“黄金分割法”在爆破工程中的应用探讨

"黄金分割法"是一种古老的数学方法,它无处不在并造就了事物的和谐美,多年来经常被应用到艺术、摄影、绘画、设计等多个领域,而且得到了意想不到的效果。根据多年的爆破工程实践,将"黄金分割法"与工程爆破实例相结合,应用到露天爆破、高耸建(构)筑物爆破拆除等工程中,取得了很好的爆破效果。     

Impact of TiO2 nanoparticles and nanowires on corrosion protection performance of chemically bonded phosphate ceramic coatings

The impact of the addition of TiO₂ nanoparticles and nanowires on the morphology, phase characteristics, contact angle, and electrochemical performance of chemically bonded phosphate ceramic coatings (CBPCs) was investigated. The chemical composition and surface morphology of the TiO₂ nanoparticle and nanowire modified with and without (heptadecafluoro-1,1,2,2-tetradecyl) trimethoxysilane were characterized. Results indicated that the hydrophobic –CF₂– and –CF₃ groups were successfully introduced into the TiO₂ nanoparticles and nanowires after modification. Corrosion resistance of CBPCs with TiO₂ was evidently improved compared with that without TiO₂. Such improvement was mainly due to the combined effects of low surface energy materials and micro/nano structures. In addition, CBPCs with TiO₂ nanowires exhibited higher hydrophobicity and corrosion resistance than those with TiO₂ nanoparticles because of the special columnar structure of the nanowires.     

我国水-能源-粮食耦合关系及影响因素

为缓解我国水、能源和粮食资源紧张问题，促进资源可持续利用，构建水-能源-粮食系统，利用耦合协调度模型对我国的30个省（自治区、直辖市）进行测算,并利用空间杜宾模型分析主要影响因素。结果表明：2003—2017年，我国能源、粮食评价[JP]指数高于水资源评价指数，系统综合评价指数逐年递增；大部分省份耦合协调度处于初级协调水平且呈现逐年上升的态势，个别省份耦合协调度濒临失调；耦合协调度空间自相关性较强，虽有明显波动，但是呈现逐年加强的态势；影响耦合协调度的主要因素有从业人口数、固定资产投资额、人均生产总值、人口总数、[JP]文盲人口占比、工业污染排放、城镇化。     

钢混结构大型厂房整体式爆破拆除

采用整体式控制爆破拆除方案对华电扬州电厂钢筋混凝土框-排架结构厂房进行了爆破拆除。爆破前,对汽机房、厂房外墙和楼梯进行了预处理。将厂房划分为3个爆区,采用非电多回路网格式爆破网路,依靠东侧锅炉房倒塌施加在西侧锅炉房上的倾覆力矩,有效地克服了西侧锅炉房向西倒的难题,可为同类工程提供一定的参考。     

Digestive protection of probiotic Lacticaseibacillus rhamnosus in Ricotta cheese by monoglyceride structured emulsions

This research aimed at studying the potential use of monoglyceride (MG) structured emulsions (MSEs) as delivery and protective systems for probiotic bacteria in Ricotta cheese. To this purpose, a low-fat commercial Ricotta cheese was added with MSEs formulated with milk, as water phase, and sunflower oil (MSE-SO) or anhydrous milk fat (MSE-AMF), as lipid phase. A commercial whole milk Ricotta cheese (W-RC) was considered as reference. A probiotic Lacticaseibacillus rhamnosus strain was inoculated as free cells in W-RC or embedded into the MSEs and added to the low-fat Ricotta at the same reference fat content. After physico-chemical characterisation, L. rhamnosus viability and sample destructuring behaviour upon in vitro digestion were evaluated. At the end of in vitro digestion, both W-RC and sample containing MSE-SO were unable to protect cells. By contrast, sample with AMF ensured a sufficient probiotic viability, even after 14 days of storage at 4 °C. This result was attributed to system composition and structure. During the gastric phase, the presence of caseins and MG-AMF mixed structures induced the formation of clots, entrapping and protecting cells against the acidic pH of the stomach, as confirmed by confocal micrographs and particle size. During the intestinal phase, cell viability was guaranteed by the formation of mixed micelles promoted by MG. It was demonstrated that microbial cells located near MG structures where they found protection.     

A comparison of shear stress estimation methods for a single geobag on a rough bed

There are several methods for estimating bed shear stress in the literature, but comprehensive comparisons among them are limited and under specific conditions. This study compared these methods first on a bare smooth bed, and then for a single geobag on a rough bed in the interest of determining the stability of geobags used in riverbank protection structures. The geobag was filled with cement or sand and tested under different open channel flow conditions. The turbulent kinetic energy method appeared to best represent the local bed shear stress on the geobag when using the newly calibrated proportionality constants. The Reynolds stress method via extrapolation was relatively unaffected by changes to the geobags shape and measurement locations, suggesting this method inadequately represents the local bed shear stress. The Patel method and the universal law of the wall method failed to represent local bed shear stress in the rough bed cases due to instrument limitations and the breakdown of the law of the wall. This study highlights the impact of different methods on the bed shear stress estimation.     

Compatible performance of low thermal conductivity and high infrared radiation of Sm2O3-HfO2 series ceramics applied for thermal protection coatings

Sm₂O₃-HfO₂ series ceramics were synthesized at high temperature using the solid-state reaction. The phase stability, thermo-physical and infrared emission properties of Sm₂Hf₂O₇ (SHO) and Sm₂Hf₂O₇-44.83 wt%HfO₂ (25S/H) composite ceramics were comparatively investigated. Furthermore, their calcium magnesium aluminosilicate (CMAS) corrosion was conducted at 1250°C for different times. The results reveal that both SHO and 25S/H ceramics have excellent phase stability at 1600°C as well as excellent sintering resistance. SHO still exhibits slightly lower thermal conductivity and lower hardness and Young's modulus, higher thermal expansion coefficient (CTE) and fracture toughness as well as higher infrared emittance (0.899 at 800°C) than 25S/H composite with the excessive HfO₂ inside. Both SHO and 25S/H ceramics react with CMAS to form a relatively compact reaction layer, which can effectively prevent the penetration of CMAS. These results preliminarily indicate that SHO ceramic can be proposed as an alternative material of the traditional YSZ for high-temperature thermal protective applications thanks to its compatible performance of low thermal conductivity and high infrared radiation, etc.     

大管径供水管线的安装与腐蚀防护分析

在近些年的发展中,我国经济水平得到了一个显著的增长,经济的增长推动了城市化的发展进程,进入21世纪,城市绿化工程建设规模呈一个稳定上升的趋势,在这种大的社会环境形势下,如何做好绿化大管径供水管线的安装与腐蚀防护工作成为了行业关注的焦点。大管径供水管线的稳定性关系着城市发展的可持续性,要从多方面做好大管径供水管线的安装工作,采取有效的措施应对管线腐蚀问题。     

Matrix Manipulation of Directly-Synthesized PbS Quantum Dot Inks Enabled by Coordination Engineering

The direct-synthesis of conductive PbS quantum dot (QD) ink is facile, scalable, and low-cost, boosting the future commercialization of optoelectronics based on colloidal QDs. However, manipulating the QD matrix structures still is a challenge, which limits the corresponding QD solar cell performance. Here, for the first time a coordination-engineering strategy to finely adjust the matrix thickness around the QDs is presented, in which halogen salts are introduced into the reaction to convert the excessive insulating lead iodide into soluble iodoplumbate species. As a result, the obtained QD film exhibits shrunk insulating shells, leading to higher charge carrier transport and superior surface passivation compared to the control devices. A significantly improved power-conversion efficiency from 10.52% to 12.12% can be achieved after the matrix engineering. Therefore, the work shows high significance in promoting the practical application of directly synthesized PbS QD inks in large-area low-cost optoelectronic devices.