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《Ceramics International》2022,48(6):7533-7549
(1-x)SrFe10Al2O19/(x)Co0.6Zn0.4Fe2O4-(SFAO/CZFO) hard/soft nanocomposite ferrite materials were synthesized by ‘one-pot’ self-propagating combustion route. The co-existence of the two magnetic phases were confirmed by XRD, FESEM, EDS and VSM. The prepared nanocomposite samples were also characterized by TGA/DSC, Raman spectroscopy and VNA. Exchange coupling between the hard and the soft magnetic grains was observed by determining the switching field distribution (SFD) curve. As a result of the competing effects of exchange interaction and dipolar interaction, magnetic parameters were observed to be sensitive to the incorporation of soft magnetic phase into the nanocomposite. Results showed that with the inclusion of soft magnetic phase, exchange coupling behaviour between the hard and the soft ferrite phases had significant influence on the microwave absorption capacity of the samples. Related electromagnetic parameters and impedance matching ratio of the nanocomposite system were discussed. A minimum reflection loss of ?42.9 dB with an absorber thickness of 2.5 mm was attained by the nanocomposite (90 wt%)SrFe10Al2O19/(10 wt %)Co0.6Zn0.4Fe2O4 at a matching frequency of 11.45 GHz. This assured the candidacy of SrFe10Al2O19/Co0.6Zn0.4Fe2O4 nanocomposite as a promising microwave absorption material in the X-band (8–12 GHz). 相似文献
3.
基于CFD?DEM耦合方法,研究了颗粒在水室内的流动状态,分析了不同刀盘转速、粒子水通入量和水室出口角度对造粒过程的影响,发现提高刀盘转速、增加粒子水通入量和水室出口倾斜一定的角度都有利于水室内颗粒的排出。进一步研究了颗粒与碎屑在水室内的流动,发现在水室出口处二者的流动基本呈现出一定的分离角度。 相似文献
4.
《International Journal of Hydrogen Energy》2022,47(32):14580-14588
Recovery of hydrogen (H2) from H2-containing gas mixtures has great significance for energy conservation, cost reduction and benefit increase. However, the common separation methods have the ubiquitous problem due to phase equilibrium principle and results in the conflict between H2 concentration and H2 recovery rate in the product gas. Consequently, an innovative conception of hydrate-membrane coupling approach is proposed in this work. In the separation process, hydration and membrane permeation two separation driving forces coexist to achieve the aim of strengthening mass transfer kinetics. H2 and non-H2 components (hydrocarbons) are synchronously and directionally selected by membrane and hydrate to improve different phase compositions. Therefore, the gas in feed side could keep relatively high two separation driving forces (H2 fugacity and hydrocarbons fugacity). The results show that the coupling method could synchronously increase both the concentration and the recovery rate of H2 in the product gas. At the same time, the volume and concentration of the hydrocarbons in hydrate both increases effectively. It indicates that hydrate and membrane separation methods support each other in the separation process. The hydrate-membrane coupling method fundamentally solves the issue of the decreasing driving force resulting from single separation method and phase equilibrium relationship. 相似文献
5.
Suzuki-Miyaura (S-M) is regarded the most powerful way for synthesis biaryls, triaryls, or incorporating of substituted aryl moieties in organic preparation by the cross-coupling of aryl boronic acid with aryl halides using the Pd catalyst. This work reports the combining of the hydrothermal and microwave-assisted protocol to convert the glucose to magnetic carbon spheres (Fe3O4-CSPs) decorated with Pd nanoparticles (NPs) as the catalyst for Suzuki-Miyaura cross-coupling reactions. The physicochemical properties in the produced composite were examined using FESEM, HRTEM, nitrogen isotherms, Raman spectroscopy, FTIR, XPS, and XRD. The as-fabricated composite Pd/Fe3O4-CSPs is mostly spherical with a core–shell structure and possesses a great surface area of 253.2 m2·g-1. Its catalytic performance demonstrates that the composite has excellent stability and high tolerance Suzuki-Miyaura cross-coupling reactions in 30 min at 80 ℃. Both activated and deactivated aryl halides provided excellent yield. The as-fabricated catalyst was recycled for up to four catalytic cycles without a substantial decline in performance. Moreover, this research offers a facile roadmap for synthesizing Pd/Fe3O4-CSPs composites and promoting the practical implementation of Pd/Fe3O4-CSPs catalysts for organic transformation processes. 相似文献
6.
