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1.
《International Journal of Hydrogen Energy》2022,47(94):40099-40115
In order to reveal the mechanism of water fog explosion suppression and research the combined effect of water fog and obstacle on hydrogen/air deflagration, multiple sets of experiments were set up. The results show that the instability of thermal diffusion under lean combustion conditions is the main influencing factor of hydrogen/air flame surface instability, and the existence of water fog will aggravate the hydrogen/air flame surface instability. When obstacle is not considered, 8 μm, 15 μm, 30 μm water fog can significantly reduce the flame velocity and explosion overpressure of hydrogen/air, 45 μm fine water fog plays the opposite role. When considering the relative position of the water fog release position and the obstacle, the 8 μm, 15 μm, 30 μm water fog has almost no suppression effect when released near the obstacle, but a significant suppression effect occur, when using the 45 μm water fog. In the field of theoretical research, the research results not only provide an experimental basis for the fine water fog to reduce the consequences of hydrogen explosion accidents, and the optimal diameter range used by the water fog, but also provide experimental reference for the numerical simulation of hydrogen/air explosion suppression in semi-open space, and promote the development of hydrogen explosion suppression theory. In terms of engineering applications, this study can provide a theoretical basis for the layout of fire fighting equipment in the engine room of nuclear power plants or hydrogen-powered ships. 相似文献
2.
《Ceramics International》2022,48(6):8069-8080
Homogeneous thin films of Molybdenum oxide (MoO3) were grown on quartz and glass substrates using the thermal evaporation method. XRD results showed that the MoO3 powder has a polycrystalline structure with an orthorhombic crystal system whereas the MoO3 thin films have amorphous nature. SEM images showed that the MoO3 thin films have a nearly uniform surfaces with worm-like shape grains. The film thickness influences on the linear and nonlinear optical characteristics of MoO3 thin films that were examined using spectrophotometric measurements and from which, the linear optical constants of the MoO3 thin films were estimated. The electronic transition type was determined as a direct allowed one. The values of the optical band gap were obtained to be in the range of 3.88–3.72 eV. The dispersion parameters, third-order nonlinear optical susceptibility, and the nonlinear refractive index of the MoO3 thin films were determined and interpreted in the light of the single oscillator model. The temperature dependence of the DC electrical conductivity and the corresponding conduction mechanism for the MoO3 films were investigated at temperatures ranging from 303 to 463 K. 相似文献
3.
针对现有基于视频监控的人流量统计方案成本高、算法复杂且不利于个人隐私保护的局限性,利用毫米波雷达体积小、成本低、分辨率高的特点,提出了一种基于双时间点检测的人流量监测方法。该方法先获取人体目标散射点位置和多普勒频移信息来构成点云数据,然后根据多普勒频移正负来判断人体的运动方向,并筛选具有高多普勒频移值的点云数据以降低干扰点对聚类结果的影响;在双时间点对特定区域内人员数量进行统计,并根据双时间点之间所获取的点云数据聚类结果对所统计人员数据进行修正。实验结果表明,该方法能够用匿名的方式以较高的正确率统计人员进出。 相似文献
4.
Zhongchao Fu Xiaodong Li Mu Zhang Qi Zhu Ji-Guang Li Jiao He Xing'an Wang Xudong Sun 《Journal of the American Ceramic Society》2021,104(6):2689-2701
An easy albeit quite effective deionization suspension treatment was adopted to alleviate the detrimental effects related to the hydrolysis of Y2O3 in an aqueous medium. Fabrication of highly transparent Y2O3 ceramics with a fine grain size via air pre-sintering and post–hot isostatic pressing (HIP) treatment without using any sintering additive was achieved using the treated suspensions. The hydrolysis issue of Y2O3 powder in an aqueous medium was effectively alleviated by using deionization treatment, and a well-dispersed suspension with a low concentration of dissolved Y3+ species was obtained. The dispersed suspensions were consolidated by the centrifugal casting method, and the green bodies derived from the suspension of 35.0 vol% solid loading showed an improved homogeneity with a relative density of 52.1%. Fully dense Y2O3 transparent ceramic with high transparency was obtained by pre-sintering consolidated green compacts at a low temperature of 1400°C for 16 h in air followed by a post-HIP treatment at 1550°C for 2 h under 200 MPa pressure. The sample had a fine average grain size of 690 nm. The in-line transmittance of the sample reached 83.3% and 81.8% at 1100 nm and 800 nm, respectively, very close to the theoretical values of Y2O3. 相似文献
5.
