Co?N graphene encapsulated cobalt catalyst for H2O2 decomposition under acidic conditions

Hydrogen peroxide (H₂O₂) has been listed as one of the 100 most important chemicals in the world. However, huge amount of residual H₂O₂ is hard to timely decomposed into O₂ and H₂O under acidic condition, easily resulting in explosion hazard. Here, we reported a core–shell structure catalyst, that is graphene with Co N structure encapsulated Co nanoparticles. Co N graphene shell serves as the active site for the H₂O₂ decomposition, and Co core further enhance this decomposition. Benefiting from it, the H₂O₂ decomposition were close to 100% after 6 cycles without pH adjustment, which increased 6 orders of magnitude compared with no catalyst. At the same time, the O₂ generation reached 99.67% in 2 h with little metal leaching, and ·OH has been greatly inhibited to only 0.08%. This work can cleanly remove H₂O₂ with little deep oxidation and protect the process of H₂O₂ utilization to achieve a safer world.     

稳产国Ⅵ柴油并兼产喷气燃料技术方案的工业应用

介绍了浙江石油化工有限公司新建的3 Mt/a柴油加氢精制装置，其配套使用中国石化石油化工科学研究院有限公司开发的催化剂级配技术，并实施了可根据原料供应及市场产品需求情况灵活调整切换的2种生产技术方案。1 a的安稳生产运行结果表明:该装置以直馏柴油为主原料，通过分馏塔的馏分切割及其侧线抽出，实现了稳产国Ⅵ柴油并兼产喷气燃料技术方案的工业化应用；在实施以兼产喷气燃料为主的生产技术方案时，通过调整常一线柴油的掺炼量，不仅可以生产含硫量小于10.0 μg/g的精制柴油产品，同时兼产所得到的喷气燃料产品含硫量小于0.5 μg/g，赛波特颜色号值大于30；在实施主产精制柴油组分方案时，通过掺炼质量分数为20%~40%的催化柴油，并使所提炼得到的精制柴油组分含硫量小于6.0 μg/g的前提下，这些精制柴油组分产品既可直接作为满足国Ⅵ柴油产品出厂待售，也可作为柴油调和组分储存待用于产品的进一步优化。     

Towards artificial intelligence at scale in the chemical industry

In the Industry 4.0 era, the chemical industry is embracing broad adoption of artificial intelligence (AI) and machine learning (ML) methods. This article provides a holistic view of how the industry is transforming digitally towards AI at scale. First, a historical perspective on how the industry used AI to aid humans in better decision-making is shown. Then state-of-the-art AI research addressing industrial needs on reliability and safety, process optimization, supply chain, material discovery, and reaction engineering is highlighted. Finally, a vision of the plant of the future is illustrated with critical components of AI-ready culture, model life cycle management, and renewed role of humans in chemical manufacturing.     

Nature inspired supply chain solutions: definitions,analogies, and future research directions

ABSTRACT

Supply chains are becoming increasingly complex, and many companies and researchers are looking to nature for finding solutions. In this paper, we provide a narrative synthesis and systematic review to explore state-of-the-art, and identify key areas for exploration of nature inspired solutions in the supply chain area. We consider strategic, tactical, and operational decisions within supply chains and identify analogies between biological systems and supply chains to create a new research agenda. Our findings show that the majority of the research in nature inspired supply chains from the systemic perspective focuses on closed loop supply chains. In contrast, similar systemic solutions such as industrial symbiosis, circular economy, and industrial ecology have not been explored as frequently. Reducing production waste (industrial symbiosis) in addition to end-of-life product waste (closed loop supply chains), optimising raw material use and extending the life of used resources (circular economy), investigating the interactions between biosphere and technosphere (industrial ecology), and seeking solutions to industrial problems from nature (biomimicry) are all possible paths for reaching a zero-waste economy. These systemic solutions have a considerable impact on the supply chains at the strategic, tactical, and operational levels, which need to be explored to identify efficient and effective solutions.     

黑龙江大豆产业高质量发展研究—以海伦大豆为例（网络首发、推荐阅读）

黑龙江是我国最大的大豆优势产区，研究其大豆产业高质量发展的思路和有效路径，对于振兴我国国产大豆产业，推动供给侧改革，助力乡村振兴战略，促进地方产业经济发展，保障粮食安全具有重要意义。通过对黑龙江大豆产业现状和海伦大豆产业优势进行分析，结合国家重大产业政策导向，提出以海伦大豆为例，基于供应链、产业链、价值链“三链协同”的黑龙江大豆产业高质量发展思路，为推进“十四五”时期我国国产大豆产业发展提供参考。     

基于模糊评价理论对层燃工业锅炉综合性能的研究与分析

为有效地平衡锅炉效率与排放之间的关系,通过分析锅炉的能效指标,建立了结合效率因素、燃料管理因素和环境因素等的能效评价指标体系。采用组合赋权法确定权重,建立了锅炉系统模糊综合评价模型,并利用该模型对山西大同某层燃蒸汽锅炉进行了综合能效评价与分析。结果表明:锅炉的综合评级得分为0.59,燃料设备因素指标得分仅为0.19。该锅炉热效率虽然达到了设计要求,但锅炉飞灰含碳量偏大,同时过量空气系数为2.34,远大于设计标准1.65。综合分析其原因是漏风过大,该分析结果与现场热力测试实验数据相符合。     

长江经济带工业集聚对水环境污染的影响——基于空间计量与门槛效应的检验

经济发展与生态环境动态良性循环已经成为社会经济发展的重要议题。为实现长江经济带高质量发展，以2007—2018年长江经济带11个省市为样本，采用空间计量和面板门槛模型考察工业集聚与水环境污染之间的关系。研究表明：长江经济带各省市水环境污染具有显著的空间自相关性；长江经济带工业集聚水平和水环境污染表现出先降低后增强的“U”形变化特征，说明工业集聚水平对水环境污染的影响存在一个阈值；长江经济带工业集聚产生的规模效应和结构效应对水环境污染存在显著的双门槛效应，在不同的工业集聚水平下，规模效应和结构效应表现出不同的外部性特征；工业集聚产生的技术溢出效应对水环境污染的影响同样具有显著的双门槛作用；随着各地区工业集聚水平的提高，技术溢出效应对水环境污染的减排作用表现出先强后弱的趋势。     

唐家河煤矿工业场地位置选择及开拓方案设计

通过对唐家河煤矿自然地形条件及外部条件分析,结合井下煤层赋存情况,设计提出三个工业场地选址方案和两个开拓布置方案,通过技术、经济比较,选择陈家湾场地立井开拓方式,减少了矿井初期投资及后期运营费。