Inversion,chemical complexity,and interstitial transport in spinels

Spinels with the generic chemical formula AB₂O₄ have potential applications in nuclear energy and batteries. In both cases, their functionality is related to mass transport through the crystal. Here, using long-time atomistic simulations, we examine the impact of the cation structure on interstitial transport in two spinel chemistries, inverse MgGa₂O₄ and double MgAlGaO₄. We emphasize two aspects of the transport properties: the unit mechanisms that are described by individual barriers, for which we introduce pole-figure-like plots, and the aggregate behavior of those unit mechanisms. Compared to previous work on normal spinels, we find that inversion significantly reduces the rate of interstitial transport in these structures and has an impact on the stability of defects as they move through the lattice. In particular, B cation interstitials are found to be kinetically stable only in the inverse MgGa₂O₄. These results provide new insight into relationship between structure, chemistry, and transport in spinels.     

Ferroelectric and electromechanical performance of diverse engineered states of Mn-doped 0.75Pb(Mg1/3Nb2/3)O3-0.25PbTiO3 ceramics

The materials processing history has a great influence on their properties and finally determines their application effect. In this paper, the ferroelectric, polarization-switching current, and strain properties of Mn-doped 0.75Pb(Mg_1/3Nb_2/3)O₃-0.25PbTiO₃ ceramics were studied in fresh state, aged state, and poled state, respectively. Compared with the symmetric polarization-electric-field (P-E) hysteresis loops, current-density-electric-field (J-E) curves, and bipolar electric-field-induced strain (S-E) curves in fresh state samples, asymmetric P-E loops, J-E curves, and bipolar S-E curves were obtained in poled state samples. Well-aged-state samples exhibit double hysteresis P-E loop, four peaks J-E curves, and symmetric S-E curves without negative strain. The symmetry-conforming short-range order (SC-SRO) principle of point defects and internal electric field E_i is employed to clarify the different phenomenon of three states. Results indicated that randomly oriented defect polarization P_D in aged samples can reverse the spontaneous polarization P_S back and result in the double hysteresis P-E loop and four peaks J-E curves. The oriented P_D and resulting E_i in poled-state samples will lead to the asymmetric loops and strain memory effect.     

基于秩序与非秩序理论的文创产品卡通形象设计研究

目的 从秩序与非秩序理论出发,研究文创产品卡通形象的设计方法.方法 对秩序与非秩序理论的视觉机制和创制理论进行梳理,结合实例,阐述了其与文创产品卡通形象设计之间的联系,分析文创产品卡通形象中的秩序与非秩序的表现形式,提出基于秩序与非秩序理论文创产品卡通形象设计的主要原则,归纳出一套基于秩序与非秩序理论的文创产品卡通形象设计流程与方法,指导设计实践,并验证这些理论方法在设计实践中有效性与可行性.结论 通过对秩序与非秩序理论的研究,文创产品卡通形象设计时应注意提高辨识度、亲和力和便于衍生设计的原则.探索基于秩序与非秩序理论的设计流程与方法,按照界定主题、主体形象设计、主体形象拓展、衍生品应用四个环节开展整体方案设计,为文创产品卡通形象设计提供新的思路与方法.     

Reduced‐order method for mathematical modeling of multiphase dc‐dc converter

A multiphase dc‐dc converter is effective for miniaturization and achieving high‐power density in a switching power supply. However, its mathematical modeling becomes complex as the phase number of the circuit increases. This study proposes a new modeling method to derive a reduced‐order method in a simple manner. The frequency characteristics of the reduced‐order model are fit to those of the original mathematical model of the multiphase dc‐dc converter. Therefore, the efficacy of the proposed method is validated.     

Numerical analysis of history-dependent hemivariational inequalities and applications to viscoelastic contact problems with normal penetration

In this paper numerical approximation of history-dependent hemivariational inequalities with constraint is considered, and corresponding Céa’s type inequality is derived for error estimate. For a viscoelastic contact problem with normal penetration, an optimal order error estimate is obtained for the linear element method. A numerical experiment for the contact problem is reported which provides numerical evidence of the convergence order predicted by the theoretical analysis.     

Generalised multivariable supertwisting algorithm

The purpose of this paper is to present an extension of the generalised supertwisting algorithm (STA) to the multivariable framework. We begin by introducing an algorithm that may be deemed as a linear, quasicontinuous, or discontinuous multivariable system, depending on the functions that define them. For the class represented by such an algorithm we prove the robust, Lyapunov stability of the origin and characterise the perturbations that preserve its stability. In particular, when its vector field is discontinuous or quasicontinuous our algorithm is endowed with finite‐time stability. Due to its resemblance to the scalar case, we denote such finite‐time stable systems as generalised multivariable STA. Furthermore, the class of finite‐time stable systems comprise the currently available versions of STAs. To finalise, by means of simulation examples, we show that our proposed finite‐time stable algorithms are well suited for signals online differentiation and highlight their dynamical traits.     

Deposition of UF5 on the surface of steel material having oxide coating in contact with gaseous UF6

When UF6 is handled in leak tight system, the amount of uranium compound formed on the surface of containers, valves, and others in UF6 handling facilities is not so significant for a short term that special attention has not been given to this problem. The present work was done to throw some more light on this problem based on the recent experiment. We discuss the possibility that the intermolecular transfer of a fluorine atom from UF6 to UF5 may participate in the formation of uranium compound. The discussion includes also the unique features contained in the experimental result, the reaction processes assumed in this problem, and the derivation of a rate equation for expressing the deposition of uranium compound. Furthermore, we propose a new method for determining nonlinear parameters included in a governing differential equation having two variables for expressing the deposition of uranium compound from experimental raw data.     

消声元件安装位置对消声效果的影响

分别以消声量和管口阶次噪声作为评价指标,研究消声元件安装位置对消声效果的影响规律,设计在直管不同位置安放四分之一波长管的消声量测量试验对消声量评价。结果表明:设计频率声模态下,在反节点处安装波长管消声量最大,与理论分析完全吻合;进一步对消声量进行仿真计算,结果与试验完全相符。对于管口噪声指标评价,设计频率为267 Hz的谐振腔解决某发动机4000 r/min时进气管口存在4阶噪声引起的噪声峰值问题,对比谐振腔安装在进气管路该频率附近的声模态反节点和节点位置的管口4阶噪声,可知谐振腔布置在反节点位置比节点位置噪音降低了24 dB。两个案例充分证明声学系统模态反节点位置是消声元件的最佳布置位置。