《Journal of the European Ceramic Society》2021,41(14):6983-6990
Ternary 0.552Pb(Ni1/3Nb2/3)O3-xPbZrO3-(0.448-x)PbTiO3 (PNN-PZ-PT) ceramics near the triple point compositions were fabricated by an improved two-step sintering method. The triple point composition 0.552PNN-0.135PZ-0.313PT ceramic has outstanding piezoelectric performance with piezoelectric coefficient d33 = 1200 pC/N. Its easy fabrication and low cost make this piezoelectric material an excellent candidate for high sensitivity sensors and ultrasonic transducers. The evolution of domain structures for ceramics with composition near the triple point provides deeper insight into the mechanism of ultrahigh piezoelectric properties of PNN-PZ-PT ceramics. 相似文献
6.
Aluminum, used as a material for heat exchangers in air conditioners, often has problems of leakage of refrigerant on the Al surface due to corrosion. The problems originate from pitting corrosion of the Al in an external environment. To understand corrosion problems, it is necessary to study the corrosion behavior of Al in various environments. In this study, the effects of environmental factors on the corrosion behavior of Al were studied by the surface analysis and electrochemical testing in 3.5 wt% NaCl solutions, with changes of dissolved oxygen, temperature, and concentration of Cl− and S ions. Among the external environmental factors, the presence of oxygen and the increase of Cl− ion concentration do not significantly affect the corrosion potential of Al, leading to an increase of only 1.1 and 6 times, respectively. There was a significant decrease in the corrosion resistance of Al, approximately 40 and 800 times, respectively, with the increase of concentration of S and temperature. 相似文献
7.
Housei Akazawa 《Ceramics International》2021,47(3):3292-3298
Undoped and Er3+-doped Bi2O3 thin films were sputter-deposited on Si(100) substrates. Sufficiently oxidized Bi2O3 films with refractive indices between 2.17?2.23 were obtained at a wavelength of 633 nm; these values are comparable to those of bulk Bi2O3 crystals. While the film composition was stable for deposition temperatures between room temperature (RT) and 450 °C, the refractive index steeply decreased above 450 °C and reached 1.4 at 600 °C. The lowering of the optical transmittance spectra indicated aggregation of metallic Bi and darkening of the film. All films exhibited X-ray diffraction patterns of α-Bi2O3. The direct and indirect bandgap energies derived from the Tauc plots were 3.4–3.7 eV and 1.9–2.5 eV, respectively, depending on the O2 flow rate and deposition temperature. Upon excitation of Er3+-doped Bi2O3 films at 532 nm, Er3+ emissions peaking at 1537 and 1541 nm appeared, and the photoluminescence spectra included fine structures reflecting crystal-field splitting. Resonant excitation of Er3+ 4f levels and indirect excitation via the defect levels of Bi2O3 followed by energy transfer to Er3+ contributed to the emission. The films deposited at RT with Er concentrations of 2 at.% had the emission intensity of Er3+, but concentration quenching strongly suppressed the Er3+ emission because the doped Er3+ ions stayed inside the Bi2O3 crystals. At deposition temperatures above 400 °C, the concentration quenching was mitigated possibly because out-diffusion of Er3+ ions reduced the effective number of Er3+ ions in the Bi2O3 crystalline domains. 相似文献
8.
9.
《Journal of the European Ceramic Society》2022,42(11):4429-4435
Here we design a novel multi-principal element carbide system (Ti,Zr,Hf,W)C with a miscibility gap using computational tools and report on the formation of a single-phase (Ti,Zr,Hf,W)C after spark plasma sintering. The (Ti,Zr,Hf,W)C shows high nanohardness (32.7 GPa) and fracture toughness (5 MPa·m1/2). Aging studies at 1350 °C for 100 h show that the single-phase carbide solid solution is quite stable even though this temperature is within the predicted miscibility gap of the system. Detailed electron microscopy characterization shows that phase separation has initiated with minor decomposition after aging by forming rock-salt (Ti,W)C- and (Zr,Hf)C-rich phases as well as hexagonal WC precipitates. We show that the (Ti,W)C- and (Zr,Hf)C-rich phases form a lamellar structure upon aging and the interlamellar spacing is considerably coarser than what has been previously found for the binary (Ti,Zr)C system. The decomposition kinetics, on the other hand, is sluggish due to the reduced driving force for phase decomposition. 相似文献
10.