首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   811篇
  免费   42篇
  国内免费   27篇
电工技术   32篇
综合类   103篇
化学工业   146篇
金属工艺   29篇
机械仪表   23篇
建筑科学   34篇
矿业工程   6篇
能源动力   24篇
轻工业   146篇
水利工程   4篇
石油天然气   10篇
武器工业   3篇
无线电   67篇
一般工业技术   57篇
冶金工业   30篇
原子能技术   3篇
自动化技术   163篇
  2022年   9篇
  2021年   6篇
  2020年   9篇
  2019年   4篇
  2018年   12篇
  2017年   6篇
  2016年   10篇
  2015年   13篇
  2014年   34篇
  2013年   41篇
  2012年   70篇
  2011年   115篇
  2010年   72篇
  2009年   64篇
  2008年   54篇
  2007年   61篇
  2006年   41篇
  2005年   40篇
  2004年   25篇
  2003年   26篇
  2002年   31篇
  2001年   18篇
  2000年   16篇
  1999年   10篇
  1998年   15篇
  1997年   6篇
  1996年   13篇
  1995年   7篇
  1994年   10篇
  1993年   10篇
  1992年   4篇
  1991年   9篇
  1990年   4篇
  1989年   2篇
  1988年   4篇
  1987年   1篇
  1986年   1篇
  1985年   2篇
  1984年   1篇
  1980年   1篇
  1979年   2篇
  1977年   1篇
排序方式: 共有880条查询结果,搜索用时 15 毫秒
1.
行波热声驱动器的性能分析   总被引:1,自引:0,他引:1  
在简单介绍行波热声驱动器的研究历史、工作机理及其与驻波型热声驱动器的区别之后,着重对环路部分的性能进行了预测分析,并给出一些有益的结论。  相似文献   
2.
Natalia Andronova 《Polymer》2005,46(18):6746-6755
The synthesis and characterization of degradable polymeric networks for biomedical applications was performed. Cross-linked films of poly(ε-caprolactone) (PCL) and poly(1,5-dioxepan-2-one) (PDXO) having various mole fractions of monomers and different cross-link densities were successfully prepared using 2,2′-bis-(ε-caprolactone-4-yl) propane (BCP) as cross-linking agent. Reaction parameters were carefully examined to optimise the film-forming conditions. Networks obtained were elastomeric materials, easy to cast and remove from the mould. Effect of CL content and cross-link density on the final properties of the polymer network was evaluated. High CL content or degree of cross-linking led to increase in Young's modulus and decrease in elongation at break. An increase in crystalline domains in films having a higher CL content was observed by optical microscopy. A greater thermal stability was observed in films having a high CL content. The hydrophilicity of the materials could be tailored by changing the CL content. The surface of the films became rougher with higher CL content.  相似文献   
3.
Methanol extracts of the green algaUlva pertusa contain four kinds of glycerolipids that are active as feeding-stimulants for marine herbivorous gastropods. These compounds are digalactosyldiacylglycerol (DGDG), 1,2-diacylglycerly-4-O-(N,N,N-trimethyl)-homoserine (DGTH), 1-monoacylglyceryl-4'-O-(N,N,N-trimethyl)-homoserine (MGTH), and 6-sulfoquinovosyldiacylglycerol (SQDG). The various gastropods exhibit marked specificity, however, as young abaloneHaliotis discus respond to DGDG and DGTH at minute dosages of 20–30 g/sample zone, but do not respond to 300 g of SQDG, which is a phagostimulant for two other kinds of gastropods,Turbo comutus andOmphalius pfeifferi.Chemical Studies on Phagostimulants for Marine Gastropods. Part VI. For Part V, see Sakata et al. (1986b).  相似文献   
4.
Acinetobacter calcoaceticus, a gram-negative bacterium isolated from field soil, was found to be responsible for the biotransformation of 2(3H)-benzoxazolinone (BOA) to 2,2-oxo-1,1-azobenzene (AZOB). Experiments were conducted to evaluate the transformation of BOA to AZOB by this microbe in sterile and nonsterile soil. Transformation studies with soils inoculated withA. calcoaceticus indicated that the production of AZOB increased linearly with the concentration of BOA in sterile soil and showed a quadratic trend in nonsterile soils. This also indicated that all soil types studied for the transformation experiments might containA. calcoaceticus capable of the conversion of benzoxazolinones.  相似文献   
5.
为了在保证安全性的前提下提高大量数据加密的加密速度,本文通过DES和RSA算法的分析,针对DES算法密钥安全性差和RSA算法加密速度慢的问题,提出DES和RSA混合算法.对比DES和RSA两种算法加密所需时间,就RSA算法耗时长的问题,通过几种可行的大素数判定算法分析,提出改进的大素数判定算法.在保证安全性的前提下,将改进的大素数判定算法应用于RSA算法中,提升了加密速度.由于改进算法加密速度仍远差于DES算法,不适合大量数据加密.因此在兼顾安全性与加密速度的基础上,提出DES和RSA混合加密算法.经分析该算法综合了前两种算法的优点,是一种理想的加密算法.  相似文献   
6.
