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1.
大排田岩体位于粤北澜河铀矿集区内,对研究区内大排田岩体粗中粒斑状黑云母花岗岩进行了详细的岩相学和地球化学分析,以探讨其岩石成因、岩浆源区及与铀成矿的关系。结果表明,大排田岩体中粗粒斑状黑云母花岗岩具有高SiO2(73.6%~76.5%),富Al2O3(12.4%~13.5%)、富碱(K2O=5.21%~5.63%,Na2O=2.44%~2.76%),且钾大于钠,贫MgO(0.23%~0.52 %)、铝饱和指数(A/CNK)为1.30~1.56,FeOt/MgO为3.21~6.61,属于高钾钙碱性过铝质花岗岩。大排田岩体微量元素显示了Rb、Th、U、Ta相对富集, Ba、Nb、Sr等元素相对亏损特征。稀土元素配分模式总体呈右倾型,轻重稀土分馏明显,轻稀土相对富集(112×10-6~245×10-6),重稀土相对亏损(26.7×10-6~53.3×10-6),Eu显示了负异常特征。上述地球化学特征指示其具有A2型花岗岩特征。推测其形成于拉张构造背景下,由变泥质沉积岩发生部分熔融形成的。  相似文献   
2.
Through a facile hydrothermal method, we have successfully prepared Ti3C2/Bi2.15WO6 (TC/BWO) composite, and systematically investigated their reactivity for the photocatalytic reduction of Cr(VI) under visible light. X-ray diffraction and Raman analysis confirm the formation of heterostructure between Bi2.15WO6 and Ti3C2. The resultant 7TC/BWO composite exhibits enhanced photoactivity toward Cr(VI) reduction. After 120 min irradiation, the conversion of Cr(VI) reaches 92.5% with the quasi-first-order kinetic constant of k = 0.0145 min?1, which is higher than that of pure BWO (30% and k = 0.0005 min?1). The electrochemical and photoluminescent characterization confirm that the introduction of Ti3C2 is conducive to the separation of carriers, thus significantly improves the photocatalytic performance of TC/BWO. Furthermore, the radical capture experiments verify that the electrons are important for enhancing reduction of Cr(VI) to Cr(III). As a result, this research provides a comprehensive understanding of the reduction of Cr(VI) by TC/BWO composite under visible light.  相似文献   
3.
The fuel cell/battery durability and hybrid system stability are major considerations for the power management of fuel cell hybrid electric bus (FCHEB) operating on complicated driving conditions. In this paper, a real time nonlinear adaptive control (NAC) with stability analyze is formulated for power management of FCHEB. Firstly, the mathematical model of hybrid power system is analyzed, which is established for control-oriented design. Furthermore, the NAC-based strategy with quadratic Lyapunov function is set up to guarantee the stability of closed-loop power system, and the power split between fuel cell and battery is controlled with the durability consideration. Finally, two real-time power management strategies, state machine control (SMC) and fuzzy logic control (FLC), are implemented to evaluate the performance of NAC-based strategy, and the simulation results suggest that the guaranteed stability of NAC-based strategy can efficiently prolong fuel cell/battery lifespan and provide better fuel consumption economy for FCHEB.  相似文献   
4.
Highly-efficient and stable non-noble metal electrocatalysts for overcoming the sluggish kinetics of oxygen evolution reaction (OER) is urgent for water electrolysis. Biomass-derived biochar has been considered as promising carbon material because of its advantages such as low-cost, renewable, simple preparation, rich structure, and easy to obtain heteroatom by in-situ doping. Herein, Ni2P–Fe2P bimetallic phosphide spherical nanocages encapsulated in N/P-doped pine needles biochar is prepared via a simple two-step pyrolysis method. Benefiting from the maximum synergistic effects of bimetallic phosphide and biochar, high conductivity of biochar encapsulation, highly exposed active sites of Ni2P–Fe2P spherical nanocages, rapid mass transfer in porous channels with large specific surface area, and the promotion in adsorption of reaction intermediates by high-level heteroatom doping, the (Ni0.75Fe0.25)2P@NP/C demonstrates excellent OER activity with an overpotential of 250 mV and a Tafel slope of 48 mV/dec at 10 mA/cm2 in 1 M KOH. Also it exhibits a long-term durability in 10 h electrolysis and its activity even improves during the electrocatalytic process. The present work provides a favorable strategy for the inexpensive synthesis of biochar-based transition metal electrocatalysts toward OER, and improves the water electrolysis for hydrogen production.  相似文献   
5.
