Noncentrosymmetric Tetrel Pnictides RuSi4P4 and IrSi3P3: Nonlinear Optical Materials with Outstanding Laser Damage Threshold

Noncentrosymmetric (NCS) tetrel pnictides have recently generated interest as nonlinear optical (NLO) materials due to their second harmonic generation (SHG) activity and large laser damage threshold (LDT). Herein nonmetal-rich silicon phosphides RuSi₄P₄ and IrSi₃P₃ are synthesized and characterized. Their crystal structures are reinvestigated using single crystal X-ray diffraction and ²⁹Si and ³¹P magic angle spinning NMR. In agreement with previous report RuSi₄P₄ crystallizes in NCS space group P1, while IrSi₃P₃ is found to crystallize in NCS space group Cm, in contrast with the previously reported space group C2. A combination of DFT calculations and diffuse reflectance measurements reveals RuSi₄P₄ and IrSi₃P₃ to be wide bandgap (E_g) semiconductors, E_g = 1.9 and 1.8 eV, respectively. RuSi₄P₄ and IrSi₃P₃ outperform the current state-of-the-art infrared SHG material, AgGaS₂, both in SHG activity and laser inducer damage threshold. Due to the combination of high thermal stabilities (up to 1373 K), wide bandgaps (≈2 eV), NCS crystal structures, strong SHG responses, and large LDT values, RuSi₄P₄ and IrSi₃P₃ are promising candidates for longer wavelength NLO materials.     

冠状动脉系统的微分积分终端滑模混沌抑制

冠状动脉系统的混沌现象会导致严重的健康问题。以非线性冠状动脉系统为研究对象，建立了不确定性冠状动脉系统动力学模型，提出了不确定性冠状动脉系统的微分积分终端滑模混沌抑制方法，针对该模型的不确定性设计了扰动观测器，根据Lyapunov理论证明了所设计控制系统的稳定性，通过仿真实验验证了所提出的混沌抑制方法的有效性和可行性。     

Effect of O2 and temperature on the catalytic performance of Ni/Al2O3 and Ni/MgAl2O4 for the dry reforming of methane (DRM)

Al₂O₃ and MgAl₂O₄ supported 10% (w/w) Ni catalysts having a dispersion of 1.5 and 2.0% are active for DRM at 600 and 750 °C. High temperature reduction of both the calcined catalysts resulted in metallic Ni being formed, suggesting strong support metal interactions. The CH₄ and CO₂ conversion during DRM are relatively constant with time-on-stream, and are higher for Ni/MgAl₂O₄ than Ni/Al₂O₃. Carbon-whiskers are also detected on both catalysts. O₂ co-feed of 2.6% (v/v) and increasing reaction temperature to 750 °C helped in decreasing the amount of carbon deposited, except for Ni/MgAl₂O₄ at 600 °C. Furthermore, higher conversions and H₂/CO ratios are achieved. It appears that on spent Ni/MgAl₂O₄ a different type of carbon species was formed, and this carbon species was difficult to remove by oxygen at 600 °C. Thus, co-feeding O₂, using an appropriate temperature, and choosing a suitable support can reduce the carbon present on the nickel catalysts during DRM.     

A two-stage vision-based method for measuring the key parameters of ball screws

Ball screws are crucial for improving the reliability and interchangeability of transmission mechanical systems; however, existing contact measurement methods that utilise stylus contact are not efficient, which precludes their use for rapid in-situ geometry evaluation. This paper presents a vision-based two-stage method for rapid measurement of key parameters (raceway arc radii and centre distance) of ball screws. The edge contour information is extracted from the acquired image using the dual-tree complex wavelet transform and non-maximal suppression. In the matching stage, a shape-matching algorithm is used for detecting approximate geometrical centres of raceway arcs. The refinement stage, on the other hand, is implemented for acquiring precise dimensional results. Furthermore, the method of averaging multiple measurements is performed to suppress random noise. A comparative experiment is presented to validate the robustness of the proposed method. Based on experimental results, the calculated mean absolute errors in the measurement of the two raceway arc radii and the centre distance are found to be 0.0082 mm, 0.0079 mm and 0.0055 mm, respectively. This study therefore paves the way for key parameter measurement without removing ball screws.     

