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1.
Phase separation during polymerization was studied in a model system consisting of a diepoxide based on diglycidyl ether of bisphenol A (DGEBA), variable amounts of ethylenediamine (EDA) and the mass of castor oil (CO) necessary to obtain a mass fraction equal to 0-15 in a final system where the stoichiometric ratio of amine to epoxy equivalents, r, was equal to 1. A two-step polymerization process was performed by curing first a system with r = 0-5, during variable times before phase separation, and then carrying the system to r = 1. Thermodynamic analysis of samples with different r values led to a linear relationship between the Flory-Huggins interaction parameter and r. The concentration (P) and average size (D?) of dispersed-phase particles followed opposite trends, i.e. P increased while D? decreased, when either r was increased or the time of curing in the first step of a two-step process was decreased. This was explained by assuming that the competition between nucleation and growth was determined by the viscosity at the cloud point, ηcp. Low values of ηcp favoured growth over nucleation and led to fewer but larger particles. 相似文献
2.
The paper describes the integration of a chemical and a vapour-compression heat pump for energy storage applications. The vapour-compression system is designed to operate using the UK cheap rate ‘Economy 7’ electricity tariff. The system is characterized thermodynamically using various refrigerant/absorbent pairs in the chemical storage circuit and an ozone-friendly refrigerant, R134a, in the vapour-compression circuit. Results indicate that the H2O/Na2S pair provides a high energy storage density and is the most suitable for use in this system. The paper also describes the design features of a domestic-sized version of this heat pump system. Air in the sunspace (conservatory) of a house was used as a heat source for the heat pump. 相似文献
3.
本文介绍了用αβ谱仪系统同时测量αβ谱、实现Rn/Th子体补偿、确定超铀α核素气溶胶体积活度及人工放射性气溶胶总β体积活度的技术途径。利用RaA、RaC′a峰的二段时间计数可确定空气中RaA、RaB、RaC的气溶胶体积活度,相应的,也能给出RaB、RaC对总β计数的贡献。根据一般环境条件下的平衡比,用ThC′的。计数修正Th子体对αβ测量的影响。 ̄[239]pu或/和 ̄[241]Am人工核素的α计数,可通过两段时间分别扣除RaA、RaC′拖尾的方法确定;β计数分别扣除Rn/Th子体β贡献即可确定。在本文规定的测量条件下,对室内天然Rn子体水平在15Bq/m ̄3以下,超铀α核素气溶胶体积活度的测量下限可达到0.1Bq/m ̄3;即使在75Bq/m ̄3环境下,人工核素总β的测量下限也可达lBq/m ̄3以下。 相似文献
4.
A stochastic differential equation involving both a Wiener process and fractional Brownian motion, with nonhomogeneous coefficients and random initial condition, is considered. The coefficients and initial condition depend on a parameter. The assumptions on the coefficients and the initial condition supplying continuous dependence of the solution on a parameter, with respect to the Besov space norm, are established. 相似文献
5.
In this paper, we investigate an inexact hybrid projection-proximal method for solving a class of generalized mixed variational inequalities in Hilbert spaces. We construct a general inexact hybrid projection-proximal point algorithm, in which an inexact relaxed proximal point step is followed by a suitable orthogonal projection onto a hyperplane. Under some suitable conditions concerned with the pseudomonotone set-valued mapping T, the nonsmooth convex function f and the step size λk, we prove the convergence of the inexact hybrid projection-proximal point algorithm for solving generalized mixed variational inequalities in Hilbert spaces. 相似文献
6.
Nguyen Quoc Dinh Author VitaeDong-Sung KimAuthor Vitae 《Computer Standards & Interfaces》2012,34(1):117-123
The International Society of Automation recently released ISA100.11a as an open standard for reliable wireless networks for industrial automation. ISA100.11a uses the TDMA scheme in the medium access layer to provide deterministic services. However, ISA100.11a adopts the CSMA-CA mechanism with priorities for retransmission from failure on dedicated links, sporadic data, and network configuration.This paper evaluates ISA100.11a CSMA-CA by simulation, considering the effects of backoff procedures and priority settings to probability of collision and successful use of slots. It's demonstrated that a high number of priority classes enable better network utilization resulting in less number of packets exceeding their lifetime. 相似文献
7.
对云南高校大学生体育兴趣程度及差异现状的调查结果表明:云南大学生体育兴趣总体兴趣程度较好,男女生体育兴趣程度差异明显,少数民族学生与汉族学生、城市生源学生与农村生源学生、独生子女学生与非独生子女学生体育兴趣程度有一定差异,但差异不明显。通过分析和研究大学生体育兴趣及差异的主要表现,提出加强大学生体育兴趣培养的建议。 相似文献
8.
Deyang Qu 《Electrochimica acta》2003,48(12):1675-1684
The proton diffusion coefficient in γ-MnO2 at various stages of discharge of an electrolytic manganese dioxide electrode has been determined taking into consideration the true molar volume and the electrochemically accessible surface area of MnO2. The unique electrochemical cell which allows the electrode expansion during the discharge to be monitored in situ was reported. The a.c. impedance technique and the transmission line equivalent circuit were used. Electrode ohmic resistance, Faradaic resistance, and double-layer capacitance were also obtained by means of numerical fitting of the impedance data using the transmission line model. 相似文献
9.
激光三角法位移传感器测头设计 总被引:1,自引:0,他引:1
LU Mai ji Zhijiang Zhang Jinfu Fan HongHebei Institute of Architecture CIVIL Engneering 《河北建筑工程学院学报》1997,(4)
本文以直射式激光三角测头为例,导出了满足Scheimpfiag成象条件下的待测面位移与象位移间的准确关系,作为仪器结构参数设计的基础,并对提高测量精度和实用性的各项改进设计进行了分析。 相似文献
10.
高校图书馆的任务是为教学科研服务,不仅包括一般图书和现刊的流通服务,而且包括过刊的再利用。我校过刊资源较丰富,但利用率很低。原因是多方面的,就图书馆本身而言,过刊管理,也未跟上。应通过优化馆藏,加强管理,进一步拓宽和完善服务内容等途径,来提高过刊的利用率,实现其价值。 相似文献