Premang R. Buch 《Polymer》2005,46(15):5524-5532
Novel diamines such as N,N′-bis(aminoaryl)terephthalamido-2-carboxylic acids (BATCA), which contain primary amine, amide and carboxylic acid groups and are soluble in dilute aqueous NaOH solution, were synthesized by reacting aromatic diamines with trimellitic anhydride chloride in dimethylformamide. Poly(amide imide)s containing 3:1 ratio of amide:imide groups in the polymer chain were prepared by low temperature solution polymerization of BATCAs with isophthaloyl chloride or terephthaloyl chloride in dimethylformamide at 5-10 °C to form poly(amide amic acid)s, and followed by treating with a mixture of triethylamine and acetic anhydride. The PAIs were soluble in polar aprotic solvents like dimethylformamide, dimethylacetamide, dimethylsulphoxide and N-methylpyrrolidone, and have inherent viscosities in the range of 0.30-0.66 dL/g. The PAIs were characterized by IR, 1H NMR and 13C NMR techniques. Thermogravimetric analysis (TGA) has shown that the initial decomposition temperatures of the polymers are in the range of 250-440 °C, depending upon the structures of diamine and diacid chloride. The glass transition temperatures of the PAIs are in the range of 128-320 °C. The IDT and Tg values of the polymers containing terephthaloyl unit are higher by about 20-40 °C than those of the polymers with isophthaloyl unit. BATCA could be utilized for the preparation of thin film composite membranes having PAA/PAI barrier layer on PES by in situ interfacial polymerization with IPC/TPC/TMC.  相似文献   
7.
Takeshi Sasaki  Shoichiro Yano 《Polymer》2005,46(18):6968-6975
In order to obtain thermoplastic (before curing) and thermosetting (after curing) polyimides with high Tg for adhesive film, we prepared novel polyimides having phenylethynyl group in the side chain (44% of concentration of curing group) from asymmetric 2,3,3′,4′-biphenyltetracarboxylic dianhydride (a-BPDA), 3,4′-oxydianiline (3,4′-ODA) or 1,3-bis(4-aminophenoxy)benzene (1,3,4-APB) or 1,3-bis(3-aminophenoxy)benzene (1,3,3-APB), and 2,4-diamino-1-(4-phenylethynylphenoxy)benzene (mPDAp). Among three kinds of polymer, uncured polyimide of a-BPDA/1,3,4-APB; mPDAp had rather high Tg (265 °C, DMA) and thermoplasticity (E′ drop>103 at Tg). After curing reaction of phenylethynyl group, the Tg of the polyimide was increased dramatically (364 °C, DMA). The polyimide derived from 1,3,4-APB having less concentration of curing group (20%) was also prepared to improve further film flexibility and toughness.  相似文献   
8.
The transformations of a molecule containing two adjacent epoxide rings, 2,2-bioxirane that is, were studied over various acidic aluminosilicates (HZSM-5, HY-FAU, AlMCM-41), for the first time, In the 373–473 K temperature range, in a pulse reactor, a ring-opening–ring-enlargment reaction producing furan only occured over the zeolites and it was the predominant reaction on AlMCM-41 as well. The driving force of this transformation route is water formation via elimination from 2,2-bioxirane. Suprising is the lack of the mono- or dialdehyde, the would-be products of the cleavage of the sterically more hindered C–O bonds – an acid-catalysed reaction typical for alkyl-substituted oxiranes.  相似文献   
9.
Chin-Ping Yang  Yu-Yang Su 《Polymer》2005,46(15):5797-5807
A series of organosoluble and light-colored polyimides (III) was prepared from 2,3,3′,4′-biphenyltetracarboxylic dianhydride (α-BPDA) with various fluorinated aromatic bis(ether amine)s via two-step method with thermal or chemical imidization of poly(amic acid)s yielded polyimides. The III series had inherent viscosity of 0.74-1.01 dl/g and showed excellent solubility in a variety of organic solvents. They were soluble in the amide polar solvent, ether-type solvent, and chlorinated solvent. These polyimide films also showed a high optical transparency and less color intensity, with an ultraviolet-visible absorption edge of 369-382 nm and low b* values (a yellowness index) of 5.0-11.7. Glass-transition temperature of the III series was recorded at 244-319 °C and higher than the isomeric polyimides V series. Compared with the nonfluorinated polyimides IV, the III series showed lighter-colored and lower dielectric constants and moisture absorptions. The good tensile properties and excellent thermal properties of the III series were also observed.  相似文献   
10.
设Q为有理数域,利用局部域的方法,讨论了素数p在Q的2m次根扩张Q(u~(1/2m))中的素理想分解问题(其中m为奇素数),并完全确定了素数p在域Q(u~(1/2m))上可能的具体素理想分解形式。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号