针对燃气轮机故障诊断过程中诊断精度不足,卡尔曼滤波易出现“弥散”现象的问题,提出了一种基于滤波阵列的燃气轮机气路故障诊断方法。该方法首先构建了一组基于健康参数调度的平衡流形展开模型阵列,然后结合平方根容积卡尔曼滤波对气路部件健康参数进行了实时估计,最后通过隔离因子实现了对故障部件的检测与隔离。仿真表明:该方法有效解决了卡尔曼滤波在故障诊断过程中出现“弥散”现象的问题,针对燃气轮机气路部件突变故障,能够有效实现故障的检测、隔离与估计。  相似文献   
6.
Nonintrusive load monitoring (NILM) is crucial for extracting patterns of electricity consumption of household appliance that can guide users’ behavior in using electricity while their privacy is respected. This study proposes an online method based on the transient behavior of individual appliances as well as system steady-state characteristics to estimate the operating states of the appliances. It determines the number of states for each appliance using the density-based spatial clustering of applications with noise (DBSCAN) method and models the transition relationship among different states. The states of the working appliances are identified from aggregated power signals using the Kalman filtering method in the factorial hidden Markov model (FHMM). Thereafter, the identified states are confirmed by the verification of system states, which are the combination of the working states of individual appliances. The verification step involves comparing the total measured power consumption with the total estimated power consumption. The use of transient features can achieve fast state inference and it is suitable for online load disaggregation. The proposed method was tested on a high-resolution data set such as Labeled hIgh-Frequency daTaset for Electricity Disaggregation (LIFTED) and it outperformed other related methods in the literature.  相似文献   
7.
Nickel selenide electrocatalysts for hydrogen evolution reaction (HER) with a high efficiency and a low-cost have a significant potential in the development of water splitting. However, the inferiority of the high overpotential and poor stability restricts their practical applications. Herein, a composite nanostructure consists of ultrasmall NiSe2 nanocrystals embedded on graphene by microwave reaction is reported. The prepared NiSe2/reduced graphite oxide (rGO) electrocatalyst exhibited a high HER activity with an overpotential of 158 mV at a current density of 10 mA/cm2 and a corresponding moderate Tafel slope of 56 mV/dec in alkaline electrolyte. In addition, a high retention of electrochemical properties (approximately 100%) was demonstrated with an unchangeable microstructure after 100 h of continuous operation.  相似文献   
8.
Sorption selective catalytic reduction of nitrogen oxides (NOx) (sorption-SCR) has ever been proposed for replacing commercial urea selective catalytic reduction of NOx (urea-SCR), while only the single-stage sorption cycle is hitherto adopted for sorption-SCR. Herein, various multi-stage ammonia production cycles is built to solve the problem of relative high starting temperature with ammonia transfer (AT) unit and help detect the remaining ammonia in ammonia storage and delivery system (ASDS) with ammonia warning (AW) unit. Except for the single-stage ammonia production cycle with MnCl2, other sorption-SCR strategies all present overwhelming advantages over urea-SCR considering the much higher NOx conversion driven by the heat source lower than 100°C and better matching characteristics with low-temperature catalysts. Furthermore, the required mass of sorbent for each type of sorption-SCR is less than half of the mass of AdBlue for urea-SCR. Therefore, the multifunctional multi-stage sorption-SCR can realize compact and renewable ammonia storage and delivery with low thermal energy consumption and high NOx conversion, which brings a bright potential for efficient commercial de-NOx technology.  相似文献   
9.
As a form of hybrid multi-energy systems, the integrated energy system contains different forms of energy such as power, thermal, and gas which meet the load of various energy forms. Focusing mainly on model building and optimal operation of the integrated energy system, in this paper, the dist-flow method is applied to quickly calculate the power flow and the gas system model is built by the analogy of the power system model. In addition, the piecewise linearization method is applied to solve the quadratic Weymouth gas flow equation, and the alternating direction method of multipliers (ADMM) method is applied to narrow the optimal results of each subsystem at the coupling point. The entire system reaches its optimal operation through multiple iterations. The power-thermal-gas integrated energy system used in the case study includes an IEEE-33 bus power system, a Belgian 20 node natural gas system, and a six node thermal system. Simulation-based calculations and comparison of the results under different scenarios prove that the power-thermal-gas integrated energy system enhances the flexibility and stability of the system as well as reducing system operating costs to some extent.  相似文献   
10.
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