全地域机动车驾驶室声学特性分析

以某全地域机动车驾驶室为研究对象,建立驾驶室的有限元模型,验证了有限元模型的有效性。以此有限元模型为基础构建驾驶室谐响应模型,进行谐响应分析,发现驾驶室后壁板的振动是引起驾驶室内部噪声的主要原因。研究驾驶室内部噪声特性,分别进行了声学空腔模态分析和声固耦合模态分析,发现声固耦合系统声压分布比较均匀,大部分呈现局部模态,主要原因可能是驾驶室后壁板的振动。通过驾驶员耳旁声压分析发现增加驾驶室后壁板的厚度,可以在一定程度内降低驾驶室内部噪声对驾驶员的影响,为同类驾驶室通过依靠结构改进来改善声场环境提供了案例依据。     

Mechanism of smoke suppression by melamine in rigid polyurethane foam

The smoke suppression of rigid polyurethane foam (RPUF) modified by melamine was investigated based on three sections: the condensed phase, the carbon layer, and the gas phase. In the condensed phase, the results of thermogravimetry, X‐ray photoelectron spectroscopy (XPS) N1S spectrum, and Fourier transform infrared spectroscopy indicated that melamine could suppress the degradation of RPUF by reacting with the aromatic hydrocarbons. It also reduced the smoke generation because the volatilizable aromatic hydrocarbons were the principal smoke precursors in a fire. In the carbon layer, the decrease from 38.50% to 24.76% of the inner layer oxygen content identified by XPS full‐spectrum and C1S spectrum indicated that melamine could prevent oxygen from transferring into the inner foam by the formation of an enhanced surface carbon layer, and the enhanced carbon layer could also block the release of smoke precursors. In the gas phase, the content of total aromatic hydrocarbons declined to 59.12% according to pyrolysis gaseous chromatography mass spectroscopy and indicated that melamine could reduce the smoke precursors. The results of smoke density chamber and cone calorimeter tests revealed that the addition of the melamine could decrease the smoke density of burning RPUF. Copyright © 2014 John Wiley & Sons, Ltd.     

Improved non-maximum suppression for object detection using harmony search algorithm

Non-maximum suppression (NMS) plays a key role in many modern object detectors. It is responsible to remove detection boxes that cover the same object. NMS greedily selects the detection box with maximum score; other detection boxes are suppressed when the degree of overlap between these detection boxes and the selected box exceeds a predefined threshold. Such a strategy easily retain some false positives, and it limits the ability of NMS to perceive nearby objects in cluttered scenes. This paper proposes an effective method combining harmony search algorithm and NMS to alleviate this problem. This method regards the task of NMS as a combination optimization problem. It seeks final detection boxes under the guidance of an objective function. NMS is applied to each harmony to remove imprecise detection boxes, and the remaining boxes are used to calculate the fitness value. The remaining detection boxes in a harmony with highest fitness value are chosen as the final detection results. The standard Pattern Analysis, Statistical Modeling and Computational Learning Visual Object Classes dataset and the Microsoft Common Objects in Context dataset are used in all of the experiments. The proposed method is applied to two popular detection networks, namely Faster Region-based Convolutional Neural Networks and Region-based Fully Convolutional Networks. The experimental results show that the proposed method improves the average precision of these two detection networks. Moreover, the location performance and average recall of these two detectors are also improved.     

干扰条件下的“北斗”信号解扩重构DOA估计

在干扰条件下，卫星导航抗干扰波束形成算法往往需要卫星信号波达方向（Direction-of-Arrival，DOA）的先验信息。但当存在低信噪比信号或主动干扰源时，常规的DOA估计算法性能急剧下降甚至失效。针对此问题，提出了一种被干扰信号压制的低信噪比“北斗”信号的DOA估计算法。该算法首先通过对接收信号进行子空间投影抑制干扰信号，然后对抑制干扰后的信号进行解扩重构处理，最后通过多重信号分类算法完成对“北斗”信号的DOA估计。仿真结果表明，在干扰信号干信比80 dB条件下，“北斗”信号DOA估计误差在5°以内，为下一步进行波束形成计算提供了高精度的入射角信息。