Barak Ratzker Avital Wagner Bar Favelukis Sharone Goldring Sergey Kalabukhov Nachum Frage 《Journal of the European Ceramic Society》2021,41(6):3520-3526
Doped transparent ceramics with high optical quality can serve as materials for photonic applications such as laser gain media. In that regard, transparent polycrystalline alumina has potential for high-power applications due to its excellent physical and chemical properties, combined with unique doping possibilities. However, optical birefringence of Al2O3 crystals make achieving sufficiently high optical transmittance a processing challenge. In the present study, we demonstrated fabrication of highly transparent 0.5 at.% Cr:Al2O3 ceramics by high-pressure spark plasma sintering (HPSPS). The optical properties of these polycrystalline ruby ceramics were analyzed in order to assess possible laser operation (at 694.3 nm). The obtained ceramics exhibit high in-line transmittance (~72.5 % at 700 nm), equivalent to a scattering coefficient of 2.15 cm?1, and characteristic ruby photoluminescence. The theoretically estimated lasing threshold and percentage of absorbed pump power indicate that such ruby ceramic lasers could operate at reasonable thresholds of 80?225 mW with short lengths of 0.5?5 mm. Thus, HPSPS is a promising method for producing laser-quality doped transparent ceramics for compact laser systems. 相似文献
7.
Incorporating microgrids coupling with utilization of flexible switching to enhance self-healing ability of electric distribution systems 下载免费PDF全文
Saeed Mousavizadeh Arman Alahyari Seyed Reza Movahhed Ghodsiny Mahmoud-Reza Haghifam 《电力系统保护与控制》2021,6(3):300-310
Electric distribution networks have to deal with issues caused by natural disasters. These problems possess unique characteristics, and their severity can make load restoration methods impotent. One solution that can help in alleviating the aftermath is the use of microgrids (MGs). Employing the cumulative capacity of the generation resources through MG coupling facilitates the self-healing capability and leads to better-coordinated energy management during the restoration period, while the switching capability of the system should also be considered. In this paper, to form and schedule dynamic MGs in distribution systems, a novel model based on mixed-integer linear programming (MILP) is proposed. This approach employs graph-related theories to formulate the optimal formation of the networked MGs and management of their proper participation in the load recovery process. In addition, the Benders decomposition technique is applied to alleviate computability issues of the optimization problem. The validity and applicability of the proposed model are evaluated by several simulation studies. 相似文献
8.
Günther Huber Otto Machhammer Maren Lepple Claudia Weidlich Cord-Henrich Dustmann Akane Hartenbach 《化学,工程师,技术》2021,93(4):664-672
A photovoltaic system could supply a single-family house with electrical power, warm water, and room heat if the energy would be distributed over the year to suit the load profile. However, storage systems for this are not state of the art yet. A concrete example is used to estimate which parameters such a power storage system should have. A suitable electrochemical reaction system based on inorganic salt mixtures is proposed. The German Federal Ministry of Education and Research is currently funding the development of a world storage facility based on the same reaction system. 相似文献
9.
Atsuki Yamaguchi Kazuki Fukui Yuki Fujiwara Shingo Tamaki Sachie Kusaka Fuminobu Sato 《Journal of Nuclear Science and Technology》2021,58(1):80-86
ABSTRACT It is important to perform neutron transport simulations with accurate nuclear data in the neutronics design of a fusion reactor. However, absolute values of large-angle scattering cross sections vary among nuclear data libraries even for well-examined nuclide of iron. Benchmark experiments focusing on large-angle scattering cross sections were thus performed to confirm the correctness of nuclear data libraries. The series benchmark experiments were performed at a DT neutron source facility, OKTAVIAN of Osaka University, Japan, by the unique experimental system established by the authors’ group, which can extract only the contribution of large-angle scattering reactions. This system consists of two shadow bars, target plate (iron), and neutron detector (niobium). Two types of shadow bars were used and four irradiations were conducted for one experiment, so that contribution of room-return neutrons was effectively removed and only large-angle scattering neutrons were extracted from the measured four Nb reaction rates. The obtained experimental results were compared with calculations for five nuclear data libraries including JENDL-4.0, JEFF.-3.3, FENDL-3.1, ENDF/B- VII, and recently released ENDF/B-VIII. It was found from the comparison that ENDF/B-VIII showed the best result, though ENDF/B-VII showed overestimation and others are in large underestimation at 14 MeV. 相似文献
10.
以氧化石墨烯溶胶为前体,通过旋涂工艺制备薄膜型气敏元件,在低温80~180℃下进行热处理,获得系列不同还原程度的还原氧化石墨烯气敏元件,采用XRD、AFM、FT-IR、XPS对样品的层结构、薄膜厚度及含氧官能团变化属性进行表征,将气敏薄膜元件在相对湿度为11.3%~93.6%的范围内进行预湿处理,并测定元件对甲醛气氛的敏感性能。结果表明:随热还原处理温度的升高,氧化石墨烯的结构逐渐向类石墨结构转变,含氧官能团逐渐脱失,缺陷增多,薄膜的方块电阻呈数量级地减小,从41 MΩ减小至928 Ω;经不同湿度预处理的气敏元件置于甲醛气氛中产生了水分子与甲醛分子的竞争吸附,从而导致电阻的明显变化;在10?4甲醛气氛下,未还原或热还原温度较低的气敏元件适用于低、高湿环境下甲醛气氛的气敏测试,最大灵敏度为69.1%,而还原温度适中的元件则适用于中湿环境的甲醛测试,最大灵敏度为80.3%。 相似文献