Facile synthesis of Ti3C2 MXene-modified Bi2.15WO6 nanosheets with enhanced reactivity for photocatalytic reduction of Cr(VI)

Through a facile hydrothermal method, we have successfully prepared Ti₃C₂/Bi_2.15WO₆ (TC/BWO) composite, and systematically investigated their reactivity for the photocatalytic reduction of Cr(VI) under visible light. X-ray diffraction and Raman analysis confirm the formation of heterostructure between Bi_2.15WO₆ and Ti₃C₂. The resultant 7TC/BWO composite exhibits enhanced photoactivity toward Cr(VI) reduction. After 120 min irradiation, the conversion of Cr(VI) reaches 92.5% with the quasi-first-order kinetic constant of k = 0.0145 min^?1, which is higher than that of pure BWO (30% and k = 0.0005 min^?1). The electrochemical and photoluminescent characterization confirm that the introduction of Ti₃C₂ is conducive to the separation of carriers, thus significantly improves the photocatalytic performance of TC/BWO. Furthermore, the radical capture experiments verify that the electrons are important for enhancing reduction of Cr(VI) to Cr(III). As a result, this research provides a comprehensive understanding of the reduction of Cr(VI) by TC/BWO composite under visible light.     

Real time power management strategy for fuel cell hybrid electric bus based on Lyapunov stability theorem

The fuel cell/battery durability and hybrid system stability are major considerations for the power management of fuel cell hybrid electric bus (FCHEB) operating on complicated driving conditions. In this paper, a real time nonlinear adaptive control (NAC) with stability analyze is formulated for power management of FCHEB. Firstly, the mathematical model of hybrid power system is analyzed, which is established for control-oriented design. Furthermore, the NAC-based strategy with quadratic Lyapunov function is set up to guarantee the stability of closed-loop power system, and the power split between fuel cell and battery is controlled with the durability consideration. Finally, two real-time power management strategies, state machine control (SMC) and fuzzy logic control (FLC), are implemented to evaluate the performance of NAC-based strategy, and the simulation results suggest that the guaranteed stability of NAC-based strategy can efficiently prolong fuel cell/battery lifespan and provide better fuel consumption economy for FCHEB.     

Enhanced oxygen evolution reaction kinetics through biochar-based nickel-iron phosphides nanocages in water electrolysis for hydrogen production

Highly-efficient and stable non-noble metal electrocatalysts for overcoming the sluggish kinetics of oxygen evolution reaction (OER) is urgent for water electrolysis. Biomass-derived biochar has been considered as promising carbon material because of its advantages such as low-cost, renewable, simple preparation, rich structure, and easy to obtain heteroatom by in-situ doping. Herein, Ni₂P–Fe₂P bimetallic phosphide spherical nanocages encapsulated in N/P-doped pine needles biochar is prepared via a simple two-step pyrolysis method. Benefiting from the maximum synergistic effects of bimetallic phosphide and biochar, high conductivity of biochar encapsulation, highly exposed active sites of Ni₂P–Fe₂P spherical nanocages, rapid mass transfer in porous channels with large specific surface area, and the promotion in adsorption of reaction intermediates by high-level heteroatom doping, the (Ni_0.75Fe_0.25)₂P@NP/C demonstrates excellent OER activity with an overpotential of 250 mV and a Tafel slope of 48 mV/dec at 10 mA/cm² in 1 M KOH. Also it exhibits a long-term durability in 10 h electrolysis and its activity even improves during the electrocatalytic process. The present work provides a favorable strategy for the inexpensive synthesis of biochar-based transition metal electrocatalysts toward OER, and improves the water electrolysis for hydrogen production.     

超临界机组发生FAC的因素及相互关系分析

为了减轻因流动加速腐蚀(FAC)引起的锅炉结垢加速、汽水系统管道厚度减小甚至爆裂现象，对超临界机组发生流动加速腐蚀的机理及其主要影响因素进行了研究，并讨论了管壁内表面粗糙度、蒸汽含汽率、pH值、溶氧量对FAC的影响，以及温度与pH值、温度与流速、pH值与溶解氧量、溶解氧量与氢电导率等影响因素之间的相互作用关系，最后结合实际电厂的运行数据验证了分析结果。研究表明：减小工质流速、管壁粗糙度和氢电导率，增大给水的pH值和溶解氧含量可以使FAC的腐蚀速率减小，超临界加氧处理时pH值应在8.9～9.2之间，溶解氧量范围为45～100μg/L,氢电导率的期望值在0.1μS/cm以下。由于各影响因素之间的作用十分复杂，本文只给出了大致范围和趋势，并未给出准确数据。     

A triptycene derived hypercrosslinked polymer for gas capture and separation applications

