao Wang Wei Ji Zhengyi Fu 《Journal of the European Ceramic Society》2021,41(1):635-645
Fully dense ceramics with retarded grain growth can be attained effectively at relatively low temperatures using a high-pressure sintering method. However, there is a paucity of in-depth research on the densification mechanism, grain growth process, grain boundary characterization, and residual stress. Using a strong, reliable die made from a carbon-fiber-reinforced carbon (Cf/C) composite for spark plasma sintering, two kinds of commercially pure α-Al2O3 powders, with average particle sizes of 220 nm and 3 μm, were sintered at relatively low temperatures and under high pressures of up to 200 MPa. The sintering densification temperature and the starting threshold temperature of grain growth (Tsg) were determined by the applied pressure and the surface energy relative to grain size, as they were both observed to increase with grain size and to decrease with applied pressure. Densification with limited grain coarsening occurred under an applied pressure of 200 MPa at 1050 °C for the 220 nm Al2O3 powder and 1400 °C for the 3 μm Al2O3 powder. The grain boundary energy, residual stress, and dislocation density of the ceramics sintered under high pressure and low temperature were higher than those of the samples sintered without additional pressure. Plastic deformation occurring at the contact area of the adjacent particles was proved to be the dominant mechanism for sintering under high pressure, and a mathematical model based on the plasticity mechanics and close packing of equal spheres was established. Based on the mathematical model, the predicted relative density of an Al2O3 compact can reach ~80 % via the plastic deformation mechanism, which fits well with experimental observations. The densification kinetics were investigated from the sintering parameters, i.e., the holding temperature, dwell time, and applied pressure. Diffusion, grain boundary sliding, and dislocation motion were assistant mechanisms in the final stage of sintering, as indicated by the stress exponent and the microstructural evolution. During the sintering of the 220 nm alumina at 1125 °C and 100 MPa, the deformation tends to increase defects and vacancies generation, both of which accelerate lattice diffusion and thus enhance grain growth. 相似文献
3.
本文采用超星学习通线上教学平台,以 “高电压技术”课程为对象,实施了规模为120余人的线上线下混合式教学。基于线上教学和传统教学的优势互补,设计了“高电压技术”多个教学环节。归纳分析了混合式教学在各个教学环节取得的效果和问题,并根据学生反馈提出了持续性的改进措施。 相似文献
4.
《Journal of the European Ceramic Society》2021,41(13):6290-6301
In this study, monolithic B4C and B4C-based ceramics incorporating FeNiCoCrMo dual-phase (FCC and BCC) high entropy alloys (HEAs) were produced by spark plasma sintering (SPS). The effect of additives on the densification behavior, mechanical properties, microstructures, and phase evaluation of the samples were investigated. X-ray analysis confirmed the existence of FCC structured HEA and depletion of BCC structured HEA, after high-temperature reaction between B4C-HEAs. The addition of HEAs enhanced the densification behavior by liquid phase sintering. Furthermore, hardness and fracture toughness values of the samples increased with increasing HEAs content. Fracture toughness and hardness values for all composites were higher than the monolithic B4C. A combination of the highest density (∼99.22 %) and the best mechanical properties (32.3 GPa hardness and 4.53 MPa m1/2 fracture toughness) was achieved with 2.00 vol.% HEA addition. 相似文献
5.
《Ceramics International》2022,48(9):12800-12805
Perovskite solid solution materials, namely, 0.67BiFeO3-0.33BaTiO3, were synthesized by spark plasma sintering method. The effects of the spark plasma sintering temperature on phase purity, microstructure, and electric properties of the as-prepared materials were investigated. The materials could be referred as pseudocubic phases based on the X-ray diffraction patterns. The bulk density first increased and then decreased. The 880 °C-sintered-ceramics had the maximal density and a compact microstructure with grain size of 0.77 ± 0.34 μm. The dielectric constant as a function of temperature exhibited a broad peak. At the optimal spark-plasma-sintering temperature, enhanced ferroelectric properties were observed with a value of Pr ~ 21 μC/cm2. This investigation on the spark plasma sintering process confirms it as an efficient approach to prepare outstanding performance BiFeO3–BaTiO3 ceramics. 相似文献
6.
《Ceramics International》2022,48(20):30376-30383
In this study, α/β-Si3N4 composite ceramics with high hardness and toughness were fabricated by adopting two different novel ternary additives, ZrN–AlN–Al2O3/Y2O3, and spark plasma sintering at 1550 °C under 40 MPa. The phase composition, microstructure, grain distribution, crack propagation process and mechanical properties of sintered bulk were investigated. Results demonstrated that the sintered α/β-Si3N4 composite ceramics with ZrN–AlN–Al2O3 contained the most α phase, which resulted in a maximum Vickers hardness of 18.41 ± 0.31 GPa. In the α/β-Si3N4 composite ceramics with ZrN–AlN–Y2O3 additives, Zr3AlN MAX-phase and ZrO phase were found and their formation mechanisms were explained. The fracture appearance presented coarser elongated β-Si3N4 grains and denser microstructure when 20 wt% TiC particles were mixed into Si3N4 matrix, meanwhile, exhibited maximum mean grain diameter of 0.98 ± 0.24 μm. As a result, the compact α/β-Si3N4 composite ceramics containing ZrN–AlN–Y2O3 additives and TiC particles displayed the optimal bending strength and fracture toughness of 822.63 ± 28.75 MPa and 8.53 ± 0.21 MPa?m1/2, respectively. Moreover, the synergistic toughening of rod-like β-Si3N4 grains and TiC reinforced particles revealed the beneficial effect on the enhanced fracture toughness of Si3N4 ceramic matrix. 相似文献
7.
《Journal of the European Ceramic Society》2022,42(13):6056-6066
We analysed with different methods the densification of UO2 nanopowders in SPS under constant heating rate (CHR) and isothermal sintering conditions. The apparent activation energy of densification in SPS (75 kJ/mol with CHR method) is significantly smaller than in conventional sintering. It is shown that this is likely not an effect of the applied current. We also observed a threshold stress at 64 MPa for the transition from pressure-insensitive sintering (stress exponent n≈0) to pressure-assisted sintering, suggesting that the contribution of the capillary stresses in such nanopowders is comparable with the typical stress applied in SPS. 相似文献
8.
基于电信运营商数字化转型,系统性地提出了数据驱动的云网发展规划体系,以及六大关键数字化能力构建,设计和实现了一种云网规划数字化平台,该平台可用于实现目标网络精细规划、边缘计算精准预测等场景,并探讨了数字孪生在规划领域的应用前景,对运营商推进云网融合战略、推进高质量发展具有指导和参考意义。 相似文献
9.
在“移动互联网+课堂”的大势趋动下,针对现在“数字电子技术实验”教学存在的教学模式落后,教学手段单一,教学内容简单、以及考核不够全面等问题,借助超星泛雅 “一平三端”平台进行“线上-线下混合教学”改革。通过课前发布任务、课中有效组织课堂活动、课后发布作业、统计数据和教学反思进行。实践表明:该方法提高了学生的自主学习能力,并且增强了教师对学生学习情况的动态跟踪和过程性指导,同时也让课堂教学更有效,教学评价方式更有针对性、更精准,最终达到知识、技能和情感态度价值观的培养。 相似文献
10.
《Ceramics International》2022,48(11):15640-15646
Ferroelectric ceramic with a large electrocaloric (EC) effect at a very low electric field is very attractive in the next solid state refrigeration technology. In this work, two Pb(Sc0.25In0.25Nb0.25Ta0.25)O3 (PSINT) medium-entropy ceramics were successfully synthesized by a spark plasma sintering (SPS) technology, including one-step-SPS processed and two-step-SPS processed samples. A large EC effect (△T ~ 0.85 K) with a high EC strength (△T/△E ~ 0.021 K cm/kV) around room temperature are obtained at a very low electric field (~40 kV/cm) in the two-step-SPS processed sample. Moreover, the working temperature range is very broad (~120 K), which can be responsible for the high relaxation degree of the dielectric peak. It can be believed that the PSINT medium-entropy ceramics can be promising candidates for application in the next-generation EC cooling devices. 相似文献