This work describes facile synthesis of a porous polymeric material ( T-HCP ) using readily available reagents. Specifically, T-HCP is a thermally stable and hypercrosslinked polymer (HCP) that is essentially microporous with a high BET specific surface area (940 m² g^?1). Triptycene based polymers are known to feature internal free volume. Thus, the incorporation of triptycene units and extensive crosslinking by an external cross-linker in T-HCP makes it a promising adsorbent for small gas capture applications. Experimental results show that T-HCP demonstrated good CO₂ capture capacity of 132 mg g^?1 (273 K, 1 bar). Molecular hydrogen storage capacity of T-HCP is estimated to be 17.7 mg g^?1 (77 K, 1 bar). T-HCP revealed high CO₂/N₂ selectivity (up to 63) as well as promising CO₂/CH₄ (up to 9.1) selectivity suggesting its potential applicability for CO₂ separation from flue and natural gases.     

高效液相色谱法测定化妆品中依克多因的含量

建立高效液相色谱法测定化妆品中依克多因的分析方法,采用Agilent Poroshell 120 EC-C₁₈色谱柱（100 mm×3.0 mm,2.7μm）分离,以甲醇和p H为3.0的40 mmol/L磷酸二氢钠-10 mmol/L 1-庚烷磺酸钠缓冲溶液梯度洗脱,流速0.8 m L/min,柱温30℃,检测波长210 nm。采用外标法定量测定化妆品中的依克多因含量。结果表明,依克多因在5～800 mg/L的质量浓度范围内呈现良好线性关系,相关系数为0.999 8,方法的检出限和定量限分别为0.3和1.0 mg/L。该方法具有分离效率高、分析时间短、节省溶剂等优点,解决了依克多因在C₁₈色谱柱上保留弱的问题。     

中国传统纺织服饰图案研究述评及价值阐释

目的 了解近年来传统纺织服饰图案的研究动态及发展趋势，归纳学术研究成果并进行评价，总结研究传统服饰图案的意义和对现代设计的启示。方法 基于史论视角、社会文化视角、工艺美术视角和设计艺术视角梳理相关文献，结合现有研究分析中国传统服饰图案的资料来源及其特色、传统服饰图案的研究热点、新时代传统服饰图案的生存策略及中国传统服饰图案创新设计的应用领域。结果指出传统服饰图案的研究史料取材丰富、研究类型呈现多元；当前传统服饰图案的传承与创新体现了数字化发展、美育引导、政策支持的特点；传统服饰图案在服装设计、公共空间、文创产品中大放异彩。结论 中国传统纺织服饰图案研究多点开花，但缺乏系统整体的“中国传统纺织服饰图案知识谱系”用于指导相关研究和实践，对中国传统纺织服饰图案的研究多处于实证分析的层面且欠缺深入独到的理论，通过综述与价值阐述，提出研究的不足之处，纵深学术研究，同时为中国传统纺织服饰图案的现代设计提供新思路。     

Direct ink writing of vancomycin-loaded polycaprolactone/ polyethylene oxide/ hydroxyapatite 3D scaffolds

Novel inks were formulated by dissolving polycaprolactone (PCL), a hydrophobic polymer, in organic solvent systems; polyethylene oxide (PEO) was incorporated to extend the range of hydrophilicity of the system. Hydroxyapatite (HAp) with a weight ratio of 55–85% was added to the polymer-based solution to mimic the material composition of natural bone tissue. The direct ink writing (DIW) technique was applied to extrude the formulated inks to fabricate the predesigned tissue scaffold structures; the influence of HAp concentration was investigated. The results indicate that in comparison to other inks containing HAp (55%, 75%, and 85%w/w), the ink containing 65% w/w HAp had faster ink recovery behavior; the fabricated scaffold had a rougher surface as well as better mechanical properties and wettability. It is noted that the 65% w/w HAp concentration is similar to the inorganic composition of natural bone tissue. The elastic modulus values of PCL/PEO/HAp scaffolds were in the range of 4–12 MPa; the values were dependent on the HAp concentration. Furthermore, vancomycin as a model drug was successfully encapsulated in the PCL/PEO/HAp composite scaffold for drug release applications. This paper presents novel drug-loaded PCL/PEO/HAp inks for 3D scaffold fabrication using the DIW printing technique for potential bone scaffold applications.     

“数字信号处理”课程的几何视角

“数字信号处理”的经典课程体系以“系统”为中心，以离散时间傅立叶变换、z变换和离散傅立叶变换为分析工具，以滤波器设计为目的，注重定理和公式推导及其性质分析，很难让学生建立一个形象的、完整统一的知识体系框架。本文从几何视角将 “系统”化和“代数”化的经典课程体系重构为面向“信号”的“几何”知识体系，从而提升学生对本质问题的“洞察力”，帮助学生建立系统